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Variational quantum algorithms (VQA) are considered as some of the most promising methods to determine the properties of complex strongly correlated quantum many-body systems, especially from the perspective of devices available in the near…

Quantum Physics · Physics 2022-12-07 Saad Yalouz , Bruno Senjean , Filippo Miatto , Vedran Dunjko

We analyse and implement a quasi-Monte Carlo (QMC) finite element method (FEM) for the forward problem of uncertainty quantification (UQ) for the Helmholtz equation with random coefficients, both in the second-order and zero-order terms of…

Numerical Analysis · Mathematics 2025-11-04 Ivan G. Graham , Frances Y. Kuo , Dirk Nuyens , Ian H. Sloan , Euan A. Spence

Quantum simulation of chemical systems is one of the most promising near-term applications of quantum computers. The variational quantum eigensolver, a leading algorithm for molecular simulations on quantum hardware, has a serious…

Quantum Physics · Physics 2019-07-16 Harper R. Grimsley , Sophia E. Economou , Edwin Barnes , Nicholas J. Mayhall

Variational quantum eigensolvers (VQEs) are a promising class of quantum algorithms for preparing approximate ground states in near-term quantum devices. Minimizing the error in such an approximation requires designing ansatzes using…

Quantum Physics · Physics 2021-12-06 Y. Herasymenko , T. E. O'Brien

Quantum Monte Carlo (QMC) forces have been studied extensively in recent decades because of their importance with spectroscopic observables and geometry optimization. Here we benchmark the accuracy and statistical cost of QMC forces. The…

Computational Physics · Physics 2021-06-16 Juha Tiihonen , Raymond C. Clay , Jaron T. Krogel

We report the first successful application of the {\it ab initio} quantum Monte Carlo (QMC) framework to a phonon dispersion calculation. A full phonon dispersion of diamond is successfully calculated at the variational Monte Carlo (VMC)…

Materials Science · Physics 2021-04-14 Kousuke Nakano , Tommaso Morresi , Michele Casula , Ryo Maezono , Sandro Sorella

Variational hybrid quantum-classical algorithms are powerful tools to maximize the use of Noisy Intermediate Scale Quantum devices. While past studies have developed powerful and expressive ansatze, their near-term applications have been…

Quantum Physics · Physics 2021-06-30 Sukin Sim , Jonathan Romero , Jerome F. Gonthier , Alexander A. Kunitsa

Recent advances in quantum information and quantum science have inspired the development of various compact dynamic structured ans\"{a}tze that are expected to be realizable in the Noisy Intermediate-Scale Quantum (NISQ) devices. However,…

Quantum Physics · Physics 2024-03-18 Dipanjali Halder , Dibyendu Mondal , Rahul Maitra

Fault-tolerant quantum computation (FTQC) is essential to implement quantum algorithms in a noise-resilient way, and thus to enjoy advantages of quantum computers even with presence of noise. In FTQC, a quantum circuit is decomposed into…

Quantum Physics · Physics 2025-07-23 Kohdai Kuroiwa , Yuya O. Nakagawa

We investigate the challenge of classical simulation of unitary quantum dynamics with variational Monte Carlo approaches, addressing the instabilities and high computational demands of existing methods. By systematically analyzing the…

Quantum Physics · Physics 2025-07-30 Luca Gravina , Vincenzo Savona , Filippo Vicentini

Quantum annealing in the transverse-field Ising model (TFIM) with open-system dynamics is known to use thermally-assisted tunneling to drive computation. However, it is still subject to debate whether quantum systems in the presence of…

Quantum Physics · Physics 2022-02-14 Daniel O'Connor , Louis Fry-Bouriaux , Paul Warburton

The auxiliary-field quantum Monte Carlo (AFMC) method is a powerful and widely used technique for ground-state and finite-temperature simulations of quantum many-body systems. We introduce several algorithmic improvements for…

Computational Physics · Physics 2021-03-18 C. N. Gilbreth , S. Jensen , Y. Alhassid

Quantum Monte Carlo (QMC) methods such as variational Monte Carlo and fixed node diffusion Monte Carlo depend heavily on the quality of the trial wave function. Although Slater-Jastrow wave functions are the most commonly used variational…

Materials Science · Physics 2015-05-28 Bryan K. Clark , Miguel A. Morales , Jeremy McMinis , Jeongnim Kim , Gustavo E. Scuseria

In this work we present a detailed study of the Fermion Monte Carlo algorithm (FMC), a recently proposed stochastic method for calculating fermionic ground-state energies [M.H. Kalos and F. Pederiva, Phys. Rev. Lett. vol. 85, 3547 (2000)].…

Strongly Correlated Electrons · Physics 2009-11-11 Roland Assaraf , Michel Caffarel , Anatole Khelif

We employ constrained path Auxiliary Field Quantum Monte Carlo (AFQMC) in the pursuit of studying physical nuclear systems using a lattice formalism. Since AFQMC has been widely used in the study of condensed-matter systems such as the…

Nuclear Theory · Physics 2024-07-16 Ryan Curry , Jayani Dissanayake , Stefano Gandolfi , Alexandros Gezerlis

We present a stepwise adaptive-timestep version of the Quantum Jump (Monte Carlo wave-function) algorithm. Our method has proved to remain robust even for problems where the integrating implementation of the Quantum Jump method is…

Quantum Physics · Physics 2019-03-27 M. Kornyik , A. Vukics

The chromium dimer (Cr2) presents an outstanding challenge for many-body electronic structure methods. Its complicated nature of binding, with a formal sextuple bond and an unusual potential energy curve, is emblematic of the competing…

Computational Physics · Physics 2015-02-17 Wirawan Purwanto , Shiwei Zhang , Henry Krakauer

A paramount goal in the field of nuclear physics is to unify ab-initio treatments of bound and unbound states. The position-space quantum Monte Carlo (QMC) methods have a long history of successful bound state calculations in light systems…

Nuclear Theory · Physics 2023-08-29 Abraham R. Flores , Kenneth M. Nollett

In this article we present a caracterization of the vibrational spectrum of the H5+ molecule using the correlation function quantum Monte Carlo (CFQMC) method and a genetic algorithm study of the topology of the potential energy surface…

Quantum Monte Carlo (QMC) methods have proven invaluable in condensed matter physics, particularly for studying ground states and thermal equilibrium properties of quantum Hamiltonians without a sign problem. Over the past decade,…

Quantum Physics · Physics 2024-11-05 Jun Takahashi , Sam Slezak , Elizabeth Crosson
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