Related papers: A Thermodynamic Analysis of Enhanced Metastability…
Simple classical thermodynamic approach to the general description of metastable states is presented. It makes possible to calculate the explicit dependence of the Gibbs free energy on temperature, to calculate the heat capacity, the…
When liquids are cooled sufficiently rapidly below their melting temperature, they may bypass crystalization and, instead, enter a long-lived metastable supercooled state that has long been the focus of intense research. Although they…
We examine the stability of an Einstein-Maxwell perfect fluid configuration with a privileged direction of symmetry by means of a $1+1+2$-tetrad formalism. We use this formalism to cast, in a quasi linear symmetric hyperbolic form the…
We apply microcanonical ensemble considerations to suggest that, whenever it may thermalize, a general disorder-free many-body Hamiltonian of a typical atomic system has solid-like eigenstates at low energies and fluid-type (and gaseous,…
We formulate a microscopic, no adjustable parameter, theory of activated relaxation in supercooled liquids directly in terms of the repulsive and attractive forces within the framework of pair correlations. Under isochoric conditions,…
Mixing and heat transfer rates are typically enhanced when operating at high-pressure transcritical turbulent flow regimes. The rapid variation of thermophysical properties in the vicinity of the pseudo-boiling region can be leveraged to…
We propose a system of conservation laws with relaxation source terms (i.e. balance laws) for non-isothermal viscoelastic flows of Maxwell fluids. The system is an extension of the polyconvex elastodynamics of hyperelastic bodies using…
For 1D Hamiltonian systems with periodic solutions, Helmholtz formalism provides a tantalizing interpretation of classical thermodynamics, based on time integrals of purely mechanical quantities and without need of statistical description.…
We show that two-dimensional systems of deformable particles undergo a continuous liquid-hexatic transition upon compression or cooling, but no hexatic-solid transition-even at zero temperature and high density. Numerical simulations reveal…
Thermodynamical stability of fluid spheres is studied in the presence of a cosmological constant, both in the Newtonian limit, as well as in General Relativity. In all cases, an increase of the cosmological constant tends to stabilize the…
The search for thermodynamic admissibility moreover reveals a fundamental difference between liquids and gases in relativistic fluid dynamics, as the reversible convection mechanism is much simpler for liquids than for gases. In…
In this paper, we consider mathematical modeling and numerical simulation of non-isothermal compressible multi-component diffuse-interface two-phase flows with realistic equations of state. A general model with general reference velocity is…
The local equilibrium thermodynamics is a basic assumption of macroscopic descriptions of the out of equilibrium dynamics for Hamiltonian systems. We numerically analyze the Hamiltonian Potts model in two dimensions to study the violation…
Phase stability, and the limits thereof, are a central concern of materials thermodynamics. However, the temperature limits of equilibrium liquid stability in chemical systems have only been widely characterized under constant (typically…
We study a gas of $N$ hard disks in a box with semi-periodic boundary conditions. The unperturbed gas is hyperbolic and ergodic (these facts are proved for N=2 and expected to be true for all $N\geq 2$). We study various perturbations by…
In this paper, we study the thermo-elastodynamics of nonlinearly viscous solids in the Kelvin-Voigt rheology where both the elastic and the viscous stress tensors comply with the frame-indifference principle. The system features a force…
The description of molecular motion by macroscopic hydrodynamics has a long and continuing history. The Stokes-Einstein relation between the diffusion coefficient of a solute and the solvent viscosity predicted using macroscopic continuum…
The efficacy of cryopreservation is constrained by the difficulty of achieving sufficiently high intracellular concentrations of cryoprotective solutes without inducing osmotic injury or chemical toxicity during loading. This thermodynamic…
This paper is devoted to study the phase space analysis of isotropic and homogenous universe model by taking a noninteracting mixture of electromagnetic and viscous radiating fluids whose viscous pressure satisfies a nonlinear version of…
The isothermal compression of a dilute nucleonic gas invoking cluster degrees of freedom is studied in an equilibrium statistical model; this clusterized system is found to be more stable than the pure nucleonic system. The equation of…