Related papers: Dehydrogenation of polycyclic aromatic hydrocarbon…
Polycyclic aromatic hydrocarbons (PAHs) play a critical role in the reprocessing of stellar radiation and in balancing the heating and cooling processes in the interstellar medium (ISM), but appear to be destroyed in HII regions. However,…
As a part of interstellar dust, polycyclic aromatic hydrocarbons (PAHs) are processed by the interaction with vacuum ultraviolet (VUV) photons that are emitted by hot young stars. This interaction leads to the emission of the well-known…
Infrared (IR) absorption spectra of individual polycyclic aromatic hydrocarbons (PAHs) containing methyl (-CH3), methylene (>CH2), or diamond-like *CH groups and IR spectra of mixtures of methylated and hydrogenated PAHs prepared by gas…
Superhydrogenated polycyclic aromatic hydrocarbons (PAHs) may be present in H-rich and ultraviolet-poor benign regions. The addition of excess H atoms to PAHs converts the aromatic bonds into aliphatic bonds, the strongest of which falls…
We have obtained new STIS/HST spectra to search for structure in the ultraviolet interstellar extinction curve, with particular emphasis on a search for absorption features produced by polycyclic aromatic hydrocarbons (PAHs). The presence…
[Abridged] The ionization of polycyclic aromatic hydrocarbons (PAHs), by ultraviolet (UV) photons from massive stars is expected to account for a large fraction of the heating of neutral gas in galaxies. Evaluation of this proposal,…
A distinct set of broad emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 $\mu$m, is often detected in protoplanetary disks (PPDs). These features are commonly attributed to polycyclic aromatic hydrocarbons (PAHs). We model these…
Recent calculations have shown that the UV bump at about 217.5 nm in the extinction curve can be explained by a complex mixture of PAHs in several charge states. Other studies proposed that the carriers are a restricted population made of…
We present a charge distribution based model that computes the infrared spectrum of polycyclic aromatic hydrocarbon (PAH) molecules using recent measurements or quantum chemical calculations of specific PAHs. The model is applied to a…
Dust grains absorb half of the radiation emitted by stars throughout the history of the universe, re-emitting this energy at infrared wavelengths. Polycyclic aromatic hydrocarbons (PAHs) are large organic molecules that trace…
PAHs constitute a major component of the interstellar medium carbon budget, locking up to 10--20% of the elemental carbon. Sequential fragmentation induced by energetic photons leads to the formation of new species, including fullerenes.…
Polycyclic Aromatic Hydrocarbons (PAHs) are carbon-based molecules resulting from the union of aromatic rings and related species, which are likely responsible for strong infrared emission features (3.3, 6.2, 7.7, 8.6, 11.3 and 12.7…
Interstellar polycyclic aromatic hydrocarbons (PAHs) are strongly affected by the absorption of vacuum ultraviolet (VUV) photons in the interstellar medium (ISM), yet the branching ratio between ionization and fragmentation is poorly…
Interstellar polycyclic aromatic hydrocarbons (PAHs) are expected to be strongly processed by vacuum ultraviolet photons. Here, we report experimental studies on the ionization and fragmentation of coronene (C24H12), ovalene (C32H14) and…
In the present contribution, I summarize a systematic study of ISO and Spitzer mid-IR spectra of Galactic regions and star forming galaxies. This study quantifies the relative variations of the main aromatic features inside spatially…
Small organic molecules are thought to provide building blocks for the formation of complex interstellar polycyclic aromatic hydrocarbons (PAHs). However, the underlying chemical mechanisms remain unclear, particularly concerning the role…
The infrared signature of polycyclic aromatic hydrocarbons (PAHs) are present in many protostellar disks and these speciesare thought to play an important role in heating of the gas in the photosphere. We aim to consider PAH cluster…
Various studies have emphasized variations of the charge state and composition of the interstellar polycyclic aromatic hydrocarbon (PAH) population in photodissociation regions (PDRs). We aim to model the spatial evolution of the charge and…
We present a new methodology for simulating mid-infrared emission from polycyclic aromatic hydrocarbons (PAHs) in galaxy evolution simulations. To do this, we combine theoretical models of PAH emission features as they respond to varying…
Polycyclic aromatic hydrocarbon (PAH) emission has been found in both starbursts and modestly starforming galaxies, but the relation between starforming activity and PAH luminosity is still a matter of debate. The different correlation…