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Hexagonal boron nitride (hBN) is a natural hyperbolic material which can also accommodate highly dispersive surface phonon-polariton modes. In this paper, we examine theoretically the mid-infrared optical properties of graphene-hBN…

Understanding the origin of electron-phonon coupling in lead-halide perovskites (LHP) is key to interpreting and leveraging their optical and electronic properties. Here we perform femtosecond-resolved, optical-pump,…

We report a photoluminescence observation of robust excitonic polarons due to strong coupling of exciton and longitudinal optical (LO) phonon as well as Fano-type interference in high quality ZnO crystal. At low enough temperatures, the…

Materials Science · Physics 2007-05-23 Shi-Jie Xu , Shi-Jie Xiong , Shen-Lei Shi

In this manuscript we study luminescence of hexagonal boron nitride (hBN) by means of non-equilibrium Green's functions plus time-dependent perturbation theory. We derive a formula for light emission in solids in the limit of a weak…

Materials Science · Physics 2019-02-13 E. Cannuccia , B. Monserrat , C. Attaccalite

The exciton-phonon coupling in highly oriented pyrolytic graphite is studied using resonant inelastic X-ray scattering (RIXS) spectroscopy. With ~ 70 meV energy resolution, multiple low energy excitations associated with coupling to phonons…

We calculate the spectral properties of the one-dimensional Holstein and breathing polarons using the self-consistent Born approximation. The Holstein model electron-phonon coupling is momentum independent while the breathing coupling…

Strongly Correlated Electrons · Physics 2007-05-23 C. Slezak , A. Macridin , G. A. Sawatzky , M. Jarrell , T. A. Maier

Exciton and polaron pair dissociation is a key functional aspect of photovoltaic devices. To improve upon the current state of interfacial transport models, we augment the existing classical models of dielectric interfaces by incorporating…

Materials Science · Physics 2017-05-08 Michael J. Waters , Daniel Hashemi , John Kieffer

We demonstrate that the valence energy-loss function of hexagonal boron nitride (hBN) displays a strong anisotropy in shape, excitation energy and dispersion for momentum transfer q parallel or perpendicular to the hBN layers. This is…

We use path integral Monte Carlo to study the energetics of excitons in layered, hybrid organic-inorganic perovskites in order to elucidate the relative contributions of dielectric confinement and electron-phonon coupling. While the…

Materials Science · Physics 2025-03-26 Rohit Rana , David T. Limmer

In this paper we theoretically describe the absorption of hexagonal boron nitride (hBN) single layer. We develop the necessary formalism and present an efficient method for solving the Wannier equation for excitons. We give predictions for…

Mesoscale and Nanoscale Physics · Physics 2019-10-18 J. C. G. Henriques , G. B. Ventura , C. D. M. Fernandes , N. M. R. Peres

Electron-hole bound pairs, or excitons, are common excitations in semiconductors. They can spontaneously form and ``condense'' into a new insulating ground state -- the so-called excitonic insulator -- when the energy of electron-hole…

We report inelastic neutron scattering measurements of the phonon density-of-states in Mg11B2, which has a superconducting transition at 39.2 K. The acoustic phonons extend in energy to 36 meV, and there are highly dispersive optic branches…

Superconductivity · Physics 2009-11-07 R. Osborn , E. A. Goremychkin , A. I. Kolesnikov , D. G. Hinks

Due to the dispersion of optical phonons, long range electron-phonon correlations renormalize downwards the coupling strength in the Holstein model. We evaluate the size of this effect both in a linear chain and in a square lattice for a…

Materials Science · Physics 2009-11-11 Marco Zoli

Large-radius excitons in polar crystals are considered. It is shown that translation invariant description of excitons interacting with a phonon field leads to a nonzero contribution of phonons into the exciton ground state energy only in…

Mesoscale and Nanoscale Physics · Physics 2021-06-24 Victor D. Lakhno

We investigated emission and propagation of polaritons in a two dimensional van der Waals material hexagonal boron nitride (hBN). Our specific emphasis in this work is on hyperbolic phonon polariton emission that we investigated by means of…

The exciton relaxation dynamics of photoexcited electronic states in poly($p$-phenylenevinylene) (PPV) are theoretically investigated within a coarse-grained model, in which both the exciton and nuclear degrees of freedom are treated…

Chemical Physics · Physics 2018-02-14 Jonathan R. Mannouch , William Barford , Sarah Al-Assam

We investigate temperature-dependent spectral properties of a single defect in hexagonal boron nitride (hBN). We observe a sharp zero-phonon line (ZPL) emission accompanied by Stokes and anti-Stokes optical phonon sidebands assisted by the…

Mesoscale and Nanoscale Physics · Physics 2025-05-14 Ozan Arı , Nahit Polat , Volkan Fırat , Özgür Çakır , Serkan Ates

In most cases, as the strength of electron-phonon coupling increases, the effective mass of polarons typically increases. However, in this paper, we uncover a fascinating phenomenon: the presence of light polarons even within the strong…

Strongly Correlated Electrons · Physics 2024-04-10 Chao Zhang

Optical properties of atomically thin transition metal dichalcogenides are controlled by robust excitons characterized by a very large oscillator strength. Encapsulation of monolayers such as MoSe$_2$ in hexagonal boron nitride (hBN) yields…

Mesoscale and Nanoscale Physics · Physics 2019-08-14 H. H. Fang , B. Han , C. Robert , M. A. Semina , D. Lagarde , E. Courtade , T. Taniguchi , K. Watanabe , T. Amand , B. Urbaszek , M. M. Glazov , X. Marie

Being a flexible wide band gap semiconductor, hexagonal boron nitride (h-BN) has great potential for technological applications like efficient deep ultraviolet light sources, building block for two-dimensional heterostructures and room…