English
Related papers

Related papers: Entropy of Liquids and Glasses from Recurring Stru…

200 papers

We study hydrodynamics coupled to order parameter based on linear sigma model. We obtain numerical solutions for both boost invariant and non-boost invariant solutions. Both solutions show the order parameter rises with oscillations, which…

Nuclear Theory · Physics 2020-04-24 Shu Lin , Gezheng Zhou

Twenty years ago Poole et al. (Nature 360, 324, 1992) suggested that the anomalous properties of supercooled water may be caused by a critical point that terminates a line of liquid-liquid separation of lower-density and higher-density…

Chemical Physics · Physics 2017-08-14 V. Holten , M. A. Anisimov

The configurational entropy of ice is calculated by thermodynamic integration from high to low temperatures. We use Monte Carlo simulations with a simple energy model which reproduces the Bernal-Fowler ice rules. This procedure is found to…

Chemical Physics · Physics 2015-06-16 Carlos P. Herrero , Rafael Ramirez

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

Statistical Mechanics · Physics 2011-06-13 P. D. Gujrati

This paper presents an {\it ab initio} derivation of the expression given by irreversible thermodynamics for the rate of entropy production for different classes of diffusive processes. The first class are Lorentz gases, where…

Chaotic Dynamics · Physics 2009-11-07 J. R. Dorfman , P. Gaspard , T. Gilbert

Truly stable metastable states are an artifact of the mean-field approximation or the zero temperature limit. If such appealing concepts in glass theory as configurational entropy are to have a meaning beyond these approximations, one needs…

Statistical Mechanics · Physics 2016-08-31 Giulio Biroli , Jorge Kurchan

We investigate numerically the low temperature equilibration of glassy systems via non-local Monte Carlo methods. We re-examine several systems that have been studied previously and investigate new systems in order to test the performance…

Soft Condensed Matter · Physics 2007-05-23 Yisroel Brumer , David R. Reichman

We develop a method of obtaining a hierarchy of new higher-order entropies in the context of compressible models with local and non-local diffusion and isentropic pressure. The local viscosity is allowed to degenerate as the density…

Analysis of PDEs · Mathematics 2019-08-07 Peter Constantin , Theodore D. Drivas , Roman Shvydkoy

The rate of entropy production by a stochastic process quantifies how far it is from thermodynamic equilibrium. Equivalently, entropy production captures the degree to which detailed balance and time-reversal symmetry are broken. Despite…

Statistical Mechanics · Physics 2020-12-02 Luca Cocconi , Rosalba Garcia-Millan , Zigan Zhen , Bianca Buturca , Gunnar Pruessner

The third law of thermodynamics dictates that the entropy of materials becomes zero as temperature ($T$) approaches zero. Contrarily, glass and other similar materials exhibit nonzero entropy at $T=0$, which contradicts the third law. For…

Statistical Mechanics · Physics 2026-02-25 Koun Shirai

A thermodynamic measure of the fragility of liquids has recently (Ito et al ref.1) been defined in terms of the temperature dependence of the excess entropy of liquid over crystal, scaled by the excess entropy at the glass transition…

Disordered Systems and Neural Networks · Physics 2007-05-23 L. -M. Martinez , C. A. Angell

By defining a spatially varying replica overlap parameter for a supercooled liquid referenced to an ensemble of fiducial liquid state configurations we explicitly construct a constrained replica free energy functional that maps directly…

Soft Condensed Matter · Physics 2009-11-13 Jacob D. Stevenson , Aleksandra M. Walczak , Randall W. Hall , Peter G. Wolynes

Preserving biodiversity and ecosystem stability is a challenge that can be pursued through modern statistical mechanics modeling. Here we introduce a variational maximum entropy-based algorithm to evaluate the entropy in a minimal ecosystem…

Biological Physics · Physics 2018-10-17 Mattia Miotto , Lorenzo Monacelli

We obtain the patch-repetition entropy Sigma within the Random First Order Transition theory (RFOT) and for the square plaquette system, a model related to the dynamical facilitation theory of glassy dynamics. We find that in both cases the…

Statistical Mechanics · Physics 2015-06-03 Chiara Cammarota , Giulio Biroli

We calculate the configurational entropy of colloidal particles in a confined geometry interacting as hard disks using Monte Carlo integration method. In particular, we consider systems with three kinds of boundary conditions: hard,…

Soft Condensed Matter · Physics 2023-01-23 Duanduan Wan

Structural glasses prepared by bulk quenching a liquid melt universally exhibit puzzling low-energy excitations commonly known as the ``two-level systems'' (TLSs). Recent studies indicate that ultrastable glassy films made by vapor…

Disordered Systems and Neural Networks · Physics 2026-04-24 Vassiliy Lubchenko

We consider critical models in one dimension. We study the ground state in thermodynamic limit [infinite lattice]. Following Bennett, Bernstein, Popescu, and Schumacher, we use the entropy of a sub-system as a measure of entanglement. We…

Strongly Correlated Electrons · Physics 2009-11-10 Vladimir Korepin

Recent studies indicate that the configurational entropy is an useful tool to investigate the stability and (or) the relative dominance of states for diverse physical systems. Recent examples comprise the connection between the variation of…

High Energy Physics - Theory · Physics 2017-02-22 Nelson R. F. Braga , Roldao da Rocha

In this paper, we investigate and compare two well-developed definitions of entropy relevant for describing the dynamics of isolated quantum systems: bipartite entanglement entropy and observational entropy. In a model system of interacting…

Quantum Physics · Physics 2020-06-01 Dana Faiez , Dominik Šafránek , J. M. Deutsch , Anthony Aguirre

Given a categorical dynamical system, i.e. a triangulated category together with an endofunctor, one can try to understand the complexity of the system by computing the entropy of the endofunctor. Computing the entropy of the composition of…

Algebraic Geometry · Mathematics 2021-07-14 Federico Barbacovi , Jongmyeong Kim