Related papers: Low sulfur depletion in the Horsehead PDR

Sulfur is an abundant element which remains undepleted in diffuse interstellar gas (Av<1) but it is traditionally assumed to deplete on dust grains at higher densities and larger Av. Photodissociation regions (PDRs) are an interesting…

Aims. Our goal is to complete the inventory of S-bearing molecules and their abundances in the prototypical photodissociation region (PDR) the Horsehead nebula to gain insight into sulphur chemistry in UV irradiated regions. Based on the…

Aims: For the first time we investigate the role of the grain surface chemistry in the Horsehead Photo-dissociation region (PDR). Methods: We performed deep observations of several H2CO rotational lines toward the PDR and its associated…

We present the first detection of the l-C3H+ hydrocarbon in the interstellar medium. The Horsehead WHISPER project, a millimeter unbiased line survey at two positions, namely the photo-dissociation region (PDR) and the nearby shielded core,…

Small hydrocarbons, such as C2H, C3H and C3H2 are more abundant in photo-dissociation regions (PDRs) than expected based on gas-phase chemical models. To explore the hydrocarbon chemistry further, we observed a key intermediate species, the…

Aims. We investigate the dominant formation mechanism of H2CO and CH3OH in the Horsehead PDR and its associated dense core. Methods. We performed deep integrations of several H2CO and CH3OH lines at two positions in the Horsehead, namely…

We present high angular resolution images of the H$_2$ 1-0 S(1) line emission obtained with the Son of ISAAC (SOFI) at the New Technology Telescope (NTT) of the Horsehead nebula. These observations are analysed in combination with H$\alpha$…

C+ is a key species in the interstellar medium but its 158 {\mu}m fine structure line cannot be observed from ground-based telescopes. Current models of fluorine chemistry predict that CF+ is the second most important fluorine reservoir, in…

Sulfur is essential for life, but its abundance and distribution in the interstellar medium remain uncertain, with over 90% of sulfur undetected in cold molecular clouds. Sulfur allotropes (S$_{\rm n}$) have been proposed as possible…

Sulphur-bearing species play crucial roles in interstellar chemistry, yet their precise characterisation remains challenging. Here, we present laboratory experiments aimed at extending the high-resolution spectroscopy of protonated carbonyl…

We analyzed archival Herschel observations of water vapor emission toward the Horsehead photon dominated region (PDR), along with supporting ground-based and airborne observations of CO isotopologues and fine structure lines of ionized and…

We performed a detailed analysis of the isotopologues with 13C, 34S, 33S, and 36S of the sulphur-bearing molecules CS, CCS, CCCS,HCS+, HCCS+, and H2CS towards TMC-1 using the QUIJOTE1. The observations were obtained with the Yebes radio…

Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very…

Measuring isotopic ratios is a sensitive technique used to obtain information on stellar nucleosynthesis and chemical evolution. We present measurements of the carbon and sulphur abundances in the interstellar medium of the central region…

A fraction of the missing sulfur in dense clouds and circumstellar regions could be in the form of three species not yet de- tected in the interstellar medium: H2S2, HS2, and S2 according to experimental simulations performed under…

Complex (iso-)nitrile molecules, such as CH3CN and HC3N, are relatively easily detected in our Galaxy and in other galaxies. We constrain their chemistry through observations of two positions in the Horsehead edge: the photo-dissociation…

The JWST has captured the sharpest IR images ever taken of the Horsehead nebula, a prototypical moderately irradiated PDR that is fully representative of most of the UV-illuminated molecular gas in the Milky Way and star-forming galaxies.…

One of the main problems in astrochemistry is determining the amount of sulfur in volatiles and refractories in the interstellar medium. The detection of the main sulfur reservoirs (icy H$_2$S and atomic gas) has been challenging, and…

The ionization fraction plays a key role in the chemistry and dynamics of molecular clouds. We study the H13CO+, DCO+ and HOC+ line emission towards the Horsehead, from the shielded core to the UV irradiated cloud edge, i.e., the…

Carbonaceous nano-grains are a significant component of interstellar dust and dominate the mid-infrared emission of photodissociation regions (PDRs). We study the evolution of nano-grains across the illuminated edge of the Horsehead PDR,…