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We propose a new method to obtain kinetic properties of infrequent events from molecular dynamics simulation. The procedure employs a recently introduced variational approach [Valsson and Parrinello, Phys. Rev. Lett. 113, 090601 (2014)] to…

Statistical Mechanics · Physics 2015-08-19 James McCarty , Omar Valsson , Pratyush Tiwary , Michele Parrinello

Rare events such as nucleation processes are of ubiquitous importance in real systems. The most popular method for nonequilibrium systems, forward flux sampling (FFS), samples rare events by using interfaces to partition the whole…

Methodology · Statistics 2013-11-22 Huijun Jiang , Mingfeng Pu , Zhonghuai Hou

Generative models, particularly Diffusion Models (DM), have shown strong potential for Computed Tomography (CT) reconstruction serving as expressive priors for solving ill-posed inverse problems. However, diffusion-based reconstruction…

Image and Video Processing · Electrical Eng. & Systems 2026-03-03 Jiayang Shi , Lincen Yang , Zhong Li , Tristan Van Leeuwen , Daniel M. Pelt , K. Joost Batenburg

Diffusion and flow matching (FM) models have achieved remarkable progress in speech enhancement (SE), yet their dependence on multi-step generation is computationally expensive and vulnerable to discretization errors. Recent advances in…

Sound · Computer Science 2025-09-23 Gang Yang , Yue Lei , Wenxin Tai , Jin Wu , Jia Chen , Ting Zhong , Fan Zhou

To minimize the sediment flowing to the outlet of a river catchment with minimal effort or cost, it is important to select the best areas to perform a certain intervention, e.g., afforestation. CAMF (Cellular Automata based heuristic for…

Computational Engineering, Finance, and Science · Computer Science 2022-02-24 Grethell Castillo-Reyes , René Estrella , Karen Gabriels , Jos Van Orshoven , Floris Abrams , Dirk Roose

We address the problem of constructing accurate mathematical models of the dynamics of complex systems projected on a collective variable. To this aim we introduce a conceptually simple yet effective algorithm for estimating the parameters…

Statistical Mechanics · Physics 2022-09-28 Karen Palacio-Rodriguez , Fabio Pietrucci

Molecular dynamics (MD) simulations are useful in obtaining thermodynamic and kinetic properties of bio-molecules but are limited by the timescale barrier, i.e., we may be unable to efficiently obtain properties because we need to run…

Chemical Physics · Physics 2017-08-23 Surl-Hee Ahn , Jay W. Grate , Eric F. Darve

Studies in atomic-scale modeling of surface phase equilibria often focus on temperatures near zero Kelvin due to the challenges in calculating the free energy of surfaces at finite temperatures. The Bayesian-inference-based nested sampling…

Materials Science · Physics 2024-04-23 Mingrui Yang , Livia B. Pártay , Robert B. Wexler

Flow matching (FM) is increasingly used in scientific domains for time series generation and forecasting, where data often arise from underlying dynamical systems. However, it is not well-understood whether it learns transferable dynamical…

Machine Learning · Statistics 2026-05-08 Soon Hoe Lim , Shizheng Lin , Michael W. Mahoney , N. Benjamin Erichson

We present an approach that extends the theory of targeted free energy perturbation (TFEP) to calculate free energy differences and free energy surfaces at an accurate quantum mechanical level of theory from a cheaper reference potential.…

Computational Physics · Physics 2021-11-15 Andrea Rizzi , Paolo Carloni , Michele Parrinello

Collective variable (CV) or order parameter based enhanced sampling algorithms have achieved great success due to their ability to efficiently explore the rough potential energy landscapes of complex systems. However, the degeneracy of…

Chemical Physics · Physics 2018-07-11 Jing Zhang , Ming Chen

A method to improve l1 performance of the CS (Compressive Sampling) for A-scan SFCW-GPR (Stepped Frequency Continuous Wave-Ground Penetrating Radar) signals with known spectral energy density is proposed. Instead of random sampling, the…

Information Theory · Computer Science 2013-11-05 Andriyan Bayu Suksmono

We study the problem of finding efficient sampling policies in an edge-based feedback system, where sensor samples are offloaded to a back-end server that processes them and generates feedback to a user. Sampling the system at maximum…

Information Theory · Computer Science 2023-02-07 Vishnu Narayanan Moothedath , Jaya Prakash Champati , James Gross

A new methodology based on energy flux similarity is suggested in this paper for large eddy simulation (LES) of transitional and turbulent flows. Existing knowledge reveals that the energy cascade generally exists in transitional and…

Fluid Dynamics · Physics 2019-10-31 Han Qi , Xinliang Li , Hao Zhou , Changping Yu

We propose a unified, few-step generative modeling framework based on \emph{cumulative flow maps} for long-range transport in probability space, inspired by flow-map techniques for physical transport and dynamics. At its core is a…

Machine Learning · Computer Science 2026-05-06 Zhiqi Li , Duowen Chen , Yuchen Sun , Bo Zhu

Stochastic electronic structure theories, e.g., Quantum Monte Carlo methods, enable highly accurate total energy calculations which in principle can be used to construct highly accurate potential energy surfaces. However, their stochastic…

In this thesis we examine methodologies for determining free energy differences (FEDs) of phases via Monte Carlo simulation. We identify and address three generic issues that arise in FED calculations; the choice of representation, the…

Statistical Mechanics · Physics 2009-09-29 Arjun R. Acharya

Enhanced sampling techniques such as umbrella sampling and metadynamics are now routinely used to provide information on how the thermodynamic potential, or free energy, depends on a small number of collective variables. The free energy…

Computational Physics · Physics 2018-08-31 Ilaria Gimondi , Gareth A. Tribello , Matteo Salvalaglio

Training-free conditional generation based on flow matching aims to leverage pre-trained unconditional flow matching models to perform conditional generation without retraining. Recently, a successful training-free conditional generation…

Computer Vision and Pattern Recognition · Computer Science 2025-08-12 Kaiyu Song , Hanjiang Lai , Yan Pan , Kun Yue , Jian yin

Many biological processes occur on time scales longer than those accessible to molecular dynamics simulations. Identifying collective variables (CVs) and introducing an external potential to accelerate them is a popular approach to address…

Computational Physics · Physics 2024-10-24 Enrico Trizio , Andrea Rizzi , Pablo M. Piaggi , Michele Invernizzi , Luigi Bonati
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