Related papers: Using H3+ and H2D+ as probes of star-forming regio…
The H3+ ion plays a key role in the chemistry of dense interstellar gas clouds where stars and planets are forming. The low temperatures and high extinctions of such clouds make direct observations of H3+ impossible, but lead to large…
The cosmic abundance of hydrides depends critically on high-energy UV, X-ray, and particle irradiation. Here we study hydrides in star-forming regions where irradiation by the young stellar object can be substantial, and density and…
Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…
We present observations of molecular high-energy radiation probes and report the first detections of CO+ toward W3 IRS5, a source containing ultracompact HII regions. UV radiation and X-rays from the central objects may enhance molecules…
The aim of this study is to investigate systematic chemical differentiation of molecules in regions of high mass star formation. We observed five prominent sites of high mass star formation in HCN, HNC, HCO+, their isotopes, C18O, C34S and…
Ions and electrons play an important role in various stages of the star formation process. By following the magnetic field of their environment and interacting with neutral species, they slow down the gravitational collapse of the…
We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to…
The astrochemistry of the HnO+ (n=1..3) ions is important as the main gas-phase formation route for water, and as tracer of the interstellar ionization rate by cosmic rays and other processes. While interstellar H3O+ has been known since…
The presence of H3+ in the interstellar medium was forecast almost four decades ago. Almost three decades ago it was asserted that its reactions with neutral molecular and atomic species directly lead to the production of many of the…
Early results from the Herschel Space Observatory revealed the water cation H2O+ to be an abundant ingredient of the interstellar medium. Here we present new observations of the H2O and H2O+ lines at 1113.3 and 1115.2 GHz using the Herschel…
The chemistry of the diffuse interstellar medium is driven by the combined influences of cosmic rays, ultraviolet (UV) radiation, and turbulence. Previously detected at the outer edges of photodissociation regions (PDRs) and formed from the…
Observations of Carbon bearing species are among the most important diagnostic probes of ongoing star formation. CO is a surrogate for H$_2$ and is found in the vicinity of star formation sites. There, [CI] emission is thought to outline…
We present a review of observational studies of high-mass star formation, based mainly on our own research. It includes surveys of high-mass star-forming regions in various molecular lines and in continuum, investigations of filamentary…
We model the production of OH+, H2O+, and H3O+ in interstellar clouds, using a steady state photodissociation region code that treats the freeze-out of gas species, grain surface chemistry, and desorption of ices from grains. The code…
Cosmic-rays are the primary initiators of interstellar chemistry, and getting a better understanding of the varying impact they have on the chemistry of interstellar clouds throughout the Milky Way will not only expand our understanding of…
The triatomic hydrogen ion H3+ is one of the most important species for the gas phase chemistry of the interstellar medium. Observations of H3+ are used to constrain important physical and chemical parameters of interstellar environments.…
This paper reviews the chemistry of star-forming regions, with an emphasis on the formation of high-mass stars. We first outline the basic molecular processes in dense clouds, their implementation in chemical models, and techniques to…
Recent models of the envelopes of seven massive protostars are used to analyze observations of H3+ infrared absorption and H13CO+ submillimeter emission lines toward these stars, and to constrain the cosmic-ray ionization rate zeta. The…
Observations of CO+ suggest column densities on the order 10^12 cm^-2 that can not be reproduced by many chemical models. CO+ is more likely to be destroyed than excited in collisions with hydrogen. An anomalous excitation mechanism may…
In diffuse interstellar clouds the chemistry that leads to the formation of the oxygen bearing ions OH+, H2O+, and H3O+ begins with the ionization of atomic hydrogen by cosmic rays, and continues through subsequent hydrogen abstraction…