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Polaritons, formed as a result of strong hybridization of matter with light, are promising for important applications including organic solar cells, optical logic gates, and qubits. Owing to large binding energies of Frenkel excitons…

Exciton-polaritons are mutually interacting quantum hybridizations of confined photons and electronic excitations. Here we demonstrate a system of optically guided, electrically polarized exciton-polaritons ('dipolaritons') that displays up…

Mesoscale and Nanoscale Physics · Physics 2018-04-18 Itamar Rosenberg , Dror Liran , Yotam Mazuz-Harpaz , Kenneth West , Loren Pfeiffer , Ronen Rapaport

We use the polarized Fock states to describe the coupled molecule-cavity hybrid system in quantum electrodynamics. The molecular permanent dipoles polarize the photon field by displacing its vector potential, leading to non-orthogonality…

Quantum Physics · Physics 2020-05-04 Arkajit Mandal , Sebastian Montillo Vega , Pengfei Huo

Nonadiabatic quantum interferences emerge whenever nuclear wavefunctions in different electronic states meet and interact in a nonadiabatic region. In this work, we analyze how nonadiabatic quantum interferences translate in the context of…

Chemical Physics · Physics 2016-08-03 Basile F. E. Curchod , Federica Agostini , E. K. U. Gross

It is widely assumed that photons cannot be manipulated using electric or magnetic fields. Even though hybridization of photons with electronic polarization to form exciton-polaritons has paved the way to a number of ground-breaking…

A lattice of trapped atoms strongly coupled to a one-dimensional nanophotonic waveguide is investigated in exploiting the concept of polariton as the system natural eigenstate. We apply a bosonization procedure, which was presented…

Quantum Physics · Physics 2014-04-22 Hashem Zoubi

The large number of degrees of freedom involved in polaritonic chemistry processes considerably restricts the systems that can be described by any ab initio approach, due to the resulting high computational cost. Semiclassical methods that…

Exposing a molecule to intense light pulses may bring this molecule to a nonstationary quantum state, thus launching correlated dynamics of electronic and nuclear subsystems. Although much had been achieved in the understanding of…

Chemical Physics · Physics 2024-04-11 Nikolay V. Golubev , Jiří Vaníček

Density functional theory is generalized to incorporate electron-phonon coupling. A Kohn-Sham equation yielding the electronic density $n_U(\mathbf{r})$, a conditional probability density depending parametrically on the phonon normal mode…

Materials Science · Physics 2019-04-25 Ryan Requist , C. R. Proetto , E. K. U. Gross

This study investigates the dynamic behavior of polaritons in an optical cavity containing one million molecules, emphasizing the influence of molecular rotation and level disorder on the coupling between molecules and photons. Through…

Optics · Physics 2024-02-22 Wei Liu , Jingqi Chen , Wenjie Dou

For certain correlated electron-photon systems we construct the exact density-to-potential maps, which are the basic ingredients of a density-functional reformulation of coupled matter-photon problems. We do so for numerically exactly…

Quantum Physics · Physics 2017-12-06 Tanja Dimitrov , Johannes Flick , Michael Ruggenthaler , Angel Rubio

We show that the combined effect of photon emission and Coulomb interactions may drive an exciton-polariton system towards a dynamical coherent state, even without phonon thermalization or any other relaxation mechanism. Exact…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Herbert Vinck-Posada , Boris A. Rodriguez , P. S. S. Guimaraes , Alejandro Cabo , Augusto Gonzalez

We present for the first time the nonlinear dynamics of quantum electrodynamic (QED) photon splitting in a strongly magnetized electron-positron (pair) plasma. By using a QED corrected Maxwell equation, we derive a set of equations that…

Astrophysics · Physics 2008-11-26 G. Brodin , M. Marklund , B. Eliasson , P. K. Shukla

Light-matter interaction not only plays an instrumental role in characterizing materials' properties via various spectroscopic techniques but also provides a general strategy to manipulate material properties via the design of novel…

Chemical Physics · Physics 2023-08-30 Braden M. Weight , Xinyang Li , Yu Zhang

The rapidly developing and converging fields of polaritonic chemistry and quantum optics necessitate a unified approach to predict strongly-correlated light-matter interactions with atomic-scale resolution. Combining concepts from both…

Quantum Physics · Physics 2018-09-19 Johannes Flick , Prineha Narang

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

Chemical Physics · Physics 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

We develop coupled-cluster theory for systems of electrons strongly coupled to photons, providing a promising theoretical tool in polaritonic chemistry with a perspective of application to all types of fermion-boson coupled systems. We show…

The concept of modifying molecular dynamics in strongly coupled exciton-polariton systems is an emerging topic in photonics due to its potential to produce customized chemical systems with tailored photophysical properties. However, before…

Materials Science · Physics 2020-10-09 Bin Liu , Vinod M. Menon , Matthew Y. Sfeir

We calculate the exact many-body time dynamics of polaritonic states supported by an optical cavity filled with organic molecules. Optical, vibrational and radiative processes are treated on an equal footing employing the Time-Dependent…

Mesoscale and Nanoscale Physics · Physics 2019-04-05 Javier del Pino , Florian A. Y. N. Schröder , Alex W. Chin , Johannes Feist , Francisco J. Garcia-Vidal

We present an exact single-electron picture that describes the correlated electron dynamics in strong laser fields. Our approach is based on the factorization of the electronic wavefunction as a product of a marginal and a conditional…

Chemical Physics · Physics 2017-04-26 Axel Schild , E. K. U. Gross