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Using dynamical mean-field theory (DMFT) we study a simplified model for heterostructures involving superconductors. The system is driven out-of-equilibrium by a voltage bias, imposed as an imbalance of chemical potential at the interface.…

Strongly Correlated Electrons · Physics 2016-03-21 A. Amaricci , M. Capone

Current theories of diffusiophoresis in porous media are limited to a porous medium saturated with a valence symmetric electrolyte. A predictive model for diffusiophoresis in porous media saturated with a valence asymmetric electrolyte, or…

Soft Condensed Matter · Physics 2024-12-03 Siddharth Sambamoorthy , Henry C. W. Chu

Lithium-ion batteries rely on particulate porous electrodes to realize high performance, especially the fast-charging capability. To minimize the particle-wise reaction heterogeneities that may lead to local hot spots, deeper understandings…

Materials Science · Physics 2022-04-15 Shubham Agrawal , Peng Bai

The transient processes of electron transport in nano-scale devices exhibit special phenomena that exist only in the transient regime. Besides how fast the steady states are approached, one interesting aspect of transient transport arises…

Mesoscale and Nanoscale Physics · Physics 2016-04-01 Matisse Wei-Yuan Tu , Amnon Aharony , Ora Entin-Wohlman , Avraham Schiller , Wei-Min Zhang

We present a theoretical investigation of the voltage-driven metal insulator transition based on solving coupled Boltzmann and Hartree-Fock equations to determine the insulating gap and the electron distribution in a model system -- a one…

Strongly Correlated Electrons · Physics 2018-12-03 Giuliano Chiriacò , Andrew J. Millis

We study the model of a molecular switch comprised of a molecule with a soft vibrational degree of freedom coupled to metallic leads. In the presence of strong electron-ion interaction, different charge states of the molecule correspond to…

Mesoscale and Nanoscale Physics · Physics 2008-12-18 Fabio Pistolesi , Yaroslav M. Blanter , Ivar Martin

Antiferroelectric liquid crystals can be considered as a promising alternative to nematic mixtures in the area of microdisplays. Switching behaviour of the molecules has been modelled as two adjacent smectic layers. However, some studies…

Soft Condensed Matter · Physics 2007-05-23 P. L. del Castillo , P. L. Lucas , N. Bennis , A. Spadlo , D. Rodriguez-Perez

Within the Poisson-Boltzmann (PB) approach electrolytes in contact with planar, spherical, and cylindrical electrodes are analyzed systematically. The dependences of their capacitance $C$ on the surface charge density $\sigma$ and the ionic…

Soft Condensed Matter · Physics 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

A lattice Boltzmann scheme able to model the hydrodynamics of phase separation and two-phase flow is described. Thermodynamic consistency is ensured by introducing a non-ideal pressure tensor directly into the collision operator. We also…

comp-gas · Physics 2009-10-28 Michael R. Swift , W. R. Osborn , J. M. Yeomans

In the present paper, we develop a semiclassical quasi-static model accounting for molecular double ionization in an intense laser pulse. With this model, we achieve insight into the dynamics of two highly-correlated valence electrons under…

Atomic and Molecular Clusters · Physics 2009-11-13 Di-Fa Ye , Jing Chen , Jie Liu

Conformational properties of a single flexible polyelectrolyte chain in a poor solvent are studied using constant temperature molecular dynamics simulation. The effects of counterions are explicitly taken in to account. Structural…

Statistical Mechanics · Physics 2012-12-04 Anoop Varghese , Satyavani Vemparala , R. Rajesh

The possibility to extract properties of an interface between two immiscible liquids, e.g., electrolyte solutions or polyelectrolyte multilayers, by means of impedance spectroscopy is investigated theoretically within a dynamic density…

Soft Condensed Matter · Physics 2013-11-22 Andreas Reindl , Markus Bier

We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the…

Soft Condensed Matter · Physics 2016-10-05 Sidney J. de Carvalho , Ralf Metzler , Andrey G. Cherstvy

The Poisson-Boltzmann (PB) equation provides a mean-field theory of electrolyte solutions at interfaces and in confinement, describing how ions reorganize close to charged surfaces to form the so-called electrical double layer (EDL), with…

Soft Condensed Matter · Physics 2024-09-10 Cecilia Herrero , Laurent Joly

We study the adsorption-desorption of fluid molecules on a solid substrate by introducing a schematic model in which the adsorption/desorption transition probabilities are given by irreversible kinetic constraints with a tunable violation…

Statistical Mechanics · Physics 2019-11-27 Mauro Sellitto

Bloch equations give a quantum description of the coupling between an atom and a driving electric force. In this article, we address the asymptotics of these equations for high frequency electric fields, in a weakly coupled regime. We prove…

Analysis of PDEs · Mathematics 2007-05-23 Brigitte Bidegaray-Fesquet , Francois Castella , Eric Dumas , Marguerite Gisclon

The present work is devoted to the simulation of a strongly magnetized plasma considered as a mixture of an ion fluid and an electron fluid. For the sake of simplicity, we assume that the model is isothermal and described by Euler equations…

Mathematical Physics · Physics 2014-04-08 Stéphane Brull , Pierre Degond , Fabrice Deluzet , Alexandre Mouton

Attosecond pulses can ionize atoms in a coherent process. Since the emerging fragments are entangled, however, each preserves only a fraction of the initial coherence, thus limiting the chance of guiding the ion subsequent evolution. In…

Atomic Physics · Physics 2021-06-30 Saad Mehmood , Eva Lindroth , Luca Argenti

In this paper we propose a nonlinear elasticity model of macromolecular conformational change (deformation) induced by electrostatic forces generated by an implicit solvation model. The Poisson-Boltzmann equation for the electrostatic…

Analysis of PDEs · Mathematics 2010-01-12 Yongcheng Zhou , Michael Holst , James Andrew McCammon

Non-equilibrium molecular dynamics simulations are used to demonstrate the asymptotic convergence of the Transient and Steady State forms of the Fluctuation Theorem. In the case of planar Poiseuille flow, we find that the Transient form,…

Statistical Mechanics · Physics 2015-06-25 Gary Ayton , Denis J. Evans
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