Related papers: The problem of relaxation to equilibrium
A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The…
Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…
The expansion of a classical Hamilton formalism consisting in adaptation of it to describe the nonequilibrium systems is offered. Expansion is obtained by construction of formalism on the basis of the dynamics equation of the equilibrium…
Lack of knowledge about the detailed many-particle motion on the microscopic scale is a key issue in any theoretical description of a macroscopic experiment. For systems at or close to thermal equilibrium, statistical mechanics provides a…
In his Comment [1], Philip Strasberg (PS) argues from the analysis of different examples that the framework we have presented in [2] does not recover known results of macroscopic textbook thermodynamics. Here, we show that such apparent…
Lagrange and Hamilton equations for thermodynamic evolution near equilibrium as well as Schrodinger-like equation for the non-equilibrium case are obtained extending the CPDQ Principle (Constancy of the product momentum-oordinate…
We briefly review some equilibrium and nonequilibrium properties of systems with long-range interactions. Such systems, which are characterized by a potential that weakly decays at large distances, have striking properties at equilibrium,…
The mathematical physics of mechanical systems in thermal equilibrium is a well studied, and relatively easy, subject, because the Gibbs distribution is in general an adequate guess for the equilibrium state. On the other hand, the…
Quantum and classical systems can consistently be coupled via non-unitary time-irreversible mechanisms. In this paper we characterize which kind of corresponding dynamics converge in the stationary regime to a thermal hybrid state, that is,…
Many-body systems relaxing to equilibrium can exhibit complex dynamics even if their steady state is trivial. At low temperatures or high densities their evolution is often dominated by steric hindrances affecting particle motion [1,2,3].…
For a quantum system to be captured by a stationary statistical ensemble, as is common in thermodynamics and statistical mechanics, it is necessary that it reaches some apparently stationary state in the first place. In this book chapter,…
Focusing on isolated macroscopic systems, described either in terms of a quantum mechanical or a classical model, our two key questions are: In how far does an initial ensemble (usually far from equilibrium and largely unknown in detail)…
We study the internal dynamics of an elementary quantum system placed close to a body held at a temperature different from that of the surrounding radiation. We derive general expressions for lifetime and density matrix valid for bodies of…
A century ago, the foundations of equilibrium statistical mechanics were laid. For a system in equilibrium with a thermal bath, much is understood through the Boltzmann factor, exp{-H[C]/kT}, for the probability of finding the system in any…
The ongoing discussion whether thermodynamic properties can be extracted from a (possibly approximate) quantum mechanical time evolution using time averages is fed with an instructive example. It is shown for the harmonic oscillator how the…
By assuming that a particle of energy hbar.omega is actually a dissipative system maintained in a nonequilibrium steady state by a constant throughput of energy (heat flow), the exact Schroedinger equation is derived, both for conservative…
We revisit the classical thermodynamic stability of the standard black hole solutions by implementing the intrinsic necessary and sufficient conditions for stable global and local thermodynamic equilibrium. The criteria for such equilibria…
In this paper we develop a generalized formalism for equilibrium thermodynamic systems when an information is shared between the system and the reservoir. The information results in a correction to the entropy of the system. This extension…
The integrable system is constrained strictly by the conservation law during the time evolution, and the nearly integrable system or nonintegrable system is also constrained by the conserved parameters (like the constants of motion) with…
Isothermal compressible two-phase flows with and without phase transition are modeled, employing Darcy's and/or Forchheimer's law for the velocity field. It is shown that the resulting systems are thermodynamically consistent in the sense…