Related papers: Small-System Group: Thermodynamics as a Complete S…
Experimental and theoretical results about entropy limits for macroscopic and single-particle systems are reviewed. It is clarified when it is possible to speak about a quantum of entropy, given by the Boltzmann constant k, and about a…
Equilibrium phase transitions usually emerge from the microscopic behavior of many-body systems and are associated to interesting phenomena such as the generation of long-range order and spontaneous symmetry breaking. They can be defined…
We provide an extension of a recent approach to study non-equilibrium thermodynamics [Phys. Rev. E 81, 051130 (2010), to be denoted by I in this work] to inhomogeneous systems by considering the latter to be composed of quasi-independent…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…
In the thermodynamic limit the ratio of system size to thermal de Broglie wavelength tends to infinity and the volume per particle of the system is constant. Our familiar Bose-Einstein statistics is absolutely valid in the thermodynamic…
The problem of temperature in nonextensive statistical mechanics is studied. Considering the first law of thermodynamics and a "quasi-reversible process", it is shown that the Tsallis entropy becomes the Clausius entropy if the inverse of…
Traditionally, phase transitions are defined in the thermodynamic limit only. We propose a new formulation of equilibrium thermo-dynamics that is based entirely on mechanics and reflects just the {\em geometry and topology} of the N-body…
This paper presents an in-depth analysis of the anatomy of both thermodynamics and statistical mechanics, together with the relationships between their constituent parts. Based on this analysis, using the renormalization group and…
Tropical limit for macroscopic systems in equilibrium defined as the formal limit of Boltzmann constant k going to 0 is discussed. It is shown that such tropical limit is well-adapted to analyse properties of systems with highly degenerated…
We study the thermodynamics near the generic (density-driven) superfluid--Mott-insulator transition in the three-dimensional Bose-Hubbard model using the nonperturbative renormalization-group approach. At low energy the physics is…
The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…
The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when…
Here we investigate how local properties of particles in a thermal bath influence the thermodynamics of the bath. We utilize nanothermodynamics, based on two postulates: that small systems can be treated self-consistently by coupling to an…
The limits of the Second Law of Thermodynamics, which reigns undisputed in the macroscopic world, are investigated at the mesoscopic level, corresponding to spatial dimensions of a few microns. An extremely simple isolated system, modeled…
In this paper we examine the behavior in temperature of the free energy on quantum systems in an arbitrary number of dimensions. We define from the free energy a function $C$ of the coupling constants and the temperature, which in the…
Thermodynamic macro variables, such as the temperature or volume macro variable, can take on a continuum of allowable values, called thermodynamic macro values. Although referring to the same macro phenomena, the macro variables of…
The principle of microscopic reversibility says that, in equilibrium, two-time cross-correlations are symmetric under the exchange of observables. Thus, the asymmetry of cross-correlations is a fundamental, measurable, and often-used…
The formulation for zero mode of a Bose-Einstein condensate beyond the Bogoliubov approximation at zero temperature [Y.Nakamura et al., Phys. Rev. A 89, 013613 (2014)] is extended to finite temperature. Both thermal and quantum fluctuations…
We describe a one-dimensional self-gravitating system derived from the problem of large-scale structure formation in cosmology. Considering small times so that the expansion can be neglected we present a thermodynamical analysis of this…
Thermodynamics is traditionally constrained to the study of macroscopic systems whose energy fluctuations are negligible compared to their average energy. Here, we push beyond this thermodynamic limit by developing a mathematical framework…