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The problem of charged polymer chains (polyelectrolytes) as they adsorb on a planar surface is addressed theoretically. We review the basic mechanisms and theory underlying polyelectrolyte adsorption on a single surface in two situations:…

Soft Condensed Matter · Physics 2012-01-31 David Andelman , Jean-Francois Joanny

The ability of metallic nanoparticles to supply heat to a liquid environment under exposure to an external optical field has attracted growing interest for biomedical applications. Controlling the thermal transport properties at a…

Chemical Physics · Physics 2017-08-14 Shenghong Ju , Bruno Palpant , Yann Chalopin

Contact electrification, or tribocharging, is pertinent to a broad range of industrial and natural processes involving dielectric materials. However, the basic mechanism by which charge is transferred between insulators is still unclear.…

Applied Physics · Physics 2019-08-21 Isaac A. Harris , Melody X. Lim , Heinrich M. Jaeger

The properties of surfaces with charge-regulated patches are studied using non-linear Poisson-Boltzmann theory. Using a mode expansion to solve the non-linear problem efficiently, we reveal the charging behaviour of Debye-length sized…

Soft Condensed Matter · Physics 2015-05-20 Niels Boon , René van Roij

Graphene-based electric power generation that converts mechanical energy of flow of ionic droplets over the device surface into electricity has emerged as promising candidate for a blue-energy network. Yet the lack of a microscopic…

Equal volume mixtures of small and large polytetrafluorethylene (PTFE) spheres are shaken in an atmosphere of controlled humidity which allows to also control their tribo-charging. We find that the contact numbers are charge-dependent: as…

Soft Condensed Matter · Physics 2017-06-21 Andre Schella , Simon Weis , Matthias Schroeter

We theoretically investigate electrostatic properties between two charged surfaces with a grafted polyelectrolyte layer in an aqueous electrolyte solution by using the Poisson-Boltzmann approach accounting for ion partitioning. In order to…

Soft Condensed Matter · Physics 2022-02-07 Jun-Sik Sin

Individual colloids often carry a charge as a result of the dissociation (or adsorption) of weakly-ionized surface groups. The magnitude depends on the precise chemical environment surrounding a particle, which in a concentrated dispersion…

Soft Condensed Matter · Physics 2017-12-12 James Hallett , David Gillespie , Robert Richardson , Paul Bartlett

We show that an electro-osmotic flow near the slippery hydrophobic surface depends strongly on the mobility of surface charges, which are balanced by counter-ions of the electrostatic diffuse layer. For a hydrophobic surface with immobile…

Fluid Dynamics · Physics 2015-04-03 S. R. Maduar , A. V. Belyaev , V. Lobaskin , O. I. Vinogradova

Surfaces are able to control physical-chemical processes in multi-component solution systems and, as such, find application in a wide range of technological devices. Understanding the structure, dynamics and thermodynamics of non-ideal…

Soft Condensed Matter · Physics 2023-09-29 Aaron R. Finney , Matteo Salvalaglio

We show that the work function of exfoliated single layer graphene can be modified by irradiation with swift (E_{kin}=92 MeV) heavy ions under glancing angles of incidence. Upon ion impact individual surface tracks are created in graphene…

Materials Science · Physics 2015-06-12 O. Ochedowski , B. Kleine Bussmann , B. Ban d'Etat , H. Lebius , M. Schleberger

The ability to induce regions of high and low ionic concentration adjacent to a permeselective membrane or nanochannel subject to an externally applied electric field (a phenomenon termed concentration-polarization) has been used for a…

Fluid Dynamics · Physics 2018-03-12 Sinwook Park , Gilad Yossifon

Recent work investigated graphene's hydrogenation with independent control of the electric field, E, and charge density, n, in the crystal and showed that the process is controlled by n. Here, we demonstrate layer-selective…

The optimal functioning of nanopore-based biosensing tools necessitates rapid polymer capture from the ion reservoir. We identify an ionic correlation-induced transport mechanism that provides this condition without the chemical…

Soft Condensed Matter · Physics 2018-05-10 Sahin Buyukdagli

The interaction between two adjacent charged surfaces immersed in aqueous solution is known to be affected by charge regulation - the modulation of surface charge as two charged surfaces approach each other. This phenomenon is particularly…

Soft Condensed Matter · Physics 2022-07-26 Tal Obstbaum , Uri Sivan

Gas-phase microdroplets have recently demonstrated exceptional chemical properties via suspected mechanisms such as contact electrification and surface charge pinning, producing high surface electric fields. Here, microdroplets are injected…

While important for many industrial applications, chemical reactions responsible for charging of solids in water are often poorly understood. We theoretically investigate the charging kinetics of solid-liquid interfaces, and find that the…

Soft Condensed Matter · Physics 2023-02-08 Willem Boon , Marjolein Dijkstra , René van Roij

A plethora of studies ranging from precision physics to quantum information employ ions, highly excited neutral atoms or polar molecules as tools. Motivated by the need for miniaturization, scalability and controllability, the particles are…

Instrumentation and Detectors · Physics 2025-03-26 M. T. Ziemba , J. Phrompao , F. Jung , I. M. Rabey , G. Rempe

We demonstrate droplet manipulation using electric signals to induce the liquid to wet or dewet on a hydrophilic conductive substrate in the air without adding layers. In this phenomenon, the contact angle changes more than 15{\deg} or…

Fluid Dynamics · Physics 2023-03-07 Lele Zhou , Rong Zhang , Hung-Ta Wang , Yifan Liu

The structure of dilute electrolyte solutions close to a surface carrying a spatially inhomogeneous surface charge distribution is investigated by means of classical density functional theory (DFT) within the approach of fundamental measure…

Soft Condensed Matter · Physics 2020-06-23 Maximilian Mußotter , Markus Bier , S. Dietrich