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There has always been a great deal of interest in the formation of H2 as well as in the binding energy released upon its formation on the surface of dust grains. The present work aims at collecting experimental evidence for how the bond…

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…

Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms are at work. An astrochemical model of a contracting low-mass…

Astrophysics of Galaxies · Physics 2015-06-23 Juris Kalvans

The formation of molecular hydrogen in the interstellar medium takes place on the surfaces of dust grains. Hydrogen molecules play a role in gas-phase reactions that produce other molecules, some of which serve as coolants during…

Astrophysics · Physics 2009-11-13 Azi Lipshtat , Ofer Biham

We describe a phenomenological model for molecular hydrogen formation suited for applications in galaxy formation simulations, which includes on-equilibrium formation of molecular hydrogen on dust and approximate treatment of both its…

Astrophysics · Physics 2010-12-28 Nickolay Y. Gnedin , Konstantinos Tassis , Andrey V. Kravtsov

Water ice is abundant both astrophysically, for example in molecular clouds, and in planetary systems. The Kuiper belt objects, many satellites of the outer solar system, the nuclei of comets and some planetary rings are all known to be…

Astrophysics · Physics 2009-11-13 Weijun Zheng , David Jewitt , Ralf I. Kaiser

We investigate the formation and evolution of interstellar dust-grain ices under dark-cloud conditions, with a particular emphasis on CO2. We use a three-phase model (gas/surface/mantle) to simulate the coupled gas--grain chemistry,…

Astrophysics of Galaxies · Physics 2015-05-28 Robin T. Garrod , Tyler Pauly

The properties of the first-discovered interstellar object (ISO), 1I/2017 (`Oumuamua), differ from both Solar System asteroids and comets, casting doubt on a protoplanetary disk origin. In this study, we investigate the possibility that it…

Earth and Planetary Astrophysics · Physics 2021-05-05 W. Garrett Levine , Gregory Laughlin

Ice is ubiquitous in the interstellar medium. We model the formation of the main constituents of interstellar ices, including H2O, CO2 , CO, and CH3 OH. We strive to understand what physical or chemical parameters influence the final…

Astrophysics of Galaxies · Physics 2023-07-26 A. Clément , A. Taillard , V. Wakelam , P. Gratier , J. -C. Loison , E. Dartois , F. Dulieu , J. A. Noble , M. Chabot

Water is usually the main component of ice mantles, which cover the cores of dust grains in cold portions of dense interstellar clouds. When molecular hydrogen is adsorbed onto an icy mantle through physisorption, a common assumption in…

Solar and Stellar Astrophysics · Physics 2015-01-21 Ugo Hincelin , Qiang Chang , Eric Herbst

The recombination of hydrogen in the interstellar medium, taking place on surfaces of microscopic dust grains, is an essential process in the evolution of chemical complexity in interstellar clouds. The H_2 formation process has been…

Condensed Matter · Physics 2009-11-07 Ofer Biham , Azi Lipshtat

Hydrogenation reactions of CO in inter- and circumstellar ices are regarded as an important starting point in the formation of more complex species. Previous laboratory measurements by two groups on the hydrogenation of CO ices resulted in…

Solar and Stellar Astrophysics · Physics 2009-06-15 G. W. Fuchs , H. M. Cuppen , S. Ioppolo , C. Romanzin , S. E. Bisschop , S. Andersson , E. F. van Dishoeck , H. Linnartz

Molecular beam experiments that use low-temperature bolometers as (energy-) detectors are well suited to the study of physisorption and recombination of hydrogen on low-temperature surfaces. Experiments where this technique is combined with…

Chemical Physics · Physics 2007-05-23 Thomas Govers

Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…

Solar and Stellar Astrophysics · Physics 2018-09-28 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Context. Interstellar surface chemistry is a complex process that occurs in icy layers accumulated onto grains of different sizes. Efficiency of surface processes often depends on the immediate environment of adsorbed molecules. Aims. We…

Astrophysics of Galaxies · Physics 2024-07-31 Juris Kalvāns , Aija Kalniņa , Kristaps Veitners

Experiments on the hydrogenation of CO on crystalline and amorphous ice at 15 K were carried out to investigate the structural effects of the ice surface. The effective rate of H atom addition to CO on the amorphous ice was found to be…

Astrophysics · Physics 2008-05-23 H. Hidaka , N. Miyauchi , A. Kouchi , N. Watanabe

In the denser and colder ($\leq$20 K) regions of the interstellar medium (ISM), near-infrared observations have revealed the presence of sub-micron sized dust grains covered by several layers of H\textsubscript{2}O-dominated ices and…

Astrophysics of Galaxies · Physics 2020-11-25 Stefano Ferrero , Lorenzo Zamirri , Cecilia Ceccarelli , Arezu Witzel , Albert Rimola , Piero Ugliengo

The first off-lattice Monte Carlo kinetics model of interstellar dust-grain surface chemistry is presented. The positions of all surface particles are determined explicitly, according to the local potential minima resulting from the…

Instrumentation and Methods for Astrophysics · Physics 2015-06-17 Robin T. Garrod

Context. The synthesis of water is one necessary step in the origin and development of life. It is believed that pristine water is formed and grows on the surface of icy dust grains in dark interstellar clouds. Until now, there has been no…

Instrumentation and Methods for Astrophysics · Physics 2015-05-13 F. Dulieu , L. Amiaud , E. Congiu , J-H. Fillion , E. Matar , A. Momeni , V. Pirronello , J. L. Lemaire