Related papers: H-D Substitution in Interstellar Solid Methanol: A…

The influence of turbulent mixing on the chemistry of the interstellar medium has so far received little attention. Previous studies of this effect have suggested that it might play an important role in mixing the various phases of the…

To measure interstellar atomic deuterium abundances, we used the Interstellar Medium Absorption Profile Spectrograph (IMAPS) to obtain spectra of gamma2 Vel and zeta Pup over the wavelength interval 930-1150 A at a resolving power of…

We present the results of formaldehyde and methanol deuteration measurements towards the Class I low-mass protostar SVS13-A, in the framework of the IRAM 30-m ASAI (Astrochemical Surveys At IRAM) project. We detected emission lines of…

We quantify the gas-phase abundance of deuterium and fractional contribution of stellar mass loss to the gas in cosmological zoom-in simulations from the Feedback In Realistic Environments project. At low metallicity, our simulations…

Deuterium-to-hydrogen (D/H) enrichments in molecular species provide clues about their original formation environment. The organic materials in primitive solar system bodies have generally higher D/H ratios and show greater D/H variation…

This work was carried out with using the Caltech Submillimeter Observatory and presents the observational study of HDS and D2S towards a sample of Class 0 sources, and dense cores. We report the first detection of doubly deuterated hydrogen…

The metallicity and gas density dependence of interstellar depletions, the dust-to-gas (D/G), and dust-to-metal (D/M) ratios have important implications for how accurately we can trace the chemical enrichment of the universe; either by…

Context: Methanol is thought to be mainly formed during the prestellar phase and its deuterated form keeps memory of the conditions at that epoch. Thanks to the unique combination of high angular resolution and sensitivity provided by ALMA,…

We investigate deuterium chemistry coupled with the nuclear spin-state chemistry of H$_2$ and H$_3^+$ in protoplanetary disks. Multiple paths of deuterium fractionation are found; exchange reactions with D atoms, such as HCO$^+$ + D, are…

Deuterium (D) was exclusively generated in the Big Bang and the standard Big Bang Nucleosynthesis (BBN) model predicts a primordial abundance of D/H~26ppm. As the Galaxy evolves, D/H gradually decreases because of astration. The Galactic…

We use high resolution spectra obtained with FUSE and STIS to obtain interstellar column densities of H I, D I, O I, S II, Fe II and P II toward the QSO HE 0226-4110 ( l = 253.4 deg , b = -65.77 deg). We obtain D/H = 21(+8, -6) ppm.…

We present observations of methanol lines in a sample of Class 0 low mass protostars. Using a 1-D radiative transfer model, we derive the abundances in the envelopes. In two sources of the sample, the observations can only be reproduced by…

The D/H ratio in interstellar gas varies on scales of a few hundred pc in the local Milky Way, with D/H values ranging from ~7 ppm to ~22 ppm. The reduction in D/H relative to the primordial value of D/H (~ 26 ppm) is usually attributed to…

Methanol is formed via surface reactions on icy dust grains. Methanol is also detected in the gas-phase at temperatures below its thermal desorption temperature and at levels higher than can be explained by pure gas-phase chemistry. The…

The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…

Observationally, the interstellar gas-phase abundance of deuterium (D) is considerably depleted and the missing D atoms are often postulated to have been locked up into carbonaceous solids and polycyclic aromatic hydrocarbon (PAH)…

Galactic destruction of primordial deuterium is inevitably linked through star formation to the chemical evolution of the Galaxy. The relatively high present gas content and low metallicity suggest only modest D-destruction. In concert with…

Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS…

Methanol (CH$_{3}$OH) ice is abundant in space and is a key feedstock for seeding chemical complexity in interstellar and circumstellar environments. Despite its ubiquity, gas-phase methanol has only been detected in one disk around a…

We present the detection of deuterated molecular hydrogen (HD) in the remote Universe in a damped Lyman-alpha cloud at zabs=2.418 toward the quasar SDSS J143912.04+111740.5. This is a unique system in which H2 and CO molecules are also…