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A comprehensive experimental and physics informed neural network numerical inverse diffusion analysis is conducted in technologically important NiAlTi ternary and NiCoFeAlTi quinary solid solutions for estimating and extracting composition…

Materials Science · Physics 2025-11-20 Ismail Kamil Worke , Suman Sadhu , Saswata Bhattacharyya , Aloke Paul

Diffusion in ternary, multiphase systems was studied theoretically and experimentally in Ni-Cr-Al system at 1200C. The samples were prepared by the multiple method. It has been shown that the method allows obtaining good quality, planar,…

Materials Science · Physics 2018-05-08 Marek Zajsuz

Until recently, it was textbook knowledge that the diffusion coefficients could not be estimated in a multi-component system following the widely practised diffusion couple method. The recently proposed constrained diffusion couple methods…

Materials Science · Physics 2024-01-22 Suman Sadhu , Anindita Chakraborty , Surendra Makineni , Saswata Bhattacharyya , Aloke Paul

In this paper the problem of determination of the diffusion coefficients in a ternary multiphase system is discussed. In the literature there is a lack of data concerning the approximation method which allows to determine diffusion…

Materials Science · Physics 2020-11-19 Daria Serafin , Wojciech J. Nowak , Bartek Wierzba

The mobility of vacancies in alloys may limit dislocation climb. Using a combined density functional theory and kinetic Monte Carlo approach we investigate vacancy diffusion in Ni-Re, Ni-W, and Ni-Ta binary alloys up to 10 at.% solute…

Materials Science · Physics 2018-12-13 Maximilian Grabowski , Jutta Rogal , Ralf Drautz

Estimating the diffusion coefficients experimentally in a four-component inhomogeneous alloy following the conventional diffusion couple method by intersecting three couples at the same composition is difficult unless a small composition…

Materials Science · Physics 2020-05-19 Anuj Dash , Neelamegan Esakkiraja , Aloke Paul

Ni/Al reactive multilayers are promising materials for applications requiring controlled local energy release and superior mechanical performance. This study systematically investigates the impact of compositional variations, ranging from…

Materials Science · Physics 2026-04-14 Nensi Toncich , Fabian Schwarz , Rebecca A. Gallivan , Jemma Gillon , Ralph Spolenak

The temporal evolution of ordered gamma-prime(L12)-precipitates and the compositional trajectories during phase-separation of the gamma(face-centered-cubic(f.c.c.)) and gamma-prime(L12)-phases are studied in a…

The binary alloy of titanium-tungsten (TiW) is an established diffusion barrier in high-power semiconductor devices, owing to its ability to suppress the diffusion of copper from the metallisation scheme into the surrounding silicon…

The secondary phase, such as Ni$_3$Al-based $L1_2$ $\gamma^\prime$, is crucially important for precipitation strengthening of superalloys. Composition-structure-property relations provide useful insights for guided alloy design. Here we use…

Materials Science · Physics 2023-06-22 Nikolai A. Zarkevich , Timothy M. Smith , John W. Lawson

Segregation engineering has emerged as a promising pathway towards designing thermally stable nanocrystalline alloys with enhanced mechanical properties. However, the compositional and processing space for solute stabilized microstructures…

Materials Science · Physics 2023-08-31 W. Streit Cunningham , Jungho Shin , Tianjiao Lei , Timothy J Rupert , Daniel S. Gianola

Interdiffusion study is conducted in the Ni-rich part of the beta-Ni(Pt)Al phase following the pseudo-binary approach. Interdiffusion coefficients over the whole composition range considered in this study increases with the increase in Pt…

Materials Science · Physics 2016-06-29 Perumalsamy Kiruthika , Aloke Paul

A few decades earlier, Kirkaldy and Lane proposed an indirect method of estimating the tracer and intrinsic diffusion coefficients in a ternary system (without showing experimental verification), which is otherwise impossible following the…

Materials Science · Physics 2020-09-11 Neelamegan Esakkiraja , Anuj Dash , Avik Mondal , K. C. Hari Kumar , Aloke Paul

Estimating composition dependent diffusion coefficients in multicomponent alloys was a longstanding challenge due to limitations in experimental methods. In this study, we have first demonstrated a strategic design of producing only three…

Materials Science · Physics 2025-06-17 Suman Sadhu , Saswata Bhattacharyya , Aloke Paul

Interdiffusion studies become increasingly difficult to perform with the increasing number of elements in a system. It is rather easy to calculate the interdiffusion coefficients for all the compositions in the interdiffusion zone in a…

Materials Science · Physics 2016-06-29 Aloke Paul

In the present work, the ideal shear strength ({\tau}_is) of dilute Ni34XZ ternary alloys (X or Z = Al, Co, Cr, Fe, Mn, Mo, Nb, Si, Ti) are predicted by first-principles calculations based on density functional theory (DFT) in terms of pure…

Materials Science · Physics 2024-12-12 Shuang Lin , Shun-Li Shang , John D. Shimanek , Yi Wang , Allison M. Beese , Zi-Kui Liu

The experimental data in the literature for the hcp phase of the Mg-Al-Zn ternary system have been critically reviewed. Based on the concentration profiles from the literature, the diffusion coefficients have been re-extracted using the…

Materials Science · Physics 2016-08-09 J. Wang , N. Li , C. Wang , J. I. Beltran , J. LLorca , Y. Cui

Nucleation and growth of Ti$_3$Al \textalpha{}$_2$ ordered domains in \textalpha{}-Ti--Al--X alloys were characterised using a combination of transmission electron microscopy, atom probe tomography and small angle X-ray scattering. Model…

Materials Science · Physics 2021-03-22 Felicity F. Dear , Paraskevas Kontis , Baptiste Gault , Jan Ilavsky , David Rugg , David Dye

Diffusion of atoms in solids is one of the most fundamental kinetic processes that ultimately governs many materials properties. Here, we report on a combined first-principles and kinetic Monte Carlo study of macroscopic diffusion…

Materials Science · Physics 2021-05-25 Tanmoy Chakraborty , Jutta Rogal

Model analogies and exchange of ideas between physics or chemistry with biology or epidemiology have often involved inter-sectoral mapping of techniques. Material mechanics has benefitted hugely from such interpolations from mathematical…

Biological Physics · Physics 2022-06-06 Amit K Chattopadhyay , Bidisha Kundu , Sujit Kumar Nath , Elias C Aifantis
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