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Water autoionization plays a critical role in determining pH and properties of various chemical and biological processes occurring in the water mediated environment. The strikingly unsymmetrical potential energy surface of the dissociation…

Chemical Physics · Physics 2023-12-29 Ling Liu , Yingqi Tian , Chungen Liu

We have studied strong-field enhanced dissociative ionization of D$_{2}$O in 40 fs, 800 nm laser pulses with focused intensities of $< 1 - 3 \times 10^{15}W/cm^2$ by resolving the charged fragment momenta with respect to the laser…

Ionization-excitation of an atom induced by the absorption of a single photon in the presence of a neighbouring atom is studied. The latter is, first, resonantly photoexcited and, afterwards, transfers the excitation energy radiationlessly…

Atomic Physics · Physics 2023-09-06 S. Kim , S. Steinhäuser , A. B. Voitkiv , C. Müller

New ab-initio surface hopping simulations of the excited state dynamics of CS$_2$ including spin-orbit coupling are compared to new experimental measurements using a multiphoton ionisation probe in a photoelectron spectroscopy experiment.…

Context. The He i 1083 nm is a powerful diagnostic for inferring properties of the upper solar chromosphere, in particular for the magnetic field. The basic formation of the line in one-dimensional models is well understood, but the…

Solar and Stellar Astrophysics · Physics 2016-10-19 Jorrit Leenaarts , Thomas Golding , Mats Carlsson , Tine Libbrecht , Jayant Joshi

Anion and cation emission following water dissociation was studied for 6.6-keV $^{16}$O$^{+}$ + H$_{2}$O collisions. Absolute cross sections for the emission of all positively and negatively charged fragments, differential in both energy…

We present models for the chemistry in gas moving towards the ionization front of an HII region. When it is far from the ionization front, the gas is highly depleted of elements more massive than helium. However, as it approaches the…

Astrophysics · Physics 2009-11-13 S. Viti , T. W. Hartquist , P. C. Myers

The angular distribution of the emitted electrons, following the two-photon ionization of the hydrogen-like ions, is studied within the framework of second order perturbation theory and the Dirac equation. Using a density matrix approach,…

Atomic Physics · Physics 2007-05-23 Peter Koval , Stephan Fritzsche , Andrey Surzhykov

Spectral characterization of Super-Earth atmospheres for planets orbiting in the Habitable Zone of M-dwarf stars is a key focus in exoplanet science. A central challenge is to understand and predict the expected spectral signals of…

Earth and Planetary Astrophysics · Physics 2015-06-15 J. L. Grenfell , S. Gebauer , M. Godolt , K. Palczynski , H. Rauer , J. Stock , P. v. Paris , R. Lehmann , F. Selsis

We experimentally demonstrate spatiotemporal steering of photoelectron emission in multiphoton above-threshold single ionization of atoms exposed to a phase-controlled orthogonally polarized two-color (OTC) laser pulse. Spatial and energy…

Within the framework of the second order of the non-relativistic quantum perturbation theory, the analytical structure and absolute values of the generalized cross-sections of the two-photon resonant single ionization of the K-shell of…

Atomic Physics · Physics 2025-09-30 Hopersky A. N. , Nadolinsky A. M. , Novikov S. A. , Koneev R.

Theoretical approaches to the photoionization of few-electron atoms are discussed. These include nonequilibrium Greens functions and wave function based approaches. In particular, the Multiconfiguration Time-Dependent Hartree-Fock method is…

Atomic Physics · Physics 2015-05-14 M. Bonitz , D. Hochstuhl , S. Bauch , K. Balzer

We present an ab initio study of the nonsequential strong-field ionization dynamics of a model two-electron atom with helium character. Single- and double-ionization events are characterized and displayed using detector signals extracted at…

Atomic Physics · Physics 2023-06-14 Daniel Younis , Joseph H. Eberly

The angular distribution of the emitted electrons, following the two--photon ionization of the hydrogen--like ions, is studied within the framework of second order perturbation theory \textit{and} the Dirac equation. Using a density matrix…

Atomic Physics · Physics 2007-05-23 Peter Koval , Stephan Fritzsche , Andrey Surzhykov

Joint electron-ion energy spectra for the dissociative ionization of a model H$_2^+$ in few-cycle, infrared laser pulses are calculated via the numerical ab initio solution of the time-dependent Schr\"odinger equation. A strong,…

Atomic Physics · Physics 2017-11-21 V. Mosert , D. Bauer

We develop an approximate model for the process of direct (nonsequential) two-photon double ionization of atoms. Employing the model, we calculate (generalized) total cross sections as well as energy-resolved differential cross sections of…

Quantum Physics · Physics 2016-08-17 Morten Førre , Sølve Selstø , Raymond Nepstad

The hydrogen ionization and dissociation front around an ultraviolet radiation source should merge when the ratio of ionizing photon flux to gas density is sufficiently low and the spectrum is sufficiently hard. This regime is particularly…

Astrophysics · Physics 2009-11-13 William J. Henney , R. J. R. Williams , Gary J. Ferland , Gargi Shaw , C. R. O'Dell

We investigate the multiphoton ionization of hydrogen driven by a strong bichromatic microwave field. In a regime where classical and quantum simulations agree, periodic orbit analysis captures the mechanism: Through the linear stability of…

Chaotic Dynamics · Physics 2009-11-13 S. Huang , C. Chandre , T. Uzer

Experimental and theoretical results are presented for double, triple, and quadruple photoionization of Si$^+$ and Si$^{2+}$ ions and for double photoionization of Si$^{3+}$ ions by a single photon. The experiments employed the photon-ion…

Highly excited eigenstates of atoms and ions with open f shell are chaotic superpositions of thousands, or even millions of Hartree-Fock determinant states. The interaction between dielectronic and multielectronic configurations leads to…

Atomic Physics · Physics 2015-06-17 V. A. Dzuba , V. V. Flambaum , G. F. Gribakin , C. Harabati , M. G. Kozlov