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Polymer based organic photovoltaic (OPV) technology offers a relatively inexpensive option for solar energy conversion provided its efficiency increases beyond the current level (6-7%) along with significant improvements in operational…

Materials Science · Physics 2015-03-17 Biswajit Ray , Pradeep R. Nair , Muhammad A. Alam

The active layer microstructure of organic solar cells is critical to efficiency. By studying the photovoltaic properties of organic solar cell's microstructure, it is possible to increase the efficiency of the solar cell. A graph-based…

Neural and Evolutionary Computing · Computer Science 2019-10-29 Caine Ardayfio

We present a pipeline to study the device performance of organic solar cells in silico. We introduce a mathematical model that includes the dynamics of excitons as well as their dissociation at bulk heterojunctions within the nanomorphology…

The performance of organic solar cells strongly depends on the bulk heterojunction (BHJ) morphology of the photoactive layer. This BHJ forms during the drying of the wet-deposited solution, because of physical processes such as…

Materials Science · Physics 2022-09-29 Olivier Ronsin , Jens Harting

The current density-voltage characteristic (JV) is a critical tool for understanding the behaviour of solar cells. In this article, we present an overview of the key aspects of JV analysis and introduce a user-friendly flowchart that…

Materials Science · Physics 2024-04-17 Albert These , L. Jan Anton Koster , Christoph J. Brabec , Vincent M. Le Corre

Organic solar cells have the potential for widespread usage due to their promise of low cost, roll-to-roll manufacturability, and mechanical flexibility. However, deployment is impeded by their relatively low power conversion efficiencies.…

Materials Science · Physics 2015-03-19 Olga Wodo , Srikanta Tirthapura , Sumit Chaudhary , Baskar Ganapathysubramanian

Machine learning enables rapid estimation of material parameters in solar cells via neural-network-based surrogate models. However, the reliability of extracted parameters depends on underlying assumptions such as the choice of…

Materials Science · Physics 2026-02-11 Eunchi Kim , Thomas Kirchartz

The photocurrent density-voltage (J(V)) curve is the fundamental characteristic to assess opto-electronic devices, in particular solar cells. However, it only yields information on the performance integrated over the entire active device…

Modern photovoltaic devices are often based on a heterojunction structure where two components with different optoelectronic properties are interfaced. The properties of each side of the junction can be tuned by either utilizing different…

The physics of organic bulk heterojunction solar cells is studied within a six state model, which is used to analyze the factors that affect current-voltage characteristics, power-voltage properties and efficiency, and their dependence on…

Materials Science · Physics 2015-06-18 Mario Einax , Marcel Dierl , Philip R. Schiff , Abraham Nitzan

Kinetic Monte Carlo (KMC) simulations have been previously used to model and understand a wide range of behaviors in bulk heterojunction (BHJ) organic photovoltaic devices, from fundamental mechanisms to full device performance. One…

Materials Science · Physics 2015-03-11 Michael C. Heiber , Ali Dhinojwala

A general problem arising in computer simulations is the number of material and device parameters, which have to be determined by dedicated experiments and simulation-based parameter extraction. In this study we analyze measurements of the…

Materials Science · Physics 2009-11-19 R. Hausermann , E. Knapp , M. Moos , N. A. Reinke , T. Flatz , B. Ruhstaller

Organic heterojunction solar cells are analyzed within a minimal model that includes the essential physical features of such systems. The dynamical properties of this model, calculated using a master equation approach, account for the…

Materials Science · Physics 2011-11-11 Mario Einax , Marcel Dierl , Abraham Nitzan

Solvent-based techniques usually involve preparing dilute blends of electron-donor and electron-acceptor materials dissolved in a volatile solvent. After some form of coating onto a substrate, the solvent evaporates. An initially…

Mesoscale and Nanoscale Physics · Physics 2012-03-01 Olga Wodo , Baskar Ganapathysubramanian

The performance of organic bulk heterojunction (BHJ) solar cells is highly sensitive to both nanomorphology and energetic disorder arising from microscopic molecular packing and structural defects. However, most models used to understand…

Models of organic bulk heterojunction photovoltaics which include the effect of spatially varying composition of donor/acceptor materials are developed and analyzed. Analytic expressions for the current-voltage relation in simplified cases…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Paul M. Haney

The use of eco-friendly materials for the environment has been addressed as a critical issue in the development of systems for renewable energy applications. In this regard, the investigation of organic photovoltaic (OPV) molecules for the…

Chemical Physics · Physics 2017-01-13 Alfredo Guillén-López , Miguel Robles , Jesús Muñiz

We provide an alternative formulation of the exact calculation of the current-voltage characteristic of solar cells which have been modeled with a lumped parameters equivalent circuit with one or two diodes. Such models, for instance, are…

Computational Physics · Physics 2016-01-13 Ken Roberts , S. R. Valluri

In this paper we will report an experimental approach for directly determining the photogenerated current at individual junctions within the triple junction solar cell. The method is based on the measurement of different current-voltage…

Materials Science · Physics 2011-02-19 Nelson Veissid , Ricardo Augusto Santos de Abreu

Kinetic Monte Carlo (KMC) simulations are a powerful tool to study the dynamics of charge carriers in organic photovoltaics. However, the key characteristic of any photovoltaic device, its current-voltage ($J$-$V$) curve under solar…

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