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The phase-transition sequence of a ferroelectric perovskite such as BaTiO_3 can be simulated by computing the statistical mechanics of a first-principles derived effective Hamiltonian [Zhong, Vanderbilt and Rabe, Phys. Rev. Lett. 73, 1861…

Materials Science · Physics 2009-12-17 Jorge Iniguez , J. B. Neaton , D. Vanderbilt

The three primary ferroics, namely ferromagnets, ferroelectrics and ferroelastics exhibit corresponding large (or even giant) magnetocaloric,electrocaloric and elastocaloric effects when a phase transition is induced by the application of…

Materials Science · Physics 2012-05-08 Teresa Castan , Antoni Planes , Avadh Saxena

Thermodynamics of ferroelectric materials and their ferroelectric to paraelectric (FE-PE) transitions including those in PbTiO3 is commonly described by the phenomenological Landau theory and more recently by effective Hamiltonian and…

Materials Science · Physics 2023-04-21 Zi-Kui Liu , Shun-Li Shang , Jinglian Du , Yi Wang

We investigate relaxation dynamics along the entire first-order phase transition line by analyzing the time evolution of the free energy landscape in the three-dimensional kinetic Ising model. Near the critical temperature $T_{\rm c}$, the…

Statistical Mechanics · Physics 2025-08-28 Ranran Guo , Xiaobing Li , Yuming Zhong , Mingmei Xu , Jinghua Fu , Yuanfang Wu

We use molecular dynamics simulations to study the dynamics of an ensemble of interacting self-propelled semi-flexible polymers in contact with a thermal bath. Our intention is to model complex systems of biological interest. We find that…

Soft Condensed Matter · Physics 2011-05-06 Davide Loi , Stefano Mossa , Leticia F. Cugliandolo

A first-principles based effective Hamiltonian is used within a molecular dynamics simulation to study the elastocaloric effect in PbTiO3. It is found that the transition temperature is a linear function of uniaxial tensile stress. Negative…

Materials Science · Physics 2015-01-19 Jordan A. Barr , Scott P. Beckman , Takeshi Nishimatsu

We present a new and improved method for simultaneous control of temperature and pressure in molecular dynamics simulations with periodic boundary conditions. The thermostat-barostat equations are build on our previously developed…

Statistical Mechanics · Physics 2014-11-20 Niels Grønbech-Jensen , Oded Farago

Based on a rigorous thermodynamic framework, this work develops a two-fluid magnetohydrodynamic model grounded in the Helmholtz free energy formalism. The model maintains full thermodynamic consistency by simultaneously satisfying energy…

Plasma Physics · Physics 2025-11-07 Ting Xiao , Qiaolin He

In this work we study the recently developed parametrized partition function formulation and show how we can infer the thermodynamic properties of fermions based on numerical simulation of bosons and distinguishable particles at various…

Quantum Gases · Physics 2023-06-07 Yunuo Xiong , Hongwei Xiong

The microscopic approach to calculating the free energy of a three-dimensional Ising-like system in a homogeneous external field is developed in the higher non-Gaussian approximation (the $\rho^6$ model) at temperatures above the critical…

Statistical Mechanics · Physics 2008-12-11 I. V. Pylyuk , M. P. Kozlovskii

The zero temperature relaxational dynamics of a particle in a short range correlated random potential is addressed. We derive a set of "two-times" mean-field dynamical equations, accounting for a possible mean displacement of the particle…

Condensed Matter · Physics 2009-10-31 Fabrice Thalmann

We present a first principles molecular dynamics approach that is based on time-reversible ex- tended Lagrangian Born-Oppenheimer molecular dynamics [Phys. Rev. Lett. 100, 123004 (2008)] in the limit of vanishing self-consistent field…

Chemical Physics · Physics 2015-06-18 Petros Souvatzis , Anders M. N. Niklasson

An extensive analysis of an optically-thin, dry atmosphere at different values of the thermal Rossby number Ro and of the Taylor number Ff is per- formed with a general circulation model by varying the rotation rate {\Omega} and the surface…

Fluid Dynamics · Physics 2015-06-11 Salvatore Pascale , Francesco Ragone , Valerio Lucarini , Yixiong Wang , Robert Boschi

We define a characteristic energy density based on the measurement of the two first moments of the extrinsic injected power smoothed over time. Using the stationarity, we show that this definition characterizes an energy per degrees freedom…

Statistical Mechanics · Physics 2018-07-06 Sebastien Aumaitre , Antoine Naert

We present a differentiable formalism for learning free energies that is capable of capturing arbitrarily complex model dependencies on coarse-grained coordinates and finite-temperature response to variation of general system parameters.…

Computational Physics · Physics 2024-05-31 Blake R. Duschatko , Xiang Fu , Cameron Owen , Yu Xie , Albert Musaelian , Tommi Jaakkola , Boris Kozinsky

We present a non-isothermal mesoscopic model for investigation of the phase transition dynamics of thermoresponsive polymers. Since this model conserves energy in the simulations, it is able to correctly capture not only the transient…

Chemical Physics · Physics 2015-04-28 Zhen Li , Yu-Hang Tang , Xuejin Li , George Em Karniadakis

Thermodynamic theory is developed for the ferroelectric phase transition of an ultrathin film in equilibrium with a chemical environment that supplies ionic species to compensate its surface. Equations of state and free energy expressions…

Materials Science · Physics 2015-05-20 G. Brian Stephenson , Matthew J. Highland

The energetic optimization problem, e.g., searching for the optimal switch- ing protocol of certain system parameters to minimize the input work, has been extensively studied by stochastic thermodynamics. In current work, we study this…

Statistical Mechanics · Physics 2010-01-07 Linchen Gong , Ming Li , Zhong-can Ou-yang

We have developed a thorough and accurate method of determining anharmonic free energies, the temperature dependent effective potential technique (TDEP). It is based on \emph{ab initio} molecular dynamics followed by a mapping onto a model…

Statistical Mechanics · Physics 2013-10-14 Olle Hellman , Peter Steneteg , Igor A. Abrikosov , Sergei I. Simak

An efficient method for computing thermodynamic equilibrium states at the micromagnetic length scale is introduced, using the Markov chain Monte Carlo method. Trial moves include not only rotations of vectors, but also a change in their…

Mesoscale and Nanoscale Physics · Physics 2021-11-10 Serban Lepadatu