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We show that quasiparticle (QP) energies as calculated in the $GW$ approximation converge to the wrong value using the projector augmented wave (PAW) method, since the overlap integrals between occupied orbitals and high energy, plane wave…

Materials Science · Physics 2014-08-20 Jiří Klimeš , Merzuk Kaltak , Georg Kresse

With the fast developments of high-performance computing, first-principles methods based on quantum mechanics play a significant role in materials research, serving as fundamental tools for predicting and analyzing various properties of…

Materials Science · Physics 2024-10-11 Haochong Zhang , Zichao Deng , Yu Liu , Tao Liu , Mohan Chen , Shi Yin , Lixin He

We present an approach to calculate the optical absorption spectra that combines the quasiparticle self-consistent GW method [Phys. Rev. B, 76 165106 (2007)] for the electronic structure with the solution of the ladder approximation to the…

Materials Science · Physics 2018-03-21 Brian Cunningham , Pooya Azarhoosh , Dimitar Pashov , Myrta Gruening , Mark van Schilfgaarde

A new implementation of the GW approximation (GWA) based on the all-electron Projector-Augmented-Wave method (PAW) is presented, where the screened Coulomb interaction is computed within the Random Phase Approximation (RPA) instead of the…

Materials Science · Physics 2009-11-10 S. Lebègue , B. Arnaud , M. Alouani , P. E. Bloechl

The Quantum Approximate Optimization Algorithm (QAOA) is among leading candidates for achieving quantum advantage on near-term processors. While typically implemented with a transverse-field mixer (XM-QAOA), the Grover-mixer variant…

Quantum Physics · Physics 2026-01-01 Evgeniy O. Kiktenko , Elizaveta V. Krendeleva , Aleksey K. Fedorov

A method for performing variable-width (thawed) Gaussian wavepacket (GWP) variational dynamics on machine-learned potentials is presented. Instead of fitting the potential energy surface (PES), the anharmonic correction to the global…

Chemical Physics · Physics 2024-12-17 Rami Gherib , Ilya G. Ryabinkin , Scott N. Genin

We develop a stochastic formulation of the optimally-tuned range-separated hybrid density functional theory which enables significant reduction of the computational effort and scaling of the non-local exchange operator at the price of…

Chemical Physics · Physics 2016-09-28 Daniel Neuhauser , Eran Rabani , Yael Cytter , Roi Baer

In electronic structure calculations the optimized effective potential (OEP) is a method that treats exchange interactions exactly using a local potential within density-functional theory (DFT). We present a method using density functional…

Materials Science · Physics 2013-01-24 Tom W. Hollins , Stewart J. Clark , Keith Refson , Nikitas I. Gidopoulos

Understanding, optimizing, and controlling the optical absorption process, exciton gemination, and electron-hole separation and conduction in low dimensional systems is a fundamental problem in materials science. However, robust and…

Mesoscale and Nanoscale Physics · Physics 2020-08-26 Keenan Lyon , María Rosa Preciado-Rivas , Duncan John Mowbray , Vito Despoja

We present quasiparticle (QP) energies from fully self-consistent $GW$ (sc$GW$) calculations for a set of prototypical semiconductors and insulators within the framework of the projector-augmented wave methodology. To obtain converged…

Materials Science · Physics 2018-10-31 Manuel Grumet , Peitao Liu , Merzuk Kaltak , Jiří Klimeš , Georg Kresse

The Quantum Approximate Optimization Algorithm (QAOA) has emerged as a promising approach for solving NP hard combinatorial optimization problems on noisy intermediate-scale quantum (NISQ) hardware. However, its performance is critically…

Quantum Physics · Physics 2025-11-13 Rakesh Saini , Nora Mohamed , Saif Al-Kuwari , Ahmed Farouk

We have developed the quasiparticle self-consistent GW (QSGW) method based on a recently developed mixed basis all-electron full-potential method (the PMT method), which uses the augmented plane waves (APWs) and the highly localized…

Materials Science · Physics 2014-08-18 Takao Kotani

The performance of the Quantum Approximate Optimization Algorithm (QAOA) on noisy intermediate-scale quantum (NISQ) devices is strongly limited by sparse qubit connectivity. When interactions required by QAOA Hamiltonians are not aligned to…

Quantum Physics · Physics 2026-04-29 Thiago Assis , Pedro Baptista , Laila Lopes , Diego Ferreira , Gabriel Coutinho

A grid-based real-space implementation of the Projector Augmented Wave (PAW) method of P. E. Blochl [Phys. Rev. B 50, 17953 (1994)] for Density Functional Theory (DFT) calculations is presented. The use of uniform 3D real-space grids for…

Materials Science · Physics 2009-11-10 J. J. Mortensen , L. B. Hansen , K. W. Jacobsen

The Maximum Cut (MaxCut) problem is NP-Complete, and obtaining its optimal solution is NP-hard in the worst case. As a result, heuristic-based algorithms are commonly used, though their design often requires significant domain expertise.…

Machine Learning · Computer Science 2025-06-17 Gabriel Maliakal , Ismail Alkhouri , Alvaro Velasquez , Adam M Alessio , Saiprasad Ravishankar

Developing quantum algorithms adaptive to specific constraints of near-term devices is an essential step towards practical quantum advantage. In a recent work [Phys. Rev. Lett. 131, 103601(2023)], we show cold atoms in an optical cavity can…

Quantum Physics · Physics 2024-06-12 Yuchen Luo , Xiaopeng Li , Jian Lin

We present an extension of the quasiparticle self-consistent $GW$ approximation (QS$GW$) [Phys. Rev. B, 76 165106 (2007)] to include vertex corrections in the screened Coulomb interaction $W$. This is achieved by solving the Bethe-Salpeter…

Materials Science · Physics 2023-10-11 Brian Cunningham , Myrta Grüning , Dimitar Pashov , Mark van Schilfgaarde

We present a semiempirical pseudopotential method based on screened atomic pseudopotentials and derived from \textit{ab initio} calculations. This approach is motivated by the demand for pseudopotentials able to address nanostructures,…

Mesoscale and Nanoscale Physics · Physics 2013-09-25 Alejandro Molina-Sánchez , Alberto García-Cristóbal , Gabriel Bester

The Quantum Approximate Optimization Algorithm (QAOA) is a hybrid quantum-classical variational algorithm designed to tackle combinatorial optimization problems. Despite its promise for near-term quantum applications, not much is currently…

Quantum Physics · Physics 2020-06-26 Leo Zhou , Sheng-Tao Wang , Soonwon Choi , Hannes Pichler , Mikhail D. Lukin

We have developed an efficient computational scheme utilizing the real-space finite-difference formalism and the projector augmented-wave (PAW) method to perform precise first-principles electronic-structure simulations based on the density…

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