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Diffusion of atoms and molecules is a key process for the chemical evolution in the star forming regions of the interstellar medium. Accurate data on the mobility of many important interstellar species is however often not available and…

Astrophysics of Galaxies · Physics 2014-10-01 L. J. Karssemeijer , H. M. Cuppen

We present a model for the formation of large organic molecules in dark clouds. The molecules are produced in the high density gas-phase that exists immediately after ice mantles are explosively sublimated. The explosions are initiated by…

Astrophysics of Galaxies · Physics 2015-06-12 J. M. C. Rawlings , D. A. Williams , S. Viti , C. Cecchi-Pestellini

Cosmic rays are able to heat interstellar dust grains. This may enhance molecule mobility in icy mantles that have accumulated on the grains in dark cloud cores. A three-phase astrochemical model was used to investigate the molecule…

Astrophysics of Galaxies · Physics 2018-03-14 Juris Kalvans

Context. Water together with O2 are important gas phase ingredients to cool dense gas in order to form stars. On dust grains, H2 O is an important constituent of the icy mantle in which a complex chemistry is taking place, as revealed by…

Solar and Stellar Astrophysics · Physics 2015-05-19 S. Cazaux , V. Cobut , M. Marseille , M. Spaans , P. Caselli

In this paper we investigate the level of star formation activity within nearby molecular clouds. We employ a uniform set of infrared extinction maps to provide accurate assessments of cloud mass and structure and compare these with…

Astrophysics of Galaxies · Physics 2015-05-19 Charles J. Lada , Marco Lombardi , João F. Alves

Carbon dioxide (CO$_2$) is one of the most important interstellar molecules. While it is considered that it forms on the surface of interstellar dust grains, the exact contribution of different chemical mechanisms is still poorly…

We investigate the physical properties of molecular hydrogen (H2) in isolated and interacting disk galaxies with different masses and Hubble types by using chemodynamical simulations with H2 formation on dust grains and dust growth and…

Astrophysics of Galaxies · Physics 2017-03-08 Kenji Bekki

Extremely large deuteration of several molecules has been observed towards prestellar cores and low-mass protostars for a decade. New observations performed towards low-mass protostars suggest that water presents a lower deuteration in the…

Astrophysics of Galaxies · Physics 2015-06-19 Vianney Taquet , Steven B. Charnley , Olli Sipilä

The recent discovery of terrestrial-type organic species such as methyl formate and dimethyl ether in the cold interstellar gas has proved that the formation of organic matter in the Galaxy begins at a much earlier stage of star formation…

Astrophysics of Galaxies · Physics 2015-06-15 A. I. Vasyunin , Eric Herbst

The isomerism of molecules in the interstellar medium and the mechanisms behind it are essential questions in the chemistry of organic molecules in space. In particular, for the simple formic and thioformic acids, the low temperatures found…

Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of…

Astrophysics of Galaxies · Physics 2015-04-24 Juris Kalvans

Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by modeling the physical conditions…

Astrophysics of Galaxies · Physics 2025-12-10 Guillermo M. Muñoz Caro , Héctor Carrascosa de Lucas , Rafael Martín-Doménech

During the evolution of diffuse clouds to molecular clouds, gas-phase molecules freeze out on surfaces of small dust particles to form ices. On dust surfaces, water is the main constituent of the icy mantle in which a complex chemistry is…

Solar and Stellar Astrophysics · Physics 2015-06-22 S. Hocuk , S. Cazaux

We have investigated the time scale for formation of molecular clouds by examining the conversion of HI to H2 using a time-dependent model. H2 formation on dust grains and cosmic ray and photo destruction are included in one-dimensional…

Astrophysics · Physics 2008-11-26 Paul F. Goldsmith , Di Li , Marko Krco

Methanol is formed via surface reactions on icy dust grains. Methanol is also detected in the gas-phase at temperatures below its thermal desorption temperature and at levels higher than can be explained by pure gas-phase chemistry. The…

Solar and Stellar Astrophysics · Physics 2018-05-02 N. F. W. Ligterink , C. Walsh , R. G. Bhuin , S. Vissapragada , J. Terwisscha van Scheltinga , H. Linnartz

Low-energy cosmic rays are a fundamental source of ionization for molecular clouds, influencing their chemical, thermal and dynamical evolution. The purpose of this work is to explore the possibility that a low-energy component of…

Solar and Stellar Astrophysics · Physics 2015-05-13 Marco Padovani , Daniele Galli , Alfred E. Glassgold

Much of the baryonic matter in the Universe is in the form of H2 which includes most of the gas in galactic and extragalactic interstellar clouds. Molecular hydrogen plays a significant role in establishing the thermal balance in many…

Astrophysics · Physics 2009-11-10 G. Shaw , G. J. Ferland , N. P. Abel , P. C. Stancil , P. A. M. van Hoof

Liquid salty micro-channels (brine) between growing ice platelets in sea ice are an important habitat for $CO_2$ - binding microalgaea with great impact on polar ecosystems. The structure formation of ice platelets is microscopically…

Pattern Formation and Solitons · Physics 2017-03-14 K. Morawetz , S. Thoms , B. Kutschan

Context. The presence of dust in the interstellar medium has profound consequences on the chemical composition of regions where stars are forming. Recent observations show that many species formed onto dust are populating the gas phase,…

Solar and Stellar Astrophysics · Physics 2015-12-16 M. Minissale , F. Dulieu , S. Cazaux , S. Hocuk

Molecules in space are synthesized via a large variety of gas-phase reactions, and reactions on dust-grain surfaces, where the surface acts as a catalyst. Especially, saturated, hydrogen-rich molecules are formed through surface chemistry.…

Astrophysics of Galaxies · Physics 2022-02-11 H. M. Cuppen , A. Fredon , T. Lamberts , E. M. Penteado , M. Simons , C. Walsh