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Nuclear quantum effects and non-Born--Oppenheimer effects play a vital role in many chemical and biological processes, motivating the incorporation of such effects into dynamical simulations. In real-time nuclear--electronic orbital…

Chemical Physics · Physics 2026-05-27 Nicholas J. Boyer , Sharon Hammes-Schiffer

TThe isotope effect is a powerful probe of electron-phonon interactions in solid-state systems, offering key insights into how atomic mass influences emergent quantum states. Here, the impact of oxygen isotope substitution ($^{16}{\rm…

An electron density functional approach for the calculation of the nuclear multipole moments is presented. The electronic matrix elements entering the experimentally observed hyperfine electron-nucleus interaction constants in atoms are…

Nuclear Theory · Physics 2007-05-23 R. L. Pavlov , P. P. Raychev , V. P. Garistov , M. Dimitrova-Ivanovich , J. Maruani

We present a first-principles study of the electronic structure and superconducting parameters of the compounds $A$Os$_2$O$_6$ ($A$ = Na, K, Rb, and Cs) and at ambient and applied hydrostatic pressure. We find that the sensitivity of the…

Superconductivity · Physics 2007-05-23 R. Saniz , A. J. Freeman

The electronic energy structures and magnetic properties of layered superconductors $R$Ni$_2$B$_2$C, $R$Fe$_4$Al$_8$ and FeSe are systematically studied, by using the density functional theory (DFT). The calculations allowed us to reveal a…

Superconductivity · Physics 2014-04-04 G. E. Grechnev , A. V. Logosha , A. A. Lyogenkaya , A. G. Grechnev , A. V. Fedorchenko

Recent experimental work has realized a new insulating state of samarium nickelate (SmNiO$_3$), accessible in a reversible manner via high-density electron doping. To elucidate this behavior, we use the first-principles density functional…

Mesoscale and Nanoscale Physics · Physics 2019-11-27 Michele Kotiuga , Karin M. Rabe

Quantum shell effects drive many aspects of many-body quantal systems and their interactions. Among these are the quasifission reactions that impede the formation of a compound nucleus in superheavy element (SHE) searches. Fragment…

Nuclear Theory · Physics 2022-09-14 Liang Li , Lu Guo , K. Godbey , A. S. Umar

The thermopower and Nernst-Ettingshausen (NE) effect in degenerate semiconductors and semimetals placed in high electric and magnetic fields are calculated by taking into account the heating of both electrons and phonons as well as their…

Condensed Matter · Physics 2007-05-23 M. M. Babaev , T. M. Gassym , M. Tas , M. Tomak

Quantum proton tunneling (QPT) in the two representative multi-electron/-proton transfer electrode processes, i.e. hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR), was investigated by using polycrystalline platinum…

Chemical Physics · Physics 2019-07-02 Ken Sakaushi

Orbital-free Density Functional Theory (OF-DFT) has been used when studying atoms, molecules and solids. In nuclear physics, there has been basically no application of OF-DFT so far, as the Density Functional Theory (DFT) has been widely…

Nuclear Theory · Physics 2023-08-03 Gianluca Colo' , Kouichi Hagino

We present a Density Functional Theory (DFT) based first-principles study on iron chalcogenides superconductor FeSe, systematically investigating pressure and doping induced modifications to its electronic, magnetic, and lattice dynamical…

Materials Science · Physics 2025-04-17 Abyay Ghosh , Piotr Chudzinski , Myrta Grüning

The hole-doped NdNiO$_2$ layer deposited on the SrTiO$_{3}$ surface exhibits unconventional superconductivity. Here, we present a systematic study of the electronic and magnetic properties of the NdNiO$_2$ superconductor using the density…

Materials Science · Physics 2025-12-24 Sajid Sekh , Andrzej Ptok , Wojciech Brzezicki , Przemysław Piekarz , Andrzej M. Oleś

We report inelastic neutron scattering measurements of the phonon spectra in a pure powder sample of the multiferroic material BiFeO3. A high-temperature range was covered to unravel the changes in the phonon dynamics across the Neel (T_N ~…

Materials Science · Physics 2015-03-19 M. Zbiri , H. Schober , N. Choudhury , R. Mittal , S. L. Chaplot , S. J. Patwe , S. N. Achary , A. K. Tyagi

Rare-earth trihydrides ($R$H$_3$) exhibit intriguing coupled electronic and structural properties as a function of doping, hydrogen vacancies, and thermodynamic conditions. Theoretical studies of these materials typically rely on density…

Strongly Correlated Electrons · Physics 2024-10-07 Adam Denchfield , Hyeondeok Shin , Panchapakesan Ganesh , Russell J Hemley , Hyowon Park

The study of nuclear generalized parton distributions (GPDs) could be a crucial achievement of hadronic physics since they open new ways to obtain new information on the structure of bound nucleons, in particular, to access the neutron…

Nuclear Theory · Physics 2015-06-19 Matteo Rinaldi

Polar optical phonons are studied in the framework of the dielectric continuum approach for a prototypical quantum-dot/quantum-well (QD/QW) heterostructure, including the derivation of the electron-phonon interaction Hamiltonian and a…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 F. Comas , Nelson Studart

We discuss quantum effects in the diffusion process which is used to describe the shape evolution from the touching configuration of fusing two nuclei to a compound nucleus. Applying the theory with quantum effects to the case where the…

Nuclear Theory · Physics 2009-11-11 Kouhei Washiyama , Bulent Yilmaz , Sakir Ayik , Noboru Takigawa

We investigate the influence of the electron-phonon interaction on the decay dynamics of a quantum dot coupled to an optical microcavity. We show that the electron-phonon interaction has important consequences on the dynamics, especially…

Mesoscale and Nanoscale Physics · Physics 2012-08-17 P. Kaer , T. R. Nielsen , P. Lodahl , A. -P. Jauho , J. Mork

We use density functional molecular dynamics (DFT-MD) to study the effect of finite temperature exchange-correlation (xc) in Hydrogen. Using the Kohn-Sham approach, the xc energy of the system, $E_{xc}(r_{s})$ is replaced by the xc free…

Materials Science · Physics 2020-05-20 Kushal Ramakrishna , Tobias Dornheim , Jan Vorberger

Hydrogen is the most abundant element in the universe. It is also the lightest and as such the most quantum of the elements, in the sense that quantum tunnelling, quantum delocalisation, and zero-point motion can be important. For practical…

Chemical Physics · Physics 2019-01-18 Wei Fang , Ji Chen , Yexin Feng , Xin-Zheng Li , Angelos Michaelides