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Aims: We explore the relation between charge state of polycyclic aromatic hydrocarbons (PAHs) and extinction curve morphology. Methods: We fit extinction curves with a dust model including core-mantle spherical particles of mixed chemical…

Astrophysics · Physics 2009-11-13 C. Cecchi-Pestellini , G. Malloci , G. Mulas , C. Joblin , D. A. Williams

The activation and subsequent covalent coupling of polycyclic aromatic hydrocarbons (PAHs) are of great interest in fields like chemistry, energy, biology, or health, among others. However, this is not a trivial process. So far, it is based…

We present a study for a sample of galaxies with active nuclei to characterize the main type of PAH molecules present in these objects and the local physical conditions of their irradiating sources, as well as the characteristics of the…

We performed mid-infrared spectroscopic observations of 18 local dusty elliptical galaxies by using the Infrared Spectrograph (IRS) on board Spitzer. We have significantly detected polycyclic aromatic hydrocarbon (PAH) features from 14 out…

Astrophysics · Physics 2009-11-13 H. Kaneda , T. Onaka , I. Sakon , T. Kitayama , Y. Okada , T. Suzuki

The signatures of polycyclic aromatic hydrocarbons (PAHs) have been observed in protoplanetary discs, and their emission features obtained from spectral energy distributions (SED) have been used in the literature to characterise their size…

Earth and Planetary Astrophysics · Physics 2023-11-22 K. Lange , C. Dominik , A. G. G. M. Tielens

The integrated luminosity from the features of the polycyclic aromatic hydrocarbons (PAHs) exceeds the luminosity from atomic and molecular emission lines in the star-forming regions in galaxies and is a potential tracer of galaxy-scale…

We explore the relationships between the Polycyclic Aromatic Hydrocarbon (PAH) feature strengths, mid-infrared continuum luminosities, far-infrared spectral slopes, optical spectroscopic classifications, and silicate optical depths within a…

The infrared signatures of polycyclic aromatic hydrocarbons (PAHs) are observed in a variety of astrophysical objects, including the circumnuclear medium of active galactic nuclei (AGNs). These are sources of highly energetic photons (0.2…

Studying the anharmonicity in the infrared (IR) spectra of polycyclic aromatic hydrocarbons (PAHs) at elevated temperatures is important to understand vibrational features and chemical properties of interstellar dust, especially in the…

Aims. Due to the limitations of current computational technology, the fragmentation and isomerization products of vibrationally-excited polycyclic aromatic hydrocarbon (PAH) molecules and their derivatives are poorly studied. In this work,…

Astrophysics of Galaxies · Physics 2020-01-22 Tao Chen , Yi Luo , Aigen Li

In this Letter we report the results of density functional theory calculations on medium-sized neutral Polycyclic Aromatic Hydrocarbon (PAH) molecules with armchair edges. These PAH molecules possess strong C-H stretching and bending modes…

Astrophysics of Galaxies · Physics 2014-10-09 A. Candian , P. J. Sarre , A. G. G. M. Tielens

The observed variations in profiles of the interstellar aromatic infrared bands correlate with the object type and are indicative of PAH populations existing i n different sources. Spectroscopic studies on PAHs can provide tools for the int…

Astrophysics · Physics 2009-11-13 Amit Pathak , Shantanu Rastogi

In order to find out capable molecular source of astronomically well observed infrared (IR) spectrum, asymmetric molecular configuration polycyclic aromatic hydrocarbon (PAH) was analyzed by the density functional theory (DFT) analysis.…

Astrophysics of Galaxies · Physics 2015-10-27 Norio Ota

We report new correlations between ratios of band intensities of the 15-20 {\mu}m emission bands of polycyclic aromatic hydrocarbons (PAHs) in a sample of fifty-seven sources observed with Spitzer/IRS. This sample includes Large Magellanic…

Astrophysics of Galaxies · Physics 2015-10-14 M. J. Shannon , D. J. Stock , E. Peeters

Long-slit 8-13 um spectroscopy of the nebula around NGC 1333 SVS reveals spatial variations in the strength and shape of emission features which are probably produced by polycyclic aromatic hydrocarbons (PAHs). Close to SVS 3, the 11.2 um…

Astrophysics · Physics 2009-10-31 G. C. Sloan , T. L. Hayward , L. J. Allamandola , J. D. Bregman , B. DeVito , D. M. Hudgins

The infrared (IR) emission of polycyclic aromatic hydrocarbons (PAHs) permeates our universe; astronomers have detected the IR signatures of PAHs around many interstellar objects. The IR emission of interstellar PAHs differs from their…

Astrophysics of Galaxies · Physics 2018-10-05 Cameron J. Mackie , Tao Chen , Alessandra Candian , Timothy J. Lee , Alexander G. G. M. Tielens

Clusters of polycyclic aromatic hydrocarbon (PAH) molecules are modelled using explicit all-atom potentials using a rigid body approximation. The PAH's considered range from pyrene (C10H8) to circumcoronene (C54H18), and clusters containing…

Chemical Physics · Physics 2016-09-28 M. Rapacioli , F. Calvo , F. Spiegelman , C. Joblin , D. J. Wales

Interstellar ubiquitous infrared spectrum (IR) due to polycyclic aromatic hydrocarbon (PAH) was observed in many astronomical dust clouds. A capable astronomical chemical evolution path from graphene to PAH was studied based on the first…

Mesoscale and Nanoscale Physics · Physics 2017-03-20 Norio Ota

We examine the UV reprocessing efficiencies of warm dust and polycyclic aromatic hydrocarbons (PAHs) through an analysis of the mid- and far-infrared surface luminosity densities of 85 nearby H$\alpha$-selected star-forming galaxies…

Astrophysics of Galaxies · Physics 2015-06-22 Jason E. Young , Caryl Gronwall , John J. Salzer , Jessica L. Rosenberg

Context: Cosmic rays are present in almost all phases of the ISM. PAHs and cosmic rays represent an abundant and ubiquitous component of the interstellar medium. However, the interaction between them has never before been fully…

Astrophysics of Galaxies · Physics 2015-05-20 E. R. Micelotta , A. P. Jones , A. G. G. M. Tielens
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