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Exchange hole is the principle constituent in density functional theory, which can be used to accurately design exchange energy functional and range separated hybrid functionals coupled with some appropriate correlation. Recently, density…

Materials Science · Physics 2017-09-14 Bikash Patra , Subrata Jana , Prasanjit Samal

We present a new adaptive method for electronic structure calculations based on novel fast algorithms for reduction of multivariate mixtures. In our calculations, spatial orbitals are maintained as Gaussian mixtures whose terms are selected…

Numerical Analysis · Mathematics 2019-06-19 Gregory Beylkin , Lucas Monzon , Xinshuo Yang

Exact exchange contributions are known to crucially affect electronic states, which in turn govern covalent bond formation and breaking in chemical species. Empirically averaging the exact exchange admixture over compositional degrees of…

The applicability of a broken symmetry version of the $G_0W_0$ approximation to the calculation of isotropic exchange coupling constants has been studied. Using a simple H--He--H model system the results show a significant and consistent…

Strongly Correlated Electrons · Physics 2020-03-16 Akseli Mansikkamäki , Zhishou Huang , Naoya Iwahara , Liviu F. Chibotaru

We present an implementation of range separated functionals utilizing the Slater-function on grids in real space in the projector augmented waves method. The screened Poisson equation is solved to evaluate the necessary screened exchange…

Computational Physics · Physics 2018-07-11 Rolf Würdemann , Michael Walter

Electronic structure calculations based on Density Functional Theory have successfully predicted numerous ground state properties of a variety of molecules and materials. However, exchange and correlation functionals currently used in the…

Materials Science · Physics 2023-08-09 Jiawei Zhan , Marco Govoni , Giulia Galli

Exact (Hartree Fock) exchange is needed to overcome some of the limitations of local and semilocal approximations of density functional theory (DFT). So far, however, computational cost has limited the use of exact exchange in plane wave…

Strongly Correlated Electrons · Physics 2009-11-13 Xifan Wu , Annabella Selloni , Roberto Car

We demonstrate the accuracy of the hybrid functional HSE06 for computing band offsets of semiconductor alloy heterostructures. The highlight of this study is the computation of conduction band offsets with a reliability that has eluded…

Materials Science · Physics 2015-05-19 Amita Wadehra , Jeremy W. Nicklas , John W. Wilkins

The optimized effective potential (OEP) approach has so far mainly been used in benchmark studies and for the evaluation of band gaps. In this work, we extend the application of the OEP by determining the analytical ionic forces within the…

Materials Science · Physics 2024-09-13 Damian Contant , Maria Hellgren

A practical electronic structure method in which a two-body functional is the fundamental variable is constructed. The basic formalism of our method is equivalent to Hartree-Fock density matrix functional theory [M. Levy in {\it Density…

Other Condensed Matter · Physics 2008-04-23 Balazs Hetenyi , Andreas W. Hauser

We perform systematic density functional theory (DFT) calculations to assess the performance of various exchange-correlation potentials $V_{xc}$ in describing the chalcogenide GaM$_4$Q$_8$ lacunar spinels (M=Mo, V, Nb, Ta; Q=S, Se). We…

Materials Science · Physics 2019-09-25 Yiqun Wang , Danilo Puggioni , James M. Rondinelli

A recently proposed approach for performing electronic-structure calculations on crystalline insulators in terms of localized orthogonal orbitals is applied to the oxides of lithium and sodium, Li2O and Na2O. Cohesive energies, lattice…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

The electronic exchange-correlation (XC) kernel constitutes a fundamental input for the estimation of a gamut of material properties such as the dielectric characteristics, the thermal and electrical conductivity, or the response to an…

Computational Physics · Physics 2024-02-26 Zhandos A. Moldabekov , Maximilian Böhme , Jan Vorberger , David Blaschke , Tobias Dornheim

With the advent of 5G and the need for energy-efficient massively connected wireless networks, in this work, we consider an energy harvesting (EH) based multi-relay downlink cooperative non-orthogonal multiple access (NOMA) system with…

Signal Processing · Electrical Eng. & Systems 2021-12-22 Shubham Bisen , Parvez Shaik , Vimal Bhatia

Warm dense matter is a highly active research area both at the frontier and interface of material science and plasma physics. We assess the performance of commonly used exchange-correlation (XC) approximation (LDA, PBE, PBEsol, and AM05) in…

Plasma Physics · Physics 2022-01-25 Zhandos Moldabekov , Tobias Dornheim , Jan Vorberger , Attila Cangi

In this talk, I present the brand new results from the H1 and ZEUS Collaborations on the combination of all previously published inclusive deep inelastic cross sections at HERA for neutral and charged current $e^\pm p$ scattering for zero…

High Energy Physics - Experiment · Physics 2015-11-18 Zhiqing Zhang

In this work, we develop a mathematical framework for a Selected Configuration Interaction (SCI) algorithm within a bi-orthogonal basis for transcorrelated (TC) calculations. The bi-orthogonal basis used here serves as the equivalent of the…

Chemical Physics · Physics 2023-06-22 Abdallah Ammar , Anthony Scemama , Emmanuel Giner

We use fully self-consistent GW calculations on diamond and silicon carbide to reparametrize the Heyd-Scuseria-Ernzerhof exact exchange density functional for use in band structure calculations of semiconductors and insulators. We show that…

Mesoscale and Nanoscale Physics · Physics 2015-08-05 V. Zólyomi , J. Kürti

Accurate prediction for the electronic structure properties of halide perovskites plays a significant role in the design of highly efficient and stable solar cells. While density functional theory (DFT) within the generalized gradient…

Chemical Physics · Physics 2023-06-27 Qi Ou , Ping Tuo , Wenfei Li , Xiaoxu Wang , Yixiao Chen , Linfeng Zhang

A recently developed density functional method, within Hohenberg-Kohn-Sham framework, is used for faithful description of atoms, molecules in Cartesian coordinate grid, by using an LCAO-MO ansatz. Classical Coulomb potential is obtained by…

Chemical Physics · Physics 2013-07-16 Amlan K. Roy