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The quantum dynamics of a system of Rb atoms, modeled by a V-type three-level system interacting with intense probe and pump pulses, are studied. The time-delay-dependent transient-absorption spectrum of an intense probe pulse is thus…

Atomic Physics · Physics 2018-02-14 Vadim Becquet , Stefano M. Cavaletto

We investigate non-equilibrium electron dynamics in crystalline ZnO induced by ultrashort, relatively intense, infrared laser pulses. Our focus is on understanding the mechanism that facilitates efficient conduction band population in ZnO…

Materials Science · Physics 2025-03-21 Xiao Chen , Thomas Lettau , Ulf Peschel , Nicolas Tancogne-Dejean , Silvana Botti

Measuring fluctuations in matter's low energy excitations is the key to unveil the nature of the nonequilibrium response of materials. A promising outlook in this respect is offered by spectroscopic methods that address matter fluctuations…

The transient-absorption spectrum of a $V$-type three-level system is investigated, when this is periodically excited by a train of equally spaced, $\delta$-like pump pulses as, e.g., from an optical-frequency-comb laser. We show that, even…

Atomic Physics · Physics 2019-01-30 Juliane Haug , Stefano M. Cavaletto

Standard optical pump-probe methods analyze a system's temporal response to a laser pulse within sub-femtoseconds to several nanoseconds, constrained by the optical delay line's length. While resistance is a sensitive detector in various…

Instrumentation and Detectors · Physics 2024-04-26 M. I. Blumenau , A. Yu. Kuntsevich

Using time dependent density functional theory (TDDFT) we examine the energy, angular and time-resolved photoelectron spectra (TRPES) of ethylene in a pump-probe setup. To simulate TRPES we expose ethylene to an ultraviolet (UV) femtosecond…

Atomic and Molecular Clusters · Physics 2014-08-28 Alison Crawford-Uranga , Umberto De Giovannini , Duncan John Mowbray , Stefan Kurth , Angel Rubio

Ultrafast laser pump-probe spectroscopy is an important and growing field of physical chemistry that allows the measurement of chemical dynamics on their natural timescales, but undergraduate laboratory courses lack examples of such…

Physics Education · Physics 2023-07-25 Ilana J Porter , Michael W. Zuerch , Anne M. Baranger , Stephen R. Leone

The route towards manipulation of the optoelectronic properties of matter beyond the current limits of electronics starts from a comprehensive study of the ultrafast dynamics triggered by interaction with light. Among them, a fundamental…

A wide range of ultrafast phenomena in various atomic, molecular and condense matter systems is governed by electron dynamics. Therefore, the ability to image electronic motion in real space and real time would provide a deeper…

Atomic Physics · Physics 2018-02-27 Daria Popova-Gorelova

Femtosecond spectroscopy is an important tool for tracking rapid photoinduced processes in a variety of materials. To spatially map the processes in a sample would substantially expand the capabilities of the method. This is, however,…

Optics · Physics 2019-05-01 Ondřej Denk , Kaibo Zheng , Donatas Zigmantas , Karel Žídek

Understanding and controlling the electronic as well as ro-vibrational motion and, thus, the entire chemical dynamics in molecules is the ultimate goal of ultrafast laser and imaging science. In photochemistry, laser-induced dissociation…

I describe the Time-Dependent Superfluid Local Density Approximation, which is an adiabatic extension of the Density Functional Theory to superfluid Fermi systems and their real-time dynamics. This new theoretical framework has been applied…

Quantum Gases · Physics 2013-06-18 Aurel Bulgac

Development of ultrafast lasers and non-linear optical techniques over the last two decades provides tools to access real-time dynamics of low energy excitations in superconductors. For example, time-resolved THz spectroscopy and time- and…

Superconductivity · Physics 2022-04-20 Jure Demsar

We present an effective linear response approach to pump-probe femtosecond coherence spectroscopy in the well separated pulse limit. The treatment presented here is based on a displaced and squeezed state representation for the…

Chemical Physics · Physics 2009-11-06 Anand T. N. Kumar , Florin Rosca , Allan Widom , Paul M. Champion

Coherent light pulses of few to hundreds of femtoseconds (fs) duration have prolifically served the field of ultrafast phenomena. While fs pulses address mainly dynamics of nuclear motion in molecules or lattices in the gas, liquid or…

Chemical Physics · Physics 2013-04-26 P. A. Carpeggiani , P. Tzallas , A. Palacios , D. Gray , F. Martín , D. Charalambidis

We investigate the ultrafast electron dynamics of a model of a wide-bandgap material with inner, valence, and conduction bands excited by an intense few-femtosecond pump and monitored by a delayed attosecond extreme-ultraviolet probe pulse.…

Optics · Physics 2026-05-08 Stefano M. Cavaletto , Lars Bojer Madsen

Quantum material systems upon applying ultrashort laser pulses provide a rich platform to access excited material phases and their transformations that are not entirely like their equilibrium counterparts. The addressability and potential…

Strongly Correlated Electrons · Physics 2021-08-19 Xiaoyi Sun , Shuaishuai Sun , Chong-Yu Ruan

Ultrafast spectroscopy paved the way for probing transient states of matter produced through photoexcitation. Despite significant advances, the microscopic processes governing the formation of these states remain largely unknown. This study…

Materials Science · Physics 2024-08-23 Francesco Libbi , Anders Johansson , Boris Kozinsky , Lorenzo Monacelli

We present a spin-adapted time-dependent coupled cluster singles and doubles model for the molecular response to a sequence of ultrashort laser pulses. The implementation is used to calculate the electronic response to a valence-exciting…

Chemical Physics · Physics 2020-08-28 Andreas S. Skeidsvoll , Alice Balbi , Henrik Koch