Related papers: Interstellar Isomers: The Importance of Bonding En…
We have performed a spectral line survey called EMoCA toward Sagittarius B2(N) between 84 and 114 GHz with ALMA. Line intensities of the main isotopic species of ethyl cyanide and its singly 13C-substituted isotopomers observed toward the…
In the interstellar medium, the amide-type molecules play an important role in the formation of the prebiotic molecules in the hot molecular cores or high-mass star formation regions. The complex amide-related molecule cyanamide…
Star formation depends critically on cooling mechanisms in the interstellar medium (ISM); however, thermal properties of gas in galaxies at the peak epoch of star formation (z ~ 2) remain poorly understood. A limiting factor in…
Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated…
Molecular hydrogen clouds are a key component of the interstellar medium because they are the birthplaces for stars. They are embedded in atomic gas that pervades the interstellar space. However, the details of how molecular clouds assemble…
Stellar and nebular abundance indicators reveal that there exists significant abundance fluctuations in the interstellar medium (ISM) of gas-rich galaxies. It is shown that at the present observed solar level of O/H $\sim 6 \times 10^{-4}$,…
Methanol masers at 6.7 GHz are known to be tracers of high-mass star formation in our Galaxy. In this paper, we study the large scale physical conditions in the star forming clumps/cores associated with 6.7 GHz methanol masers using…
This paper presents the study of the interstellar medium toward beta CMa, a disk sight-line known for its low neutral gas density. This study uses high and medium resolution HST-GHRS spectra including lines from many species. The line of…
Methyl carbamate CH$_3$OC(O)NH$_2$ is an isomer of glycine. Quantum chemical analyses show that methyl carbamate is more stable isomer than glycine. Because of this, there could be a higher chance for methyl carbamte to exist in the…
Methanol masers are often detected in regions of intense star formation. Several studies in the last decade indicate that they may even be the earliest signpost of a high-mass star-forming region. Their powerful emission make them very good…
G31.41+0.31 is a well known chemically rich hot molecular core (HMC). Using Band 3 observations of Atacama Large Millimeter Array (ALMA), we have analyzed the chemical and physical properties of the source. We have identified methyl…
Accurate enthalpies of formation are reported for known and potential astromolecules using high level ab initio quantum chemical calculations. A total of 130 molecules comprising of 31 isomeric groups and 24 cyanide/isocyanide pairs with…
In this study, we analyse the characteristics of stellar populations and the interstellar medium (ISM) in 15,107 early-type central galaxies from the SPIDER survey. Using optical spectra from the Sloan Digital Sky Survey (SDSS), we…
The wavelength range 912-2000A (hereafter far-UV) provides access to absorption lines of the interstellar medium (ISM), circumgalactic medium (CGM), and intergalactic medium (IGM) in phases spanning a wide range of ionization, density,…
The astronomical observation of isopropyl cyanide further stresses the link between the chemical composition of the ISM and molecular composition of the meteorites in which there is a dominance of branched chain amino acids as compared to…
In this paper we use observations of molecular tracers in metal rich and alpha-enhanced galaxies to study the effect of abundance changes on molecular chemistry. We selected a sample of metal rich spiral and star bursting objects from the…
We have obtained high resolution (FWHM = 4.4 km/s) Keck spectra of images A and C of the gravitationally lensed QSO Q1422+231. The images are separated by 1.3" on the sky. In an absorption system at z = 3.538 gas column density variations…
Isocyanide-metal binding is governed by sigma-donation and pi-back-bonding, which affects the energy of the isocyanide stretching mode-a characteristic probe for ligand-metal interactions. While extensive correlations exist between…
The Infrared Space Observatory (ISO) has shown the complexity of the Galactic center (GC) Interstellar medium (ISM) detecting, not only large column densities of warm molecular gas (H2), but the emission of neutral atoms and ions of low…
At centimeter wavelengths, single-dish observations have suggested that the Sagittarius (Sgr) B2 molecular cloud at the Galactic Center hosts weak maser emission from several organic molecules, including CH$_2$NH, HNCNH, and HCOOCH$_3$.…