Related papers: Linking molecular timescales to linear viscoelasti…
The concept of a `persistent worm' is introduced, representing the smallest possible length of a wormlike micelle, and modelled by a bead-spring chain with sticky beads at the ends. Persistent worms are allowed to combine with each other at…
The linear viscoelastic response of flexible polymer solutions in the dilute and semidilute unentangled regimes is investigated using Brownian dynamics simulations. The relaxation modulus and dynamic moduli are computed over a wide range of…
We show the existence of three well defined time scales in the dynamics of wormlike micelles after a step between two shear rates on the stress plateau. These time scales are compatible with the presence of a structured interface between…
We present a reformulation of the 'reactive rod model' (RRM) of Dutta and Graham [Dutta, Sarit and Graham, Michael D., JNNFM 251 (2018)], a constitutive model for describing the behavior of dilute wormlike micelle solutions. The RRM treats…
We study the dynamics of a spherical steel ball falling freely through a solution of entangled wormlike-micelles. If the sphere diameter is larger than a threshold value, the settling velocity shows repeated short oscillatory bursts…
Wormlike micelles are self-assemblies of polymer chains that can break and recombine reversibly. In this paper, we derive a thermodynamically consistent two species micro-macro model of wormlike micellar solutions by employing an energetic…
Velocity profiles in a wormlike micelle solution (CTAB in D2O) are recorded using ultrasound every 2 s after a step-like shear rate into the shear-banding regime. The stress relaxation occurs over more than six hours and corresponds to the…
A mean-field kinetic model suggests that the relaxation dynamics of wormlike micellar networks is a long and complex process due to the problem of reducing the number of free end-caps (or dangling ends) while also reaching an equilibrium…
We review the experimental and theoretical results obtained during the past decade on the structure and rheology of wormlike micellar solutions. We focus on the linear and nonlinear viscoelasticity and emphasize the analogies with polymers.…
The dynamic response of prestressed semiflexible biopolymers is characterized by the propagation and relaxation of tension, which arises due to the near inextensibility of a stiff backbone. It is coupled to the dynamics of contour length…
The linear and non-linear dynamic response to an oscillatory shear flow of giant wormlike micelles consisting of Pb-Peo block copolymers is studied by means of Fourier transform rheology. Experiments are performed in the vicinity of the…
Microrheology experiments show that viscoelastic media composed by wormlike micellar networks display complex relaxations lasting seconds even at the scale of micrometers. By mapping a model of patchy colloids with suitable mesoscopic…
The behaviour of semi-dilute wormlike micelle solutions under vertical vibrations is investigated using classical measurements of the Faraday instability threshold along with two new experiments based on particle imaging velocimetry and…
We report the flow dynamics of two shear-banding wormlike micellar solutions with distinct surfactant chemistries in a Taylor-Couette (TC) setup following a startup shear. The solutions, formulated with CTAB/NaSal and CPyCl/NaSal, exhibit…
The motion of suspended colloidal particles generates fluid disturbances in the surrounding medium that create interparticle interactions. While such colloidal hydrodynamic interactions (HIs) have been extensively studied in viscous…
We present a tensor constitutive model for predicting stress and flow-induced structure formation in dilute wormlike micellar solutions. The micellar solution is treated as a dilute suspension of rigid Brownian rods whose length varies…
Amphiphilic block copolymers self-assemble into diverse nanoscale morphologies with significant implications for drug delivery. This work presents systematic Brownian dynamics simulations of multi-chain diblock and triblock copolymers…
The flow of viscoelastic wormlike micellar solutions (WLMs) in porous media is encountered in many practical applications like enhanced oil recovery or groundwater remediation. To understand the flow dynamics of these complex fluids in…
Wormlike micelle (WLM) solutions are abundant in energy, environmental, and industrial applications, which often rely on their flow through tortuous channels. How does the interplay between fluid rheology and channel geometry influence the…
Wormlike micelle solutions are submitted to small-amplitude oscillatory shear superimposed to steady shear in the shear banding regime. By imposing a shear oscillation, the interface between high- and low-shear regions oscillates in time. A…