Related papers: Detection of D2H+ in the Dense Interstellar Medium

Motivated by recent observations of deuterated molecules in the interstellar medium, we examine the production of HD and D$_2$ molecules on dust grain surfaces. A mechanism for the enhanced production of these deuterated molecules is…

High levels of deuterium fractionation of $\rm N_2H^+$ (i.e., $\rm D_{frac}^{N_2H^+} \gtrsim 0.1$) are often observed in pre-stellar cores (PSCs) and detection of $\rm N_2D^+$ is a promising method to identify elusive massive PSCs. However,…

High levels of deuterium fraction in N$_2$H$^+$ are observed in some pre-stellar cores. Single-zone chemical models find that the timescale required to reach observed values ($D_{\rm frac}^{{\rm N}_2{\rm H}^+} \equiv {\rm N}_2{\rm D}^+/{\rm…

The cosmic-ray ionization rate (zeta) of dense molecular clouds is a key parameter for their dynamics and chemistry. Variations of zeta are well established, but it is unclear if these are related to source column density or to Galactic…

The H3O+ molecule probes the oxygen chemistry and the ionization rate of dense circumnuclear gas in galaxies. In particular, recent H3O+ observations show variations in the cosmic-ray ionization rate by factors of $>$10 within our Galaxy.…

The present survey represents a continuation of our study of high mass star forming regions in the lines of deuterated molecules, the first results of which were published in Trofimova et al. (2020). This paper presents the results of…

Deuterium fractionation in molecular ions, in particular HCO+, has been extensively used to estimate the degree of ionization in molecular clouds. This paper reviews recent work on ionization degree in homogeneous clouds. We will show that…

We report the first detection of the S(1) pure rotational line of ortho-H2 at 17.04 um in an asymptotic giant branch star, using observations of IRC+10216 with the Echelon-cross-echelle Spectrograph (EXES) mounted on the Stratospheric…

We report the first interstellar identification of protonated acetylene, C2H3+, a fundamental hydrocarbon, in the z=0.89 molecular absorber toward the gravitationally lensed quasar PKS1830-211. The molecular species is identified from clear…

We use spectra and maps of NH2D, ND2H, and ND3, obtained with the CSO, IRAM 30m and Arecibo telescopes, to study deuteration processes in dense cores. The data include the first detection of the hyperfine structure of ND2H. The emission of…

Context. The different theoretical models concerning the formation of high-mass stars make distinct predictions regarding their progenitors, i.e. the high-mass prestellar cores. However, so far no conclusive observation of such objects has…

Using high resolution infrared spectroscopy we have surveyed twenty sightlines for H3+ absorption. H3+ is detected in eight diffuse cloud sightlines with column densities varying from 0.6x10^14 cm^-2 to 3.9x10^14 cm^-2. This brings to…

We present echelle spectrophotometry of the Galactic H II region S 311. The data have been taken with the Very Large Telescope UVES echelle spectrograph in the 3100 to 10400 angstroms range. We have measured the intensities of 263 emission…

We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model…

Aims. We measure the deuterium fraction, RD, and the CO-depletion factor, fd, toward a number of starless and protostellar cores in the L1688 region of the Ophiuchus molecular cloud complex and search for variations based upon environmental…

We present N2D+ 3-2 (IRAM) and H2D+ 1_11 - 1_10 and N2H+ 4-3 (JCMT) maps of the small cluster-forming Ophiuchus B2 core in the nearby Ophiuchus molecular cloud. In conjunction with previously published N2H+ 1-0 observations, the N2D+ data…

Herschel/HIFI observations toward the compact HII region W51 has revealed the presence of a cold dense core along its line of sight in a high-velocity stream located just in front of W51. This detection has been made possible through…

We have performed a pointed survey of N2D+ 2-1 and N2D+ 3-2 emission toward 64 N2H+-bright starless and protostellar cores in the Perseus molecular cloud using the Arizona Radio Observatory Submillimeter Telescope and Kitt Peak 12 m…

The first definite discoveries of extragalactic deuterium are reported. DCO$^+$ has been detected in three and DCN has been measured in one star-forming region of the Large Magellanic Cloud (LMC). While the HCO$^+$/DCO$^+$ abundance ratios…

We report the first detection in space of the two doubly deuterated isotopologues of methyl acetylene. The species CHD2CCH and CH2DCCD were identified in the dense core L483 through nine and eight, respectively, rotational lines in the…