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We experimentally investigate the influence of surfactant adsorption kinetics on cavity dynamics during the rapid formation of interfaces. For this purpose, we use a submillimeter jet impacting onto a surfactant-laden liquid pool much…

We investigated the effect of surfactants on an interface between two kinds of liquid by molecular dynamics simulation. We adopted the simple bead-spring model with two atoms as the surfactants. We controlled the interfacial tension of the…

Statistical Mechanics · Physics 2024-10-14 Shunta Kikuchi , Hiroshi Watanabe

A multispecies diffuse interface model is formulated in a fluctuating hydrodynamics framework for the purpose of simulating surfactant interfaces at the nanoscale. The model generalizes previous work to ternary mixtures, employing a…

Fluid Dynamics · Physics 2025-08-26 John B. Bell , Andrew Nonaka , Alejandro L. Garcia

We present three-dimensional numerical simulations, employing the well-established lattice Boltzmann method, and investigate similarities and differences between surfactants and nanoparticles as additives at a fluid-fluid interface. We…

Soft Condensed Matter · Physics 2012-07-26 Stefan Frijters , Florian Günther , Jens Harting

We present a model treating the kinetics of adsorption of soluble surface-active molecules at the interface between an aqueous solution and another fluid phase. The model accounts for both the diffusive transport inside the solution and the…

Soft Condensed Matter · Physics 2007-05-23 H. Diamant , D. Andelman

We study the effect of surfactant on the dynamics of a bubble bursting through an interface. We perform fully three-dimensional direct numerical simulations using a hybrid interface-tracking/level-set method accounting for…

Fluid Dynamics · Physics 2021-02-24 C. R. Constante-Amores , L. Kahouadji , A. Batchvarov , S. Shin , J. Chergui , D. Juric , O. K. Matar

Using a hydrodynamic lattice-gas model, we study interface growth in a binary fluid with various concentrations of surfactant. We find that the interface is smoothed by small concentrations of surfactant, while microemulsion droplets form…

Condensed Matter · Physics 2009-10-28 Francis W. Starr , Stephen T. Harrington , Bruce M. Boghosian , H. Eugene Stanley

The surfactant-driven spreading of droplets is an essential process in many applications ranging from coating flow technology to enhanced oil recovery. Despite the significant advancement in describing spreading processes in…

Fluid Dynamics · Physics 2019-09-04 Panagiotis E. Theodorakis , Edward R. Smith , Erich A. Müller

Insoluble surfactants adsorbed at liquid-liquid or gas-liquid interfaces alter interfacial tension, leading to variations in the normal stress jump and generating tangential Marangoni stresses that can dramatically affect the flow dynamics.…

Fluid Dynamics · Physics 2025-07-15 Zhong-Han Xue , Jacques Magnaudet , Jie Zhang

We present a theory for the kinetics of surfactant adsorption at the interface between an aqueous solution and another fluid (air, oil) phase. The model relies on a free-energy formulation. It describes both the diffusive transport of…

Condensed Matter · Physics 2007-05-23 H. Diamant , D. Andelman

A surfactant-laden droplet of one fluid dispersed in another immiscible fluid serves as an artificial model system capable of mimicking microbial swimmers. Either an interfacial chemical reaction or the process of solubilization generates…

Fluid Dynamics · Physics 2022-08-22 Souradeep Roychowdhury , Rajarshi Chattopadhyay , Rahul Mangal , Dipin S. Pillai

The present study deals with the effect of interfacial slip on the deformation and emulsion rheology of a dilute suspension of droplets in a linear flow. The droplets are laden with surfactants that are bulk-insoluble and get transported…

Fluid Dynamics · Physics 2018-04-18 Sayan Das , Anirban Bhattacharjee , Suman Chakraborty

Using numerical simulations, we investigate the effects of Marangoni stresses induced by surfactants on the effective slip length of liquid-infused surfaces (LIS) with transverse grooves. The surfactants are assumed soluble in the external…

Fluid Dynamics · Physics 2022-11-09 Johan Sundin , Shervin Bagheri

The behavior of thin liquid films is known to be strongly affected by the presence of surfactants at the interfaces. The detailed mechanism by which the latter enhance film stability is still a matter of debate, in particular concerning the…

Soft Condensed Matter · Physics 2019-07-24 Lorène Champougny , Benoit Scheid , Frédéric Restagno , Jan Vermant , Emmanuelle Rio

We study the formation of the dynamic adsorption layer when a bubble is released in a tank containing water with a tiny amount of surfactant. The influence of the sorption kinetic constants is examined by comparing the experiments with…

The dynamics of wetting and dewetting is largely determined by the velocity field near the contact lines. For water drops it has been observed that adding surfactant decreases the dynamic receding contact angle even at a concentration much…

Guided by computation, we theoretically calculate the steady flow driven by Marangoni stress due to surfactant introduced on a fluid interface at a constant rate. Two separate extreme cases, where the surfactant dynamics is dominated by the…

Fluid Dynamics · Physics 2018-02-06 S. Mandre

We review a new theoretical approach to the kinetics of surfactant adsorption at fluid-fluid interfaces. It yields a more complete description of the kinetics both in the aqueous solution and at the interface, deriving all equations from a…

Soft Condensed Matter · Physics 2012-07-19 H. Diamant , D. Andelman

We study spreading of a droplet, with insoluble surfactant covering its capillary surface, on a textured substrate. In this process, the surfactant-dependent surface tension dominates the behaviors of the whole dynamics, particularly the…

Fluid Dynamics · Physics 2022-11-08 Yuan Gao , Jian-Guo Liu

Motivated by microfluidic applications, we investigate drag reduction in laminar pressure-driven flows in channels with streamwise-periodic superhydrophobic surfaces (SHSs) contaminated with soluble surfactant. We develop a model in the…

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