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Recently, Ryu et al. showed that two broadened bands connected by a set of four Einstein-coefficient spectra for stimulated and spontaneous single-photon transitions will obey detailed balance at equilibrium if the spectra satisfy…

Chemical Physics · Physics 2026-03-12 Jisu Ryu , David M. Jonas

We present Einstein coefficient spectra and a detailed-balance derivation of generalized Einstein relations between them that is based on the connection between spontaneous and stimulated emission. If two broadened levels or bands overlap…

Chemical Physics · Physics 2024-09-05 Jisu Ryu , Sarang Yeola , David M. Jonas

The method employed by Einstein to derive his famous relation between the diffusion coefficient and the friction coefficient of a Brownian particle is used to derive a generalized Einstein relation for the mutual diffusion coefficient of a…

Fluid Dynamics · Physics 2017-09-13 B. U. Felderhof

In this paper we present a quantum stochastic model for spectroscopic line-shapes in the presence of a co-evolving and non-stationary background population of excitations. Starting from a field theory description for interacting bosonic…

Chemical Physics · Physics 2020-10-27 Hao Li , Ajay Ram Srimath Kandada , Carlos Silva , Eric R. Bittner

Einstein's Brownian motion of a quantum particle in a classical environment is studied via virial and equipartition theorems. The effect of continuous measurement in a strongly dissipative environment is accounted for and a quantum…

Quantum Physics · Physics 2012-11-13 R. Tsekov

The validity of Einstein's fluctuation-dissipation relation is discussed in respect to the type of relaxation in an isothermal system. The first model, presuming isothermic fluctuations, leads to the Einstein formula. The second model…

Statistical Mechanics · Physics 2011-04-08 Roumen Tsekov

Based on the generalized Langevin equation for the momentum of a Brownian particle a generalized asymptotic Einstein relation is derived. It agrees with the well-known Einstein relation in the case of normal diffusion but continues to hold…

Soft Condensed Matter · Physics 2015-06-23 Hyun Kyung Shin , Bongsik Choi , Peter Talkner , Eok Kyun Lee

A formulation of Einstein equations is presented that could yield advantages in the study of collisions of binary compact objects during regimes between linear-nonlinear transitions. The key idea behind this formulation is a separation of…

General Relativity and Quantum Cosmology · Physics 2009-10-31 Pablo Laguna

A generalized Einstein relation is studied for Brownian motion in a tilted potential. The exact form of the diffusion constant of the Brownian motion is compared with the generalized Einstein relation. The generalized Einstein relation is a…

Statistical Mechanics · Physics 2015-06-25 Hidetsugu Sakaguchi

The semiconductor Bloch equations for a two-band model including inter- and intraband excitation are used to study the nonlinear absorption of single and multiple light pulses by direct-gap semiconductors. For a consistent analysis the…

Mesoscale and Nanoscale Physics · Physics 2019-03-13 W. -R. Hannes , T. Meier

The diffusion coefficient--a measure of dissipation, and the entropy--a measure of fluctuation are found to be intimately correlated in many physical systems. Unlike the fluctuation dissipation theorem in linear response theory, the…

Statistical Mechanics · Physics 2021-03-25 Yi Liao , Xiao-Bo Gong

We present a theory of electronic excitation energies and optical absorption spectra which incorporates energy-level renormalization and phonon-assisted optical absorption within a unified framework. Using time-independent perturbation…

Materials Science · Physics 2016-07-28 Christopher E. Patrick , Feliciano Giustino

Quantum stochastic differential equations have been used to describe the dynamics of an atom interacting with the electromagnetic field via absorption/emission processes. Here, by using the full quantum stochastic Schroedinger equation…

Quantum Physics · Physics 2009-10-31 Alberto Barchielli , Giancarlo Lupieri

With a decomposition scheme for the bath correlation function, the hierarchical equations of motion (HEOM) are extended to the zero-temperature sub-Ohmic and Ohmic spin-boson model. We investigate the linear absorption spectrum of the…

Quantum Physics · Physics 2023-02-06 Qianlong Wang , Jianlan Wu

We develop a general framework for response theory in diffusion processes governed by Fokker-Planck equations, based on the notion of the Dissipation Function. Using the analytically solvable Brownian oscillator model, we derive exact…

Statistical Mechanics · Physics 2025-07-25 Matteo Colangeli , Lamberto Rondoni , Pasquale Vozza

We present ab initio absorption spectra of six three-dimensional semiconductors and insulators calculated using Gaussian-based periodic equation-of-motion coupled-cluster theory with single and double excitations (EOM-CCSD). The spectra are…

Chemical Physics · Physics 2021-07-13 Xiao Wang , Timothy C. Berkelbach

We study many interacting Brownian particles under a tilted periodic potential. We numerically measure the linear response coefficient of the density field by applying a slowly varying potential transversal to the tilted direction. In…

Statistical Mechanics · Physics 2009-03-02 Takenobu Nakamura , Shin-ichi Sasa

Pressure broadening and pressure shift coefficients for 127I2 (diatomic iodine) in the presence of various buffer gases were determined respectively from the line-widths and line-center shifts observed in Doppler-limited, steady-state,…

Chemical Physics · Physics 2009-10-28 Erich N. Wolf

Einstein-Smoluchowski diffusion, damped harmonic oscillations, and spatial decoherence are special cases of an elegant class of Markovian quantum Brownian motion models that is invariant under linear symplectic transformations. Here we…

Quantum Physics · Physics 2016-02-04 C. Jess Riedel

A Brownian harmonic oscillator, which dissipates energy either by friction or via emission of electromagnetic radiation, is considered. This Brownian emitter is driven by the surrounding thermo-quantum fluctuations, which are theoretically…

Quantum Physics · Physics 2016-06-17 R. Tsekov
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