Related papers: Master Equation for Hydrogen Recombination on Grai…
The interactions of atomic and molecular hydrogen with bare interstellar dust grain surfaces are important for understanding H2 formation at relatively high temperatures (>20 K). We investigate the diffusion of physisorbed H atoms and the…
Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…
The methodology for modeling grain-surface chemistry has been greatly improved by taking into account the grain size and fluctuation effects. However, the reaction rate coefficients currently used in all practical models of gas-grain…
In the coldest (10--20 K) regions of the interstellar medium, the icy surfaces of interstellar grains serve as solid-state supports for chemical reactions. Among their plausible roles, that of third body is advocated, in which the reaction…
Protoplanetary disks are the target of many chemical studies (both observational and theoretical) as they contain the building material for planets. Their large vertical and radial gradients in density and temperature make them challenging…
Grain surfaces play a central role in the formation and desorption of molecules in space. To form molecules on a grain surface, adsorbed species trapped in binding sites must be mobile and migrate to adjacent sites. Thermal hopping is a…
A model of key processes influencing the evolution of a hydrocarbon grain of an arbitrary size under astrophysical conditions corresponding to ionized hydrogen regions (HII regions) and supernova remnants is presented. The considered…
The $\mathrm{H}_2$ formation on grains is known to be sensitive to dust temperature, which is also known to fluctuate for small grain sizes due to photon absorption. We aim at exploring the consequences of simultaneous fluctuations of the…
We present the first systematic measurement of the binding energy $E_a$ of hydrogen atoms to the surface of saturated $^3$He-$^4$He mixture films. $E_a$ is found to decrease almost linearly from 1.14(1) K down to 0.39(1) K, when the…
We consider the survival of solid H2 in the diffuse interstellar medium, with application to grains which are small enough to qualify as dust. Consideration of only the thermal aspects of this problem leads to the familiar conclusion that…
The study of the chemical evolution of glycine in the interstellar medium is one of challenging topics in astrochemistry. Here, we present the chemical modeling of glycine in hot cores using the state-of-the-art three-phase chemical model…
The progress in high-precision spectroscopy requires one to verify the accuracy of theoretical models such as the master equation describing spontaneous emission of atoms. For this purpose, we apply the coarse-graining method to derive a…
The temperatures of interstellar dust grains are analyzed using stochastic simulations, taking into account the grain composition and size and the discreteness of the photon flux. [...] The distribution of grain temperatures is calculated…
A model was developed for the excitation of the UIBs by H atom impacts in the Interstellar Medium. It builds upon the fact that, in the presence of far UV radiation and hydrocarbon grains, the hydrogen gas will be partially dissociated and…
A model of the grain surface chemistry involving the accretion of atoms of two different elements, X and Y, and their reactions to form species X_2, XY, and Y_2 was examined for a wide range of choices for the values of its three free…
In this work, we present an off-lattice Monte Carlo model of accretion and migration of hydrogen atoms on a rough surface of carbon dust grain. The migration of physisorbed atoms by means of thermal diffusion and quantum tunnelling through…
There exists much uncertainty surrounding interstellar grain-surface chemistry. One of the major reaction mechanisms is grain-surface diffusion for which the the binding energy parameter for each species needs to be known. However, these…
Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…
The basic approach for measuring electron-ion recombination rate coefficients in merged-beams electron-ion collision experiments at heavy-ion storage rings is outlined. As an example experimental results for the low temperature…
Molecular hydrogen is the most abundant molecular species in the Universe. While no doubts exist that it is mainly formed on the interstellar dust grain surfaces, many details of this process remain poorly known. In this work, we focus on…