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Nonequilibrium statistical mechanics close to equilibrium is studied using SRB states and a formula for their derivatives with respect to parameters. We write general expressions for the thermodynamic fluxes (or currents) and the transport…

chao-dyn · Physics 2016-08-31 Giovannni Gallavotti , David Ruelle

Concepts of everyday use like energy, heat, and temperature have acquired a precise meaning after the development of thermodynamics. Thermodynamics provides the basis for understanding how heat and work are related and with the general…

Statistical Mechanics · Physics 2007-05-23 D. Reguera , J. M. Rubi , J. M. G. Vilar

Onsager's variational principle (OVP) provides us with a systematic way to derive dynamical equations for various soft matter and active matter. By reformulating the Onsager-Machlup variational principle (OMVP), which is a time-global…

Soft Condensed Matter · Physics 2024-10-04 Kento Yasuda , Kenta Ishimoto , Shigeyuki Komura

We study thermal diffusion in binary mixtures in the framework of non-equilibrium thermodynamics. Our formal result displays the role of partial enthalpies and Onsager's generalized mobilities. The mobility ratio provides a measure for the…

Soft Condensed Matter · Physics 2014-01-30 Alois Würger

We discuss an invertible version of Furstenberg's `Ergodic CP Shift Systems'. We show that the explicit regularity of these dynamical systems with respect to magnification of measures, implies certain regularity with respect to translation…

Dynamical Systems · Mathematics 2016-02-10 Nadav Dym

We derive the distribution function of work performed by a harmonic force acting on a uniformly dragged Brownian particle subjected to a rotational torque. Following the Onsager and Machlup's functional integral approach, we obtain the…

Statistical Mechanics · Physics 2016-01-29 Bappa Saha , Sutapa Mukherji

A comparative analysis of two concepts aimed at microscopic substantiation of thermodynamics and kinetics has been performed. The first concept is based on the idea of microscopic reversibility of the dynamics of a system of particles,…

Statistical Mechanics · Physics 2024-02-28 A. Yu. Zakharov

Generalizing a recent work [T. Taniguchi and E. G. D. Cohen, J. Stat. Phys. 126, 1 (2006)] that was based on the Onsager-Machlup theory, a nonlinear relaxation process is considered for a macroscopic thermodynamic quantity. It is found that…

Statistical Mechanics · Physics 2009-11-13 Yuki Sughiyama , Sumiyoshi Abe

Onsager's relations allow one to express the second law of thermodynamics in terms of the underlying associated currents. These relations, however, are usually valid only close to equilibrium. Using a quantum phase space formulation of the…

Quantum Physics · Physics 2020-07-22 Domingos S. P. Salazar , Gabriel T. Landi

We give the explicit structure of the functional governing the dynamical density and current fluctuations for a mesoscopic system in a nonequilibrium steady state. Its canonical form determines a generalised Onsager-Machlup theory. We…

Statistical Mechanics · Physics 2015-05-07 Christian Maes , Karel Netočný

For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

Statistical Mechanics · Physics 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

Universal properties of the statistics of stochastic efficiency for mesoscopic time-reversal symmetry broken energy transducers are revealed in the Gaussian approximation. We also discuss how the second law of thermodynamics restricts the…

Statistical Mechanics · Physics 2015-07-23 Jian-Hua Jiang , Bijay Kumar Agarwalla , Dvira Segal

In this paper we show that the existence of a primarily discrete space-time may be a fruitful assumption from which we may develop a new approach of statistical thermodynamics in pre-relativistic conditions. The discreetness of space-time…

Quantum Physics · Physics 2010-05-17 J. P. Badiali

Time reversal of vast classes of phenomena has direct implications with predictability, causality and the second principle of thermodynamics. We analyze in detail time reversibility of a paradigmatic dissipative nonlinear dynamical system,…

Chaotic Dynamics · Physics 2023-06-26 Constantino Tsallis , Ernesto P. Borges

The principle of microscopic reversibility says that, in equilibrium, two-time cross-correlations are symmetric under the exchange of observables. Thus, the asymmetry of cross-correlations is a fundamental, measurable, and often-used…

Statistical Mechanics · Physics 2023-08-24 Naruo Ohga , Sosuke Ito , Artemy Kolchinsky

The general equation for the flux of an electrolyte in solution in the presence of an external magnetic field was derived mathematically in accordance with the Onsager formalism of irreversible thermodynamics. The time reversal symmetry was…

Chemical Physics · Physics 2007-05-23 A. Eftekhari

At the molecular level fluid motions are, by first principles, described by time reversible laws. On the other hand, the coarse grained macroscopic evolution is suitably described by the Navier-Stokes equations, which are inherently…

We prove an instance of the Reciprocity Theorem that demonstrates that Kerr rotation, also known as the magneto-optical Kerr effect, may only arise in materials that break microscopic time reversal symmetry. This argument applies in the…

Optics · Physics 2014-10-08 Alexander D. Fried

It is a great challenge of nonequilibrium statistical mechanics to calculate entropy production within a microscopic theory. In the framework of linear irreversible thermodynamics, we combine the Mori-Zwanzig-Forster projection operator…

Statistical Mechanics · Physics 2014-01-28 Raphael Wittkowski , Hartmut Löwen , Helmut R. Brand

Recently a number of approaches has been developed to connect the microscopic dynamics of particle systems to the macroscopic properties of systems in nonequilibrium stationary states, via the theory of dynamical systems. This way a direct…

Statistical Mechanics · Physics 2009-10-31 L. Rondoni , E. G. D. Cohen