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A non-linear conjugate gradient optimization scheme is used to obtain excitation energies within the Random Phase Approximation (RPA). The solutions to the RPA eigenvalue equation are located through a variational characterization using a…

Materials Science · Physics 2011-11-21 Melissa J. Lucero , Anders M. N. Niklasson , Sergei Tretiak , Matt Challacombe

We present an optimized random phase approximation method (optRPA26) that significantly improves upon conventional RPA. The method employs an empirically constructed hybrid functional to generate DFT orbitals to evaluate the RPA correlation…

Chemical Physics · Physics 2026-02-06 Neung-Kyung Yu , Johannes Voss , Andrew J. Medford

We study phase separation and transient gelation in a mixture consisting of polydisperse colloids and non-adsorbing polymers, where the ratio of the average size of the polymer to that of the colloid is approximately 0.063. Unlike what has…

Soft Condensed Matter · Physics 2011-06-23 S. M. Liddle , T. Narayanan , W. C. K. Poon

We investigate the steady-state extensional rheology of a dilute suspension of spherical particles in a dilute polymer solution. For a particle-free polymeric fluid, in addition to the solvent viscosity, the extensional viscosity due to the…

Soft Condensed Matter · Physics 2022-09-01 Arjun Sharma , Donald L. Koch

The associative interaction, such as hydrogen bonding, can bring about versatile functionalities to polymer systems, which has been investigated by tremendous researches, but the fundamental understanding on association process is still…

Soft Condensed Matter · Physics 2025-01-20 Xiangyu Zhang , Dong Meng

Coherent potential approximation (CPA) has widely been used for studying residual resistivity of bulk alloys and electrical conductivity in inhomogeneous systems with structural disorder. Here we revisit the single-site CPA within the…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 M. Ye. Zhuravlev , A. V. Vedyayev , K. D. Belashchenko , E. Y. Tsymbal

The Random Phase and Amplitude Formalism (RPA) has significantly extended the scope of weak turbulence studies. Because RPA does not assume any proximity to the Gaussianity in the wavenumber space, it can predict, for example, how the…

Chaotic Dynamics · Physics 2014-01-15 Mitsuhiro Tanaka , Naoto Yokoyama

The Hartree-Fock-RPA approach is applied to the 1D anti-ferromagnetic Heisenberg model in the Jordan-Wigner representation. Somewhat contrary to expectation, this leads to reasonable results for spectral functions and sum rules in the…

Strongly Correlated Electrons · Physics 2009-11-11 A. Rabhi , P. Schuck , J. Da Providencia

A new mean-field type theory is proposed to study order-disorder transitions (ODT) in block copolymers. The theory applies to both the weak segregation (WS) and the strong segregation (SS) regimes. A new energy functional is proposed…

Materials Science · Physics 2016-08-31 A. Rebei , J. de Pablo

We apply the computational methodology of phase retrieval to the problem of folding heteropolymers. The ground state fold of the polymer is defined by the intersection of two sets in the configuration space of its constituent monomers: a…

Biomolecules · Quantitative Biology 2013-05-29 Veit Elser , Ivan Rankenburg

We propose a practical method to solve the random-phase approximation (RPA) in the self-consistent Hartree-Fock (HF) and density-functional theory. The method is based on numerical evaluation of the residual interactions utilizing finite…

Nuclear Theory · Physics 2010-11-26 Takashi Nakatsukasa , Tsunenori Inakura , Kazuhiro Yabana

The non-stretching approximation of polymer rheology simplifies a constitutive equation but fundamentally changes its behavior in fast flows, and the circumstances under which fast flows emerge cannot always be predicted a-priori. In this…

Soft Condensed Matter · Physics 2024-10-25 Vickie Chen , Brandon Wang , Joseph D. Peterson

A fully self-consistent renormalized random-phase approximation is constructed based on the self-consistent Hartree-Fock mean field plus exact pairing solutions (EP). This approach exactly conserves the particle number and restores the…

Nuclear Theory · Physics 2019-06-06 L. Tan Phuc , N. Quang Hung , N. Dinh Dang

An extension of the Asakura-Oosawa-Vrij model of hard sphere colloids and non-adsorbing polymers, that takes polymer non-ideality into account through a repulsive stepfunction pair potential between polymers, is studied with grand canonical…

Soft Condensed Matter · Physics 2007-05-23 R. L. C. Vink , M. Schmidt

Brownian motion and viscoelasticity of semiflexible polymers is a subject that has been studied for many years. Still, rigorous analysis has been hindered due to the difficulty in handling the constraint that polymer chains cannot be…

Soft Condensed Matter · Physics 2024-05-22 Zhongqiang Xiong , Ryohei Seto , Masao Doi

The formation of (bio)molecular condensates via liquid-liquid phase separation in cells has received increasing attention, as these coacervates play important functional and regulatory roles within biological systems. However, the majority…

Soft Condensed Matter · Physics 2022-11-24 Arash Nikoubashman , Miho Yanagisawa

In this note we study the field theory of dynamic isotropic percolation (DIP) with quenched randomness that has long range correlations decaying as $r^{-a}$. We argue that the quasi static limit of this field theory describes the critical…

Statistical Mechanics · Physics 2007-05-23 Vesselin I. Marinov

The accuracy of the constrained random phase approximation(cRPA) method is examined in multi-orbital Hubbard models containing all possible on-site density-density interactions. Using DMFT, we show that the effective model constructed using…

Strongly Correlated Electrons · Physics 2018-10-16 Qiang Han , B. Chakrabarti , K. Haule

This study focuses on comparing the individual polymer chain dynamics in an entangled polymeric liquid under different shear and extension rates. Polymer chains under various shear rates and extension rates were simulated using a…

Chemical Physics · Physics 2021-01-15 Behrouz Behdani , Tong Mou , Cody Spratt , Slava Butcovich , Ryan Gettler , Joontaek Park

Broadband energy-time entanglement can be used to enhance the rate of two-photon absorption (TPA) by combining a precise two-photon resonance with a very short coincidence time. Because of this short coincidence time, broadband TPA is not…

Quantum Physics · Physics 2023-12-04 Baihong Li , Holger F. Hofmann