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We show how crystalline inversion symmetry can be dynamically broken by optical phonons with generic, hardening Kerr-like non-linearities. The symmetry-broken state is reached through a parametric instability that can be accessed by driving…

Mesoscale and Nanoscale Physics · Physics 2026-03-23 Egor I. Kiselev

Anharmonic lattice vibrations play a key role in many physical phenomena. They govern the heat conductivity of solids, strongly affect the phonon spectra, play a prominent role in soft mode phase transitions, allow ultrafast engineering of…

Materials Science · Physics 2026-02-12 Gili Scharf , Tomer Hasharoni , Lara Donval , Leah Ben Gur , Alon Ron

Second harmonic generation is a powerful tool directly connected to the symmetry of materials. Phase transitions, lattice rotations or electromagnetic coupling in multiferroic compounds can be revealed by using second harmonic…

Optics · Physics 2010-01-11 Pablo Molina , Mariola O Ramirez , Basilio J. Garcia , Luisa E. Bausa

Selective excitation of coherent high-amplitude vibrations of atoms in a solid can induce exotic nonequilibrium states, in which the character of interactions between electronic, magnetic and lattice degrees of freedom is considerably…

Materials Science · Physics 2020-12-08 A. A. Melnikov , Yu. G. Selivanov , S. V. Chekalin

We explore a novel coupling mechanism of electrons with the transverse optical (TO) phonon branch in a regime when the TO mode becomes highly anharmonic and drives the ferroelectric phase transition. We show that this anharmonicity, which…

Strongly Correlated Electrons · Physics 2020-03-04 P. Chudzinski

We study the variations of electron-phonon coupling and their spectroscopic consequences in response to sliding of two layers in bilayer graphene using first-principles calculations and a model Hamiltonian. Our study shows that the long…

Mesoscale and Nanoscale Physics · Physics 2013-07-25 Seon-Myeong Choi , Seung-Hoon Jhi , Young-Woo Son

Beyond the constraints of conservative systems, altering wave propagation frequency emerges as a crucial factor across diverse physical domains. This Letter demonstrates bi-directional asymmetric frequency conversion -- either upward or…

Applied Physics · Physics 2024-08-20 Yeongtae Jang , Beomseok Oh , Eunho Kim , Junsuk Rho

Ferroelastic twin walls in centrosymmetric perovskites can host emergent polar and magnetic properties forbidden in the bulk. We use density functional theory calculations to study the geometry and magnetic properties of ferroelastic domain…

Materials Science · Physics 2025-11-18 Ida C. Skogvoll , Benjamin A. D. Williamson , Sverre M. Selbach

We describe an ultrafast coherent control of the transient structural distortion arising from nonlinear phononics in ErFeO$_3$. Using density functional theory, we calculate the structural properties as input to an anharmonic phonon model…

Materials Science · Physics 2017-02-08 Dominik Maximilian Juraschek , Michael Fechner , Nicola Ann Spaldin

Significantly enhanced second order nonlinearity resulting from local symmetry breaking in domain walls is reported. By this new giant nonlinearity, novel hexagonally, conically and trigonally distributed second harmonic beams closely…

Optics · Physics 2010-05-18 Xuewei Deng , Huaijin Ren , Yuanlin Zheng , Kun Liu , Xianfeng Chen

Spin-phonon coupling enables the mutual manipulation of phonon and spin degrees of freedom in solids. In this study, we reveal the inherent nonlinearity within this coupling. Using a paramagnet as an illustration, we demonstrate the…

Mesoscale and Nanoscale Physics · Physics 2024-04-16 Yafei Ren , Mark Rudner , Di Xiao

Ferroelectric domain walls, recognized as distinct from the bulk in terms of symmetry, structure, and electronic properties, host exotic phenomena including conductive walls, ferroelectric vortices, novel topologies, and negative…

Extensive inelastic neutron scattering measurements of phonons on a single crystal of CaFe2As2 allowed us to establish a fairly complete picture of phonon dispersions in the main symmetry directions. The phonon spectra were also calculated…

Local positional disorder in soft, anharmonic materials has emerged as a central factor in shaping their electronic, vibrational, optical, and transport properties. Viewed mainly as a source of performance degradation, recent theoretical…

Materials Science · Physics 2025-10-24 Marios Zacharias , Jacky Even

Phonon-phonon anharmonic effects have a strong influence on the phonon spectrum; most prominent manifestation of these effects are the softening (shift in frequency) and broadening (change in FWHM) of the phonon modes at finite temperature.…

The periodically poled ferroelectric wafer is a two-dimensional phononic superlattice. The important applications of such a solid include novel ultrasonic transducers at the micro/nano-scale for low intensity ultra-sonography, ferroelectric…

Mesoscale and Nanoscale Physics · Physics 2012-05-17 Igor Ostrovskii , Lucien Cremaldi

Time-resolved Raman spectroscopy has been applied to probe the anharmonic coupling and electron-phonon interaction of optical phonons in graphite. From the decay of the transient anti-Stokes scattering of the G-mode following ultrafast…

Materials Science · Physics 2015-05-14 Hugen Yan , Daohua Song

Domain-wall dynamics in ferroelectric materials are strongly position-dependent since each polar interface is locked into a unique local microstructure. This necessitates spatially resolved studies of the wall-pinning using scanning-probe…

Materials Science · Physics 2025-06-02 Kamyar Barakati , Yu Liu , Hiroshi Funakubo , Sergei V. Kalinin

The symmetry of boundaries between ferroelectric, ferroelastic and antiphase domains is a key element for a theoretical understanding of their properties. Here, we derive this symmetry from their organic relation to the symmetry of the…

Materials Science · Physics 2014-04-21 Pierre Tolédano , Mael Guennou , Jens Kreisel

Ferroic materials are well known to exhibit heterogeneity in the form of domain walls. Understanding the properties of these boundaries is crucial for controlling functionality with external stimuli and for realizing their potential for…

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