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Faradaic deionization (FDI) is a promising technology for energy-efficient water desalination using porous electrodes containing redox-active materials. Herein, we demonstrate for the first time the capability of a symmetric FDI flow cell…

Chemical Physics · Physics 2023-06-09 Vu Q. Do , Erik R. Reale , Irwin C. Loud , Paul G. Rozzi , Haosen Tan , David A. Willis , Kyle C. Smith

Capacitive deionization (CDI) is a technology in which water is desalinated by ion electrosorption into the electric double layers (EDLs) of charging porous electrodes. In recent years significant advances have been made in modeling the…

Chemical Physics · Physics 2017-02-01 Amit N. Shocron , Matthew E. Suss

Water desalination by capacitive deionization (CDI) is performed via electrochemical cells consisting of two porous carbon electrodes. Upon transferring charge from one electrode to the other, ions are removed from the feedwater by…

Materials Science · Physics 2015-06-15 P. M. Biesheuvel , M. E. Suss , H. V. M. Hamelers

Capacitive deionization (CDI) is a fast-emerging water desalination technology in which a small cell voltage of ~1 V across porous carbon electrodes removes salt from feedwaters via electrosorption. In flow-through electrode (FTE) CDI cell…

Computational Engineering, Finance, and Science · Computer Science 2017-02-01 Eric N. Guyes , Amit N. Shocron , Anastasia Simanovski , P. M. Biesheuvel , Matthew E. Suss

Many industrial and agricultural applications require the treatment of water streams containing high concentrations of ionic species for closing material cycles. High concentration factors are often desired, but hard to achieve with…

We present porous electrode theory for capacitive deionization (CDI) with electrodes containing nanoparticles that consist of a redox-active intercalation material. A geometry of a desalination cell is considered which consists of two…

Chemical Physics · Physics 2019-12-24 K. Singh , H. J. M. Bouwmeester , L. C. P. M de Smet , M. Z. Bazant , P. M. Biesheuvel

Several harmful or valuable ionic species present in sea, brackish and wastewaters are amphoteric, and thus their properties depend on the local water pH. Effective removal of these species can be challenging by conventional membrane…

Capacitive Deionization (CDI) is a non-energy intensive water treatment technology. To harness the enormous potential of CDI requires improving performance, while offering industrially feasible solutions. Following this idea, the…

Electrochemical desalination devices that use redox-active cation intercalation electrodes show promise for desalination of salt-rich water resources with high water recovery and low energy consumption. While previous modeling and…

Applied Physics · Physics 2018-04-02 Sizhe Liu , Kyle C. Smith

Scale-up of flow-electrode capacitive deionization is hindered due to the reliance on thick brittle graphite current collectors. Inspired by developments of electrochemical technologies we present the use of flexible membrane electrode…

Over the past decade, capacitive deionization (CDI) has realized a surge in attention in the field of water desalination and can now be considered as an important technology class, along with reverse osmosis and electrodialysis. While many…

The rapid and efficient exchange of ions between porous electrodes and aqueous solutions is important in many applications, such as electrical energy storage by super-capacitors, water desalination and purification by capacitive…

Chemical Physics · Physics 2015-05-14 P. M. Biesheuvel , M. Z. Bazant

Capacitive mixing (CAPMIX) and capacitive deionization (CDI) are promising candidates for harvesting clean, renewable energy and for the energy efficient production of potable water, respectively. Both CAPMIX and CDI involve water-immersed…

Soft Condensed Matter · Physics 2016-08-08 Andreas Härtel , Mathijs Janssen , Sela Samin , René van Roij

Solid polymer electrolytes hold significant promise as materials for next-generation batteries due to their superior safety performance, enhanced specific energy, and extended lifespans compared to liquid electrolytes. However, the…

Chemical Physics · Physics 2025-04-04 Zhenze Yang , Weike Ye , Xiangyun Lei , Daniel Schweigert , Ha-Kyung Kwon , Arash Khajeh

A two-scale model is presented to simulate the dynamic ion transport and adsorption processes in porous electrodes used for capacitive deionization (CDI). At the pore scale, the Stokes equation governing water flow in porous CDI electrodes…

Fluid Dynamics · Physics 2022-01-14 Min Liu , John Waugh , Siddharth Komini Babu , Jacob S. Spendelow , Qinjun Kang

The freshwater crisis is a growing concern and a pressing problem for the world because of the increasing population, civilization, and rapid industrial growth. The water treatment facilities are able to supply less than 1% of the total…

Soft Condensed Matter · Physics 2023-11-28 Nudrat Nawal , Md Rashed Nizam , Priom Das , A K M Monjur Morshed

Separation of salt ions from seawater using graphene oxide (GO) membrane is an emerging desalination method. Here, we investigate the dynamic behavior of water, sodium, and chloride ions inside GO membrane using a computational approach.…

Chemical Physics · Physics 2021-08-25 One-Sun Lee

In the growing field of capacitive deionization (CDI), a number of performance metrics have emerged to describe the desalination process. Unfortunately, the separation conditions under which these metrics are measured are often not…

Capacitive deionization (CDI) is a fast-emerging technology most commonly applied to brackish water desalination. In CDI, salt ions are removed from the feedwater and stored in electric double layers (EDLs) within micropores of electrically…

Chemical Physics · Physics 2017-10-11 Matthew E. Suss

Solid polymer electrolytes for lithium batteries promise improvements in safety and energy density if their conductivity can be increased. Nanostructured block copolymer electrolytes specifically have the potential to provide both good…

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