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Dispersion interactions such as the van der Waals interaction between atoms or molecules derive from quantum fluctuations of the electromagnetic field and can be understood as the exchange of virtual photons between the interacting…

Quantum Physics · Physics 2015-06-11 Harald R. Haakh , Stefan Scheel

Van der Waals interactions, as a result of the exchange of photons between particles, can be altered by modifying the environment through which these photons propagate. As a consequence, phenomena such as the Rydberg blockade mechanism…

Atomic Physics · Physics 2018-01-03 Johannes Block , Stefan Scheel

We introduce a class of variational wavefunctions that capture the long-range interaction between neutral systems (atoms and molecules) without changing the diagonal of the density matrix of each monomer. The corresponding energy…

Chemical Physics · Physics 2019-03-26 Derk P. Kooi , Paola Gori-Giorgi

The van der Waals interaction between neutral atoms is typically studied using stationary perturbation theory for the short-distance (London) limit, while long-distance (Casimir-Polder) results are usually derived via semiclassical,…

Quantum Physics · Physics 2025-12-30 L. Saba , C. D. Fosco

Within the frame of macroscopic quantum electrodynamics in causal media, the van der Waals interaction between an atomic system and an arbitrary arrangement of dispersing and absorbing dielectric bodies including metals is studied. It is…

Quantum Physics · Physics 2007-05-23 Stefan Yoshi Buhmann , Ho Trung Dung , Dirk-Gunnar Welsch

Using fourth-order perturbation theory, a general formula for the van der Waals potential of two neutral, unpolarized, ground-state atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is…

Quantum Physics · Physics 2007-05-23 Hassan Safari , Stefan Yoshi Buhmann , Dirk-Gunnar Welsch , Ho Trung Dung

Dispersion interactions are long-range interactions between neutral ground-state atoms or molecules, or polarizable bodies in general, due to their common interaction with the quantum electromagnetic field. They arise from the exchange of…

Quantum Physics · Physics 2018-12-13 Roberto Passante

Van der Waals interactions are ubiquitous and they play an important role for the stability of materials. Current understanding of this type of coupling is based on linear response theory, while optical nonlinearities are rarely considered…

Materials Science · Physics 2024-08-27 Dai-Nam Le , Pablo Rodriguez-Lopez , Lilia M. Woods

A local approximation for dynamic polarizability leads to a nonlocal functional for the long-range dispersion interaction energy via an imaginary-frequency integral. We analyze several local polarizability approximations and argue that the…

Chemical Physics · Physics 2015-03-17 Oleg A. Vydrov , Troy Van Voorhis

We derive the complete form of the van der Waals dispersion interaction between two infinitely long anisotropic semiconducting/insulating thin cylinders at all separations. The derivation is based on the general theory of dispersion…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 A. Šiber , R. F. Rajter , R. H. French , W. Y. Ching , V. A. Parsegian , R. Podgornik

We consider the interatomic van der Waals interaction energy between two neutral ground-state atoms moving in the vacuum space with the same uniform acceleration. We assume the acceleration orthogonal to their separation, so that their…

Quantum Physics · Physics 2013-07-25 Antonio Noto , Roberto Passante

Using Schwinger's quantum action principle, dispersion relations are obtained for neutral scalar mesons interacting with bi-local sources. These relations are used as the basis of a method for representing the effect of interactions in the…

High Energy Physics - Theory · Physics 2009-10-28 Mark Burgess

We show that the usual sum of $R^{-6}$ contributions from elements separated by distance $R$ can give \emph{qualitatively} wrong results for the electromagnetically non-retarded van der Waals interaction between non-overlapping bodies. This…

Soft Condensed Matter · Physics 2009-11-11 John F. Dobson , Angela White , Angel Rubio

The impact of van der Waals interaction on the electronic structure between a pentacene monolayer and a graphite surface was investigated. Upon cooling the monolayer, newly formed dispersive bands, showing the constant final state nature…

The theory of self-consistent effective interactions in nuclei is extended for a system with a velocity dependent mean potential. By means of the field coupling method, we present a general prescription to derive effective interactions…

Nuclear Theory · Physics 2009-09-25 T. Kubo , H. Sakamoto , T. Kammuri , T. Kishimoto

We present an approach for computing long-range van der Waals (vdW) interactions between complex molecular systems and arbitrarily shaped macroscopic bodies, melding atomistic treatments of electronic fluctuations based on density…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Prashanth S. Venkataram , Jan Hermann , Alexandre Tkatchenko , Alejandro W. Rodriguez

The long-range electrostatic interactions between molecules depend strongly on their relative orientation, which manifests as a rotational state dependence. Interactions between molecules in the same rotational quantum state are well-known…

Atomic Physics · Physics 2024-05-16 Etienne F. Walraven , Tijs Karman

Electrophoretic deposition is a method of choice for generating coatings thanks to its ease of implementation and its ability to produce coatings of relatively large thicknesses in a single step process. While this process also benefits…

Materials Science · Physics 2026-05-01 Rémi Martin , Sandrine Duluard , Céline Merlet

The processing and material properties of commercial organic semiconductors, for e.g. fullerenes is largely controlled by their precise arrangements, specially intermolecular symmetries, distances and orientations, more specifically,…

Mesoscale and Nanoscale Physics · Physics 2020-12-02 Saunak Das , Johannes Fiedler , Oliver Staufert , Michael Walter , Stefan Yoshi Buhmann , Martin Presselt

A GW calculation based on a truncated Coulomb interaction with an added small q limit was applied to 2D van der Waals heterolayered structures, and the Kane dispersion model was used to determine the accurate band gap edge. All ab initio…

Materials Science · Physics 2025-06-25 Eyasu Tadesse Muda , Tewodros Eyob Ada , Kenate Nemera Nigussa , Cecil N. M. Ouma
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