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Three-dimensional epitaxial heterostructures are based on covalently-bonded interfaces, whereas those from 2-dimensional (2D) materials exhibit van der Waals interactions. Under the right conditions, however, material structures with mixed…

Silicon carbide (SiC) is an excellent substrate for growth and manipulation of large scale, high quality epitaxial graphene. On the carbon face (the ($\bar{1}\bar{1}\bar{1}$) or $(000\bar{1}$) face, depending on the polytype), the onset of…

Materials Science · Physics 2019-10-23 Jan Kloppenburg , Lydia Nemec , Björn Lange , Matthias Scheffler , Volker Blum

The electronic structure and magnetic properties of the graphene/Fe/Ni(111) system were investigated via combination of the density functional theory calculations and electron-spectroscopy methods. This system was prepared via intercalation…

Materials Science · Physics 2017-09-13 M. Weser , E. N. Voloshina , K. Horn , Yu. S. Dedkov

We present a study of quasi-free-standing monolayer graphene obtained by intercalation of Au atoms at the interface between the carbon buffer layer (Bu-L) and the silicon-terminated face (0001) of 4H-silicon carbide. Au intercalation is…

Because of the dominant role of the surface of molecules and their individuality, molecules behave dis-tinctively in a confined space, which has far-reaching implications in many physical, chemical and bio-logical systems. Here, we…

Mesoscale and Nanoscale Physics · Physics 2014-04-29 DaeEung Lee , Gwanghyun Ahn , Sunmin Ryu

Superlattice potentials are theoretically predicted to modify the single-particle electronic structures. The resulting Coulomb-interaction-dominated low-energy physics would generate highly novel many-body phenomena. Here, by in situ…

Mesoscale and Nanoscale Physics · Physics 2022-06-22 Chaofei Liu , Jian Wang

Graphene has attracted great attentions since its first discovery in 2004. Various approaches have been proposed to control its physical and electronic properties. Here, we report that graphene based intercalation compounds is an efficient…

Materials Science · Physics 2010-11-04 Da Zhan , Li Sun , Zhenhua Ni , Lei Liu , Xiaofeng Fan , Yingying Wang , Ting Yu , Yeng Ming Lam , Wei Huang , Zexiang Shen

We report on an investigation of quasi-free-standing graphene on 6H-SiC(0001) which was prepared by intercalation of hydrogen under the buffer layer. Using infrared absorption spectroscopy we prove that the SiC(0001) surface is saturated…

Materials Science · Physics 2011-10-03 F. Speck , J. Jobst , F. Fromm , M. Ostler , D. Waldmann , M. Hundhausen , H. B. Weber , Th. Seyller

Decoupling of the graphene layer from the ferromagnetic substrate via intercalation of sp metal has recently been proposed as an effective way to realize single-layer graphene-based spin-filter. Here, the structural and electronic…

Materials Science · Physics 2011-12-30 E. N. Voloshina , A. Generalov , M. Weser , S. Boettcher , K. Horn , Yu. S. Dedkov

Intercalation of metal atoms at the SiC(0001)-graphene (Gr) interface can provide confined 2D metal layers with interesting properties. The intercalated Pb monolayer (ML) has shown the coexistence of the Gr(10x10)-moire and a stripe phase,…

Materials Science · Physics 2024-12-10 Lin-Lin Wang , Shen Chen , Marek Kolmer , Yong Han , Michael C. Tringides

The linear band dispersion of graphene's bands near the Fermi level gives rise to its unique electronic properties, such as a giant carrier mobility, and this has triggered extensive research in applications, such as graphene field-effect…

Graphene-metal contact resistance is governed by both intrinsic and extrinsic factors. Intrinsically, both the density of states bottleneck near the Dirac point and carrier reflection at the graphene-metal interface lead to a high contact…

We explore the electronic ground states of Bernal-stacked multilayer graphenes using the Hartree-Fock mean-field approximation and the full-parameter band model. We find that the electron-electron interaction tends to open a band gap in…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Mikito Koshino , Kyoka Sugisawa , Edward McCann

Graphene nanoelectronics potential was limited by the lack of an intrinsic bandgap[1] and attempts to tailor a bandgap either by quantum confinement or by chemical functionalization failed to produce a semiconductor with a large enough band…

Mesoscale and Nanoscale Physics · Physics 2023-08-25 Jian Zhao , Peixun Ji , Yaqi Li , Rui Li , Kaiming Zhang , Hao Tian , Kaichen Yu , Boyue Bian , Luzhen Hao , Xue Xiao , Will Griffin , Noel Dudeck , Ramiro Moro , Lei Ma , Walt A. de Heer

Epitaxial bismuthene on SiC(0001) hosts symmetry-protected metallic edge states within a large bulk band gap, establishing it as a promising two-dimensional topological insulator for hightemperature quantum spin Hall (QSH) transport. Here…

The crystallographic symmetries and spatial distribution of stacking domains in graphene films on SiC have been studied by low energy electron diffraction (LEED) and dark field imaging in a low energy electron microscope (LEEM). We find…

The effect of Mn intercalation on the atomic, electronic and magnetic structure of the graphene/Cu(111) interface is studied using state-of-the-art density functional theory calculations. Different structural models of the…

Materials Science · Physics 2021-12-23 Qilin Guo , Yuriy Dedkov , Elena Voloshina

We demonstrate the fabrication of an ultra thin gallium film, also known as gallenene, beneath epitaxial graphene on 6H-SiC under ambient conditions triggered by liquid gallium intercalation. Gallenene has been fabricated using the liquid…

We report the use of a surfactant molecule during the epitaxy of graphene on SiC(0001) that leads to the growth in an unconventional orientation, namely $R0^\circ$ rotation with respect to the SiC lattice. It yields a very high-quality…

Materials Science · Physics 2020-09-08 F. C. Bocquet , Y. -R. Lin , M. Franke , N. Samiseresht , S. Parhizkar , S. Soubatch , T. -L. Lee , C. Kumpf , F. S. Tautz

Cross-sectional transmission electron microscopy (TEM) is used to characterize an amorphous layer observed at the interface in graphite and graphene films grown via thermal decomposition of C-face 4H-SiC. The amorphous layer does not to…

Materials Science · Physics 2015-05-28 R. Colby , M. L. Bolen , M. A. Capano , E. A. Stach