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The basic physics of nucleation in solid \hl{single-crystal} nanoparticles is revealed by a phase-field theory that includes surface energy, chemical reactions and coherency strain. In contrast to binary fluids, which form arbitrary contact…

Materials Science · Physics 2014-09-17 Daniel A. Cogswell , Martin Z. Bazant

We investigate the conformation, position, and dynamics of core-shell nanoparticles (CSNPs) composed of a silica core encapsulated in a cross-linked poly-N-isopropylacrylamide shell at a water-oil interface for a systematic range of core…

Soft Condensed Matter · Physics 2018-09-07 Siddarth A. Vasudevan , Astrid Rauh , Martin Kröger , Matthias Karg , Lucio Isa

In this work, we determine the dissociation temperature of the hydrogen (H$_2$) hydrate by computer simulation using two different methods. In both cases, the molecules of water and H$_2$ are modeled using the TIP4P/Ice and a modified…

Soft Condensed Matter · Physics 2026-01-27 Miguel J. Torrejon , S. Blazquez , Jesus Algaba , M. M. Conde , F. J. Blas

In this work, we examine metal electrode-ionomer electrolyte systems at high voltage / negative surface charge and at high pH to assess factors that influence hydrogen production efficiency. We simulate the hydrogen evolution electrode…

Chemical Physics · Physics 2019-09-04 Reese E. Jones , William C. Tucker , Matthew J. L. Mills , Sanjeev Mukerjee

We reconsider the applicability of classical nucleation theory (CNT) to the calculation of the free energy of solid cluster formation in a liquid and its use to the evaluation of interface free energies from nucleation barriers. Using two…

Statistical Mechanics · Physics 2012-06-19 Santi Prestipino , Alessandro Laio , Erio Tosatti

The interface formation model is applied to describe the initial stages of the coalescence of two liquid drops in the presence of a viscous ambient fluid whose dynamics is fully accounted for. Our focus is on understanding (a) how this…

Fluid Dynamics · Physics 2015-06-22 James E. Sprittles , Yulii D. Shikhmurzaev

Despite the mounting evidence proving that the air-water interface or the microdroplet geometry has nothing to do with the spontaneous formation of hydrogen peroxide (H2O2), the myth persists. Three recent studies by George and co-workers…

Soft Condensed Matter · Physics 2025-05-28 Muzzamil Ahmad Eatoo , Himanshu Mishra

Recent first-principle calculations unveiled a distinctive dynamic behavior in water molecule rotation during the melting process of highly confined water, indicating a notable time-scale separation in diffusion. In this short paper, we…

Chemical Physics · Physics 2024-03-27 Yuheng Zhao , Yi Qin Gao

We develop a computational method for simulating the nonlinear dynamics of an elastic tumor-host interface. This work is motivated by the recent linear stability analysis of a two-phase tumor model with an elastic membrane interface in 2D.…

Numerical Analysis · Mathematics 2019-12-12 Min-Jhe Lu , Chun Liu , Shuwang Li

We consider heterostructures obtained by stacking layers of two s-wave superconductors with significantly different coupling strengths, respectively in the weak- and strong-coupling regimes. The weak- and strong-coupling superconductors are…

Superconductivity · Physics 2021-03-31 Giacomo Mazza , Adriano Amaricci , Massimo Capone

In this study, molecular dynamic simulations are employed to investigate the nucleation of NaCl crystal in solutions. According to the simulations, the dissolved behaviors of NaCl in water are dependent on ion concentrations. With…

Chemical Physics · Physics 2018-11-29 Qiang Sun

We present a flexible discretization technique for computational models of thin tubular networks embedded in a bulk domain, for example a porous medium. These systems occur in the simulation of fluid flow in vascularized biological tissue,…

Computational Engineering, Finance, and Science · Computer Science 2022-02-01 Timo Koch

In this work, we conducted molecular dynamics simulations to study the fracture mechanism of ice crystals in a bulk phase and at ice-ice interfaces at the atomistic scale. We show that there exists a narrow disordered interfacial layer…

Chemical Physics · Physics 2019-07-23 A. Afshar , J. Zhong , D. S. Thompson , D. Meng

Aqueous solutions of LiCl are probably the most studied electrolyte solutions related to the complexity of liquid water at low temperatures. Despite the large amount of available experimental data hardly any computational studies were…

Soft Condensed Matter · Physics 2020-04-29 Philip H. Handle

Chemistry occurring at or near the surfaces of aqueous droplets and thin films in the atmosphere influences air quality and climate. Molecular dynamics simulations are becoming increasingly useful for gaining atomic-scale insight into the…

Soft Condensed Matter · Physics 2013-07-01 Douglas J. Tobias , Abraham C. Stern , Marcel D. Baer , Yan Levin , Christopher J. Mundy

Freezing is a fundamental physical phenomenon that has been studied over many decades; yet the role played by surfaces in determining nucleation has remained elusive. Here we report direct computational evidence of surface induced…

Statistical Mechanics · Physics 2015-05-13 T. Li , D. Donadio , L. M. Ghiringhelli , G. Galli

The passage of single air bubbles through the horizontal interface between miscible viscoplastic and Newtonian fluids, considering various combinations of densities and viscosities for the fluid layers, is studied computationally. The…

Fluid Dynamics · Physics 2023-10-30 Marjan Zare , Ian Frigaard , Gregory Lawrence

Recent research has revealed several different techniques for nanoscopic gas nucleation on submerged surfaces, with findings seemingly in contradiction with each other. In response to this, we have systematically investigated the occurrence…

Water freezing is ubiquitous on Earth, affecting many areas from biology to climate science and aviation technology. Probing the atomic structure in the homogeneous ice nucleation process from scratch is of great value but still…

Materials Science · Physics 2023-04-27 Mingyi Chen , Lin Tan , Han Wang , Linfeng Zhang , Haiyang Niu

The non-wetting phenomena of water on certain solid surfaces have been under intensive study for decades, but the nature of hydrophobic/water interfaces remains controversial. Here a water/graphite interface is investigated with…

Soft Condensed Matter · Physics 2012-04-02 Ing-Shouh Hwang , Chih-Wen Yang , Yi-Hsien Lu
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