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A critical challenge for density functional theory (DFT) in practice is its limited ability to treat static electron correlation, leading to errors in its prediction of charges, multiradicals, and reaction barriers. Recently, we combined…

Chemical Physics · Physics 2024-11-05 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

We present a modification to our recently published SAFT-based classical density functional theory for water. We have recently developed and tested a functional for the averaged radial distribution function at contact of the hard-sphere…

Soft Condensed Matter · Physics 2015-06-17 Eric J. Krebs , Jeff B. Schulte , David Roundy

We investigate effects of optical lattice potential in one- and two-dimensional two-component trapped Fermi gases with population imbalances. Using the exact diagonalization and the density matrix renormalization group methods…

Strongly Correlated Electrons · Physics 2008-06-05 M. Machida , S. Yamada , M. Okumura , Y. Ohashi , H. Matsumoto

We study the dynamics of colloidal suspensions of hard spheres that are subject to Brownian motion in the overdamped limit. We obtain the time evolution of the self and distinct parts of the van Hove function by means of dynamical density…

Soft Condensed Matter · Physics 2018-01-16 Daniel Stopper , Kevin Marolt , Hendrik Hansen-Goos , Roland Roth

Two-point density-density correlation functions for the diffusive binary reaction system $A+A\to\emptyset$ are obtained in one dimension via Monte Carlo simulation. The long-time behavior of these correlation functions clearly deviates from…

Statistical Mechanics · Physics 2009-11-07 Su-Chan Park , Jeong-Man Park , Doochul Kim

The onset of condensation of hard spheres in a gravitational field is studied using density functional theory. In particular, we find that the local density approximation yields results identical to those obtained previously using the…

Statistical Mechanics · Physics 2009-11-07 Joseph A. Both , Daniel C. Hong

We start from the Bethe-Goldstone equation (BGE) to derive a simple orbital-dependent correlation functional -- BGE2 -- which terminates the BGE expansion at the second-order, but retains the self-consistent coupling of electron-pair…

Materials Science · Physics 2018-10-19 Igor Ying Zhang , Patrick Rinke , Matthias Scheffler

We investigate solutions of the 2d incompressible Euler equations, linearized around steady states which are radially decreasing vortices. Our main goal is to understand the smoothness of what we call the spectral density function…

Analysis of PDEs · Mathematics 2022-09-14 Alexandru D. Ionescu , Hao Jia

A fluid of hard right isosceles triangles was studied using an extension of Scaled-Particle Density-Functional Theory which includes the exact third virial coefficient. We show that the only orientationally ordered stable liquid-crystal…

Soft Condensed Matter · Physics 2021-12-10 Yuri Martinez-Raton , Enrique Velasco

Recent work on local functional theories of critical inhomogeneous fluids and Ising-like magnets has shown them to be a potentially exact, or near exact, description of universal finite-size effects associated with the excess free-energy…

Condensed Matter · Physics 2009-10-31 A. O. Parry , E. D. Macdonald , C. Rascon

Density-functional theory is applied to compute the ground-state energies of quantum hard-sphere solids. The modified weighted-density approximation is used to map both the Bose and the Fermi solid onto a corresponding uniform Bose liquid,…

Statistical Mechanics · Physics 2009-10-30 A. R. Denton , P. Nielaba , N. W. Ashcroft

We numerically study the jamming transition of frictionless polydisperse spheres in three dimensions. We use an efficient thermalisation algorithm for the equilibrium hard sphere fluid and generate amorphous jammed packings over a range of…

Statistical Mechanics · Physics 2017-10-16 Misaki Ozawa , Ludovic Berthier , Daniele Coslovich

Interfacial structure and correlation functions near a two-dimensional (2D) wedge filling transition are studied using effective interfacial Hamiltonian models. An exact solution for short range binding potentials and results for Kratzer…

Statistical Mechanics · Physics 2009-11-10 J. M. Romero-Enrique , A. O. Parry , M. J. Greenall

The construction of density-functional approximations is explored by modeling the adiabatic connection em locally, using energy densities defined in terms of the electrostatic potential of the exchange-correlation hole. These local models…

Chemical Physics · Physics 2016-05-04 Stefan Vuckovic , Tom Irons , Andreas Savin , Andrew M. Teale , Paola Gori-Giorgi

Condensates of active particles such as cells form almost-crystalline lattices which play a central role in many biological systems. Typically, their properties have been determined merely by analogy to the rather trivial one-dimensional…

Soft Condensed Matter · Physics 2025-12-02 Connor Roberts , Gunnar Pruessner

The organization of water molecules and ions between charged mineral surfaces determines the stability of colloidal suspensions and the strength of phase-separated particulate gels. In this article we assemble a density functional that…

Soft Condensed Matter · Physics 2024-05-15 Thomas Petersen

Two basic correlation functions are calculated for a model of $N$ harmonically interacting identical particles in a parabolic potential well. The density and the pair correlation function of the model are investigated for the boson case.…

Statistical Mechanics · Physics 2009-10-30 F. Brosens , J. T. Devreese , L. F. Lemmens

We propose microscopic density functional theory for inhomogeneous star polymers. Our approach is based on fundamental measure theory for hard spheres, and on Wertheim's first- and second-order perturbation theory for the interparticle…

Soft Condensed Matter · Physics 2007-05-23 A. Malijevsky , P. Bryk , S. Sokolowski

We consider an anisotropic version of Baxter's model of `sticky hard spheres', where a nonuniform adhesion is implemented by adding, to an isotropic surface attraction, an appropriate `dipolar sticky' correction (positive or negative,…

Soft Condensed Matter · Physics 2009-11-13 Domenico Gazzillo , Riccardo Fantoni , Achille Giacometti

The depletion potential between two hard spheres in a solvent of thin hard disclike platelets is investigated by using either the Derjaguin approximation or density functional theory. Particular attention is paid to the density dependence…

Soft Condensed Matter · Physics 2009-11-10 L. Harnau , S. Dietrich