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The confinement of an ionic liquid between charged solid surfaces is treated using an exactly solvable 1D Coulomb gas model. The theory highlights the importance of two dimensionless parameters: the fugacity of the ionic liquid, and the…

Soft Condensed Matter · Physics 2014-09-08 Alpha A Lee , Dominic Vella , Susan Perkin , Alain Goriely

Thermodynamics and dynamics of a classical two-dimensional system with dipole-like isotropic repulsive interactions are studied systematically using extensive molecular dynamics (MD) simulations supplemented by appropriate theoretical…

Soft Condensed Matter · Physics 2018-03-02 Sergey Khrapak , Nikita Kryuchkov , Stanislav Yurchenko

Coulomb crystallisation of large ensembles of ions has in the past years been intensively studied experimentally with many spectacular results of relevance to infinite systems in one-, two-, and three-dimensions.While strings of a few ions…

Atomic and Molecular Clusters · Physics 2012-02-14 Michael Drewsen , Thierry Matthey , Anders Mortensen , Jan Petter Hansen

The authors present a study of the non equilibrium statistical properties of a one dimensional hard-rod fluid dissipating energy via inelastic collisions and subject to the action of a Gaussian heat bath, simulating an external driving…

Materials Science · Physics 2009-11-13 Umberto Marini-Bettolo-Marconi , Pedro Tarazona , Fabio Cecconi

On a basis of a two-length scale description of hydrophobic interactions we develop a continuous self-consistent theory of solute-water interactions which allows to determine a hydrophobic layer of a solute molecules of any geometry with…

Soft Condensed Matter · Physics 2007-05-23 G. Sitnikov , S. Nechaev , M. Taran , A. Muryshev

The dynamics and thermodynamics of melting in two-dimensional Coulomb clusters is revisited using molecular dynamics and Monte Carlo simulations. Several parameters are considered, including the Lindemann index, the largest Lyapunov…

Atomic and Molecular Clusters · Physics 2007-05-23 E. Yurtsever , F. Calvo , D. J. Wales

We present results of Monte-Carlo simulations for finite 2D single and bilayer systems. Strong Coulomb correlations lead to arrangement of particles in configurations resembling a crystal lattice. For binary layers, there exists a…

Mesoscale and Nanoscale Physics · Physics 2015-06-24 A. V. Filinov , M. Bonitz , Yu. E. Lozovik

A new computational method is presented for study suspensions of charged soft particles undergoing fluctuating hydrodynamic and electrostatic interactions. The proposed model is appropriate for polymers, proteins and porous particles…

Soft Condensed Matter · Physics 2015-04-14 Juan P. Hernandez-Ortiz , Juan J. de Pablo

Ionic liquids are promising candidates for novel electrolytes as they possess large electrochemical and thermodynamic stability and offer a high degree of tunability. As purely-ionic electrolyte without neutral solvent they exhibit…

Chemical Physics · Physics 2022-01-12 Max Schammer , Birger Horstmann , Arnulf Latz

For inhomogeneous classical Coulomb fluids in thermal equilibrium, like the jellium or the two-component Coulomb gas, there exists a variety of exact sum rules which relate the particle one-body and two-body densities. The necessary…

Soft Condensed Matter · Physics 2013-10-09 Ladislav Samaj

The Debye-Huckel (DH) formalism of bulk electrolytes equivalent to the gaussian-level closure of the electrostatic Schwinger-Dyson identities without the interionic hard-core (HC) coupling is extended via the cumulant treatment of these…

Soft Condensed Matter · Physics 2024-04-11 Sahin Buyukdagli

Stochastic density functional theory is applied to analyze the conductivity of strong two species electrolytes at arbitrary field strengths. The corresponding stochastic equations for the density of the electrolyte species are solved by…

Statistical Mechanics · Physics 2016-05-04 Vincent Démery , David S Dean

The electric microfield distribution at charged particles is studied for two-component electron-ion plasmas using molecular dynamics simulation and theoretical models. The particles are treated within classical statistical mechanics using…

Plasma Physics · Physics 2009-11-11 H. B. Nersisyan , C. Toepffer , G. Zwicknagel

We study ionic liquids interacting with electrified interfaces. The ionic fluid is modeled as a Coulomb lattice gas. We compare the ionic density profiles calculated using a popular modified Poisson-Boltzmann equation with the explicit…

Soft Condensed Matter · Physics 2017-12-21 Matheus Girotto , Thiago Colla , Alexandre P. dos Santos , Yan Levin

Thermodynamic quantities of Coulomb plasmas consisting of point-like ions immersed in a compressible, polarizable electron background are calculated for ion charges Z=1 to 26 and for a wide domain of plasma parameters ranging from the…

Plasma Physics · Physics 2016-09-08 G. Chabrier , A. Y. Potekhin

Molecular simulations in an open environment, involving ion exchange, are necessary to study various systems, from biosystems to confined electrolytes. However, grand-canonical simulations are often computationally demanding in condensed…

Chemical Physics · Physics 2023-11-13 Jeongmi Kim , Luc Belloni , Benjamin Rotenberg

In this paper, we present the theoretical formalism describing the collective ion dynamics of the nonideal Coulomb classical one-component plasmas on the basis of the self-consistent relaxation theory. The theory is adapted to account for…

Plasma Physics · Physics 2023-08-08 Ilnaz I. Fairushin , Anatolii V. Mokshin

Colloidal particles that are confined to an interface such as the air-water interface are an example of a two-dimensional fluid. Such dispersions have been observed to spontaneously form cluster and stripe morphologies in certain systems…

Soft Condensed Matter · Physics 2008-09-17 A. J. Archer

The electron self-energy for long-range Coulomb interactions plays a crucial role in understanding the many-body physics of interacting electron systems (e.g. in metals and semiconductors), and has been studied extensively for decades. In…

Strongly Correlated Electrons · Physics 2020-08-25 Yunxiang Liao , Donovan Buterakos , Mike Schecter , Sankar Das Sarma

In this paper we develop a simple theory to study the effects of ionic size on ionic distributions around a charged spherical particle. We include a correction to the regular Poisson-Boltzmann equation in order to take into account the size…

Soft Condensed Matter · Physics 2017-08-30 Thiago Colla , Lucas Nunes Lopes , Alexandre P. dos Santos