Related papers: Comparing gas-phase and grain-catalyzed H2 formati…
Context: The HD and H2 molecules play important roles in the cooling of primordial and very metal-poor gas at high redshift. Aims: Grain surface and gas phase formation of HD and H2 is investigated to assess the importance of trace amounts…
We study the formation of molecular hydrogen on dust grain surfaces and apply our results to the high redshift universe. We find that a range of physical parameters, in particular dust temperature and gas temperature, but not so much dust…
Context. Water together with O2 are important gas phase ingredients to cool dense gas in order to form stars. On dust grains, H2 O is an important constituent of the icy mantle in which a complex chemistry is taking place, as revealed by…
Aims. Interstellar dust grains, because of their catalytic properties, are crucial to the formation of H2, the most abundant molecule in the Universe. The formation of molecular hydrogen strongly depends on the ability of H atoms to stick…
Aims: The production of molecular hydrogen and its deuterated forms onto carbonaceous dust grains is investigated in detail. The goal of this study is to estimate the importance of the chemistry occuring on grain surfaces for the…
Molecular hydrogen (H2) is the main constituent of the gas in the planet-forming disks that surround many PMS stars. H2 can be incorporated in the atmosphere of the giant planets. HD has been detected in a few disks and can be considered…
Context. Interstellar dust particles, which represent 1% of the total mass, are recognized to be very powerful interstellar catalysts in star-forming regions. The presence of dust can have a strong impact on the chemical composition of…
Previous work by various authors has suggested that the detection by Herschel/HIFI of nitrogen hydrides along the low density lines of sight towards G10.6-0.4 (W31C) cannot be accounted for by gas-phase chemical models. In this paper we…
On galactic scales, the surface density of star formation appears to be well correlated with the surface density of molecular gas. This has lead many authors to suggest that there exists a causal relationship between the chemical state of…
We present models of the evolution of the gaseous and stellar content of galaxies incorporating the formation of H_2 out of HI gas as part of such a model. We do so by formulating a subgrid model for gas clouds that uses well-known cloud…
Star formation is observed to be strongly correlated to dense regions of molecular gas. Although the exact nature of the link between star formation and molecular hydrogen is still unclear, some have suggested that shielding of dense gas by…
The expected episodic or intermittent star formation histories (SFHs) of gas rich dwarf irregular galaxies (dIrrs) are the longstanding puzzles to understand their whole evolutional history. Solving this puzzle, we should grasp what…
The formation of H2 and HD molecules on interstellar dust grains is studied using rate equation and master equation models. Rate equations are used in the analysis of laboratory experiments which examine the formation of molecular hydrogen…
This paper will review the basic concepts of gas-phase and grain surface chemistry of dense molecular clouds, where low mass and high mass stars form. The chemistry of cold pre-stellar cloud cores, where molecular freeze-out and deuterium…
Methods: The microscopic equations of H2-formation and protonation are integrated numerically over time in such a manner that the overall structures evolve self-consistently under benign conditions. Results: The equilibrium H2 formation…
Motivated by recent observations of deuterated molecules in the interstellar medium, we examine the production of HD and D$_2$ molecules on dust grain surfaces. A mechanism for the enhanced production of these deuterated molecules is…
Recent laboratory experiments on interstellar dust analogues have shown that H_2 formation on dust grain surfaces is efficient in a range of grain temperatures below 20 K. These results indicate that surface processes may account for the…
We study the effects of grain surface reactions on the chemistry of protoplanetary disks where gas, ice surface layers and icy mantles of dust grains are considered as three distinct phases. Gas phase and grain surface chemistry is found to…
Formamide has a key role in prebiotic chemistry as it is the simplest molecule containing the four most important atoms from a biological point of view: hydrogen, carbon, nitrogen and oxygen. Due to its importance, the formation of this…
Protoplanetary disks are the target of many chemical studies (both observational and theoretical) as they contain the building material for planets. Their large vertical and radial gradients in density and temperature make them challenging…