Related papers: Anomalous Absorption in Cyclic C$_3$H Radical
Cyclic C5H (c-C5H), the radical formed by substituting an ethynyl group CCH for the hydrogen atom in the c-C3H radical, has been detected for the first time in the space. The c-C5H species is an isomer of the well-known linear radical l-C5H…
We show the combined spectral analysis of \emph{Chandra} high energy transmission grating (HETG) and \emph{XMM-Newton} reflection grating spectrometer (RGS) observations of the broad-line radio galaxy 3C 111. The source is known to show…
We report the detection of linear and cyclic isomers of C3H and C3H2 towards various starless cores and review the corresponding chemical pathways involving neutral (C3Hx with x=1,2) and ionic (C3Hx+ with x = 1,2,3) isomers. We highlight…
We report the first detection of c-C3H2 in a circumstellar disk. The c-C3H2 J=6-5 line (217.882 GHz) is detected and imaged through Atacama Large Millimeter Array (ALMA) Science Verification observations toward the disk around the Herbig Ae…
We report the first detection in interstellar medium of the 1-cyano propargyl radical, HC$_3$HCN. This species is an isomer of the 3-cyano propargyl radical (CH$_2$C$_3$N), which was recently discovered in TMC-1. The 1-cyano propargyl…
The partially deuterated linear isomer HDCCC of the ubiquitous cyclic carbene ($c$-C$_3$H$_2$) was observed in the starless cores TMC-1C and L1544 at 96.9 GHz, and a confirming line was observed in TMC-1 at 19.38 GHz. To aid the…
Using high resolution infrared spectroscopy we have surveyed twenty sightlines for H3+ absorption. H3+ is detected in eight diffuse cloud sightlines with column densities varying from 0.6x10^14 cm^-2 to 3.9x10^14 cm^-2. This brings to…
Observations of chemical species can provide an insight into the physical conditions of the emitting gas but it is important to understand how their abundances and excitation vary within different heating environments. C$_2$H is a molecule…
We present detailed photoionization models of well aligned optically thin C III absorption components at $2.1 < z < 3.4$. Using our models we estimate density ($n_{\rm \tiny H}$), metallicity ($[C/H]$), total hydrogen column density and…
We report the first detection in interstellar space of the 3-cyano propargyl radical (CH2C3N). This species was observed in the cold dark cloud TMC-1 using the Yebes 40m telescope. A total of seven rotational transitions for both ortho- and…
We consider the physical conditions and origin of the z = 0.0777 absorption system observed in C III, C II, Si III, C IV, O VI, and H I absorption along the line of sight towards the quasar PHL 1811. We analysed the HST/STIS and FUSE…
The transition between atomic and molecular hydrogen is associated with important changes in the structure of interstellar clouds, and marks the beginning of interstellar chemistry. Because of the relatively simple networks controlling…
We present a detailed analysis of 99 optically thin C III absorption systems at redshift, $0.2 \le z \le 0.9$ associated with neutral hydrogen column densities in the range, $15 \le {\rm log}$ $N_{\rm H\,I}$ ($cm^{-2}$) $\le 16.2$. Using…
We present Jansky Very Large Array observations of 20 - 37 GHz absorption lines from nearby Galactic diffuse molecular gas seen against four cosmologically-distant compact radio continuum sources. The main new observational results are that…
We present Yebes 40m telescope observations of the three most stable C4H3N isomers towards the cyanopolyyne peak of TMC-1. We have detected 13 transitions from CH3C3N (A and E species), 16 lines from CH2CCHCN, and 27 lines (a-type and…
The chemical pathways linking the small organic molecules commonly observed in molecular clouds to the large, complex, polycyclic species long-suspected to be carriers of the ubiquitous unidentified infrared emission bands remain unclear.…
We report the first detection in space of propadienone, the linear isomer (l-H$_2$C$_3$O) of cyclopropenone (c-H$_2$C$_3$O). We also report the first detection of the isotopologue c-H$_2$$^{13}$CCCO, and c-HDCCCO of c-H$_2$C$_3$O. The…
We report the detection in TMC-1 of the protonated form of C3S. The discovery of the cation HC3S+ was carried through the observation of four harmonically related lines in the Q band using the Yebes 40m radiotelescope, and is supported by…
Doubly ionized silicon (SiIII) is a powerful tracer of diffuse ionized gas inside and outside of galaxies. It can be observed in the local Universe in ultraviolet (UV) absorption against bright extragalactic background sources. We here…
We report the first interstellar identification of protonated acetylene, C2H3+, a fundamental hydrocarbon, in the z=0.89 molecular absorber toward the gravitationally lensed quasar PKS1830-211. The molecular species is identified from clear…