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We propose a method to solve the electronic Schr\"odinger equation for strongly correlated systems by applying a unitary transformation to reduce the complexity of the physical Hamiltonian. In particular, we seek a transformation that maps…

Chemical Physics · Physics 2026-04-14 Daniel F. Calero-Osorio , Paul W. Ayers

We show how to add the effects of residual electron correlation to a reference seniority-zero wavefunction by making a unitary transformation of the true electronic Hamiltonian into seniority-zero form. The transformation is treated via the…

Chemical Physics · Physics 2026-04-14 Daniel F. Calero-Osorio , Paul W. Ayers

We investigate two methods of constructing a solution of the Schr\"{o}dinger equation from the canonical transformation in classical mechanics. One method shows that we can formulate the solution of the Schr\"{o}dinger equation from linear…

Quantum Physics · Physics 2007-05-23 Akihiro Ogura , Motoo Sekiguchi

Recent breakthroughs have opened the possibility to intermediate-scale quantum computing with tens to hundreds of qubits, and shown the potential for solving classical challenging problems, such as in chemistry and condensed matter physics.…

Quantum Physics · Physics 2025-10-30 Zhong-Xia Shang , Ming-Cheng Chen , Xiao Yuan , Chao-Yang Lu , Jian-Wei Pan

We develop a modified semi-classical approach to the approximate solution of Schrodinger's equation for certain nonlinear quantum oscillations problems. At lowest order, the Hamilton-Jacobi equation of the conventional semi-classical…

Mathematical Physics · Physics 2015-06-03 Vincent Moncrief , Antonella Marini , Rachel Maitra

A novel canonical transformation is offered as the mean for studying properties of a system of strongly correlated electrons. As an example of the utility of the transformation, it is used to demonstrate the existence of a quantum phase…

Strongly Correlated Electrons · Physics 2014-04-23 Valentin Voroshilov

We propose a method for obtaining effective classical Hamiltonians \cal H for many-body quantum spin systems with large spins. This method uses the coherent-state representation of the partition function Z and the cumulant expansion in…

Statistical Mechanics · Physics 2009-10-31 D. A. Garanin , K. Kladko , P. Fulde

Quantum simulations of electronic structure with a transformed Hamiltonian that includes some electron correlation effects are demonstrated. The transcorrelated Hamiltonian used in this work is efficiently constructed classically, at…

Application of current and near-term quantum hardware to the electronic structure problem is highly limited by qubit counts, coherence times, and gate fidelities. To address these restrictions within the variational quantum eigensolver…

Quantum Physics · Physics 2020-11-24 Robert A. Lang , Ilya G. Ryabinkin , Artur F. Izmaylov

Hybrid classical-quantum algorithms aim at variationally solving optimisation problems, using a feedback loop between a classical computer and a quantum co-processor, while benefitting from quantum resources. Here we present experiments…

The numerical version of the Hamilton-Jacobi quantization method, recently proposed, is applied to the one dimensional quartic oscillator. A suitable quantization condition is formulated and various energy levels and wave functions are…

Quantum Physics · Physics 2017-11-28 Mario Fusco Girard

The Schrieffer-Wolff transformation aims to solve degenerate perturbation problems and give an effective Hamiltonian that describes the low-energy dynamics of the exact Hamiltonian in the low-energy subspace of unperturbed Hamiltonian. This…

Quantum Physics · Physics 2022-10-13 Zongkang Zhang , Yongdan Yang , Xiaosi Xu , Ying Li

Hamiltonian simulation is a central task in quantum computing, with wide-ranging applications in quantum chemistry, condensed matter physics, and combinatorial optimization. A fundamental challenge lies in approximating the unitary…

Quantum Physics · Physics 2025-05-15 Molena Nguyen , Naihuan Jing

A numerical method for solving Schrodinger's equation based upon a Baker-Campbell-Hausdorff (BCH) expansion of the time evolution operator is presented herein. The technique manifestly preserves wavefunction norm, and it can be applied to…

Quantum Physics · Physics 2007-05-23 Peter Cho , Karl Berggren

We study a class of SYK-type models in large N limit from the gravity dual side in terms of Schwarzian action analytically. The quantum correction to two point correlation function due to the Schwarzian action produces transfer of degree of…

High Energy Physics - Theory · Physics 2019-03-13 Yong-Hui Qi , Yunseok Seo , Sang-Jin Sin , Geunho Song

Deriving quantum error correction and quantum control from the Schrodinger equation for a unified qubit-environment Hamiltonian will give insights into how microscopic degrees of freedom affect the capability to control and correct quantum…

Quantum Physics · Physics 2021-05-21 Donghyun Jin , Grihith Manchanda , Dragomir Davidovic

The Cornwall-Jackiw-Tomboulis (CJT) effective action for composite operators at finite temperature is used to investigate the chiral phase transition within the framework of the linear sigma model as the low-energy effective model of…

High Energy Physics - Phenomenology · Physics 2009-11-10 Tran Huu Phat , Nguyen Tuan Anh , Le Viet Hoa

We introduce a quantum information theory-inspired method to improve the characterization of many-body Hamiltonians on near-term quantum devices. We design a new class of similarity transformations that, when applied as a preprocessing…

Quantum Physics · Physics 2024-07-24 Andi Gu , Hong-Ye Hu , Di Luo , Taylor L. Patti , Nicholas C. Rubin , Susanne F. Yelin

This report discusses two new ideas for using perturbation methods to solve the time-independent Schr\"odinger equation. The first concept begins with rewriting the perturbation equations in a form that is closely related to matrix…

Quantum Physics · Physics 2013-10-25 Gerald I. Kerley

The quantum mechanical version of the four kinds of classical canonical transformations is investigated by using non-hermitian operator techniques. To help understand the usefulness of this appoach the eigenvalue problem of a harmonic…

High Energy Physics - Theory · Physics 2009-10-28 Haewon Lee , W. S. l'Yi
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