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We present an approach to calculate the electronic structure for a range of materials using the quasiparticle self-consistent GW method with vertex corrections included in the screened Coulomb interaction W. This is achieved by solving the…

Materials Science · Physics 2023-10-10 Brian Cunningham , Myrta Gruening , Dimitar Pashov , Mark van Schilfgaarde

We implement the GW space-time method at finite temperatures, in which the Green's function G and the screened Coulomb interaction W are represented in the real space on a suitable mesh and in imaginary time in terms of Chebyshev…

Materials Science · Physics 2025-11-11 Sam Azadi , Arkadiy Davydov , Evgeny Kozik

The GW approximation is a well-known method to improve electronic structure predictions calculated within density functional theory. In this work, we have implemented a computationally efficient GW approach that calculates central…

We present an approach for GW calculations of quasiparticle energies with quasi-quadratic scaling by approximating high-energy contributions to the Green's function in its Lehmann representation with effective stochastic vectors. The method…

Materials Science · Physics 2023-12-07 Aaron R. Altman , Sudipta Kundu , Felipe H. da Jornada

We introduce an alternative route to quasiparticle self-consistent $GW$ calculations ($\mathrm{qs}GW$) on the basis of a Joint Approximate Diagonalization of the one-body $GW$ Green's functions $G(\varepsilon_n^{QP})$ taken at the input…

Materials Science · Physics 2024-12-05 Ivan Duchemin , Xavier Blase

The main goal of electronic structure methods is to solve the Schroedinger equation for the electrons in a molecule or solid, to evaluate the resulting total energies, forces, response functions and other quantities of interest. In this…

Materials Science · Physics 2015-06-24 Peter E. Blöchl , Johannes Kaestner , Clemens J. Foerst

A GW approximation (GWA) method named U+GWA is proposed, where we can start GWA with more localized wave functions obtained by the local spin-density approximation (LSDA)+U method. Then GWA and U+GWA are applied to MnO, NiO, and V$_2$O$_3$…

Strongly Correlated Electrons · Physics 2008-10-18 S. Kobayashi , Y. Nohara , S. Yamamoto , T. Fujiwara

We present a code implementing the linearized self-consistent quasiparticle GW method (scQPGW) in the LAPW basis. Our approach is based on the linearization of the self-energy around zero frequency which differs it from the existing…

Materials Science · Physics 2017-09-13 Andrey L. Kutepov , Viktor S. Oudovenko , Gabriel Kotliar

Fully self-consistent GW (sc-GW) methods are now available to evaluate quasiparticle and spectral properties of various molecular and bulk systems. However, such techniques based on the full matrix of G and W are computationally demanding.…

Materials Science · Physics 2020-11-17 Yashpal Singh , Lin-Wang Wang

We present a plane wave implementation of the G0W0 approximation within the projector augmented wave method code GPAW. The computed band gaps of ten bulk semiconductors and insulators deviate on average by 0.2 eV (~ 5 %) from the…

Materials Science · Physics 2014-01-10 Falco Hüser , Thomas Olsen , Kristian S. Thygesen

We present quasiparticle (QP) energies from fully self-consistent $GW$ (sc$GW$) calculations for a set of prototypical semiconductors and insulators within the framework of the projector-augmented wave methodology. To obtain converged…

Materials Science · Physics 2018-10-31 Manuel Grumet , Peitao Liu , Merzuk Kaltak , Jiří Klimeš , Georg Kresse

The so-called local density approximation plus the multi-orbital mean-field Hubbard model (LDA+U) has been implemented within the all-electron projector augmented-wave method (PAW), and then used to compute the insulating antiferromagnetic…

Strongly Correlated Electrons · Physics 2009-10-31 O. Bengone , M. Alouani , P. Bloechl , J. Hugel

A new cumulant-based $GW$ approximation for the retarded one-particle Green's function is proposed, motivated by an exact relation between the improper Dyson self-energy and the cumulant generating function. Qualitative aspects of this…

Strongly Correlated Electrons · Physics 2016-09-21 Matthew Z. Mayers , Mark S. Hybertsen , David R. Reichman

In solid-state physics, energies of crystals are usually computed with a plane-wave discretization of Kohn-Sham equations. However the presence of Coulomb singularities requires the use of large plane-wave cut-offs to produce accurate…

Numerical Analysis · Mathematics 2023-01-02 Mi-Song Dupuy

Simulation of conditional master equations is important to describe systems under continuous measurement and for the design of control strategies in quantum systems. For large bosonic systems, such as BEC and atom lasers, full quantum field…

Quantum Physics · Physics 2013-05-30 M. R. Hush , A. R. R. Carvalho , J. J. Hope

It is demonstrated that estimators of the angular power spectrum commonly used for the stochastic gravitational-wave background (SGWB) lack a closed-form analytical expression for the likelihood function and, typically, cannot be accurately…

Instrumentation and Methods for Astrophysics · Physics 2026-01-30 Xiangyu Zhang , Erik Floden , Hongru Zhao , Sara Algeri , Galin Jones , Vuk Mandic , Jesse Miller

Multivariate global polynomial approximations - such as polynomial chaos or stochastic collocation methods - are now in widespread use for sensitivity analysis and uncertainty quantification. The pseudospectral variety of these methods uses…

Numerical Analysis · Mathematics 2013-04-09 Paul G. Constantine , Michael S. Eldred , Eric T. Phipps

Quasiparticle (QP) excitations are extremely important for understanding and predicting charge transfer and transport in molecules, nanostructures and extended systems. Since density functional theory (DFT) within the Kohn-Sham (KS)…

Chemical Physics · Physics 2017-07-18 Vojtech Vlcek , Eran Rabani , Daniel Neuhauser , Roi Baer

We apply the quasiparticle self-consistent GW method (QSGW) to slab models of ionic materials, LiF, KF, NaCl, MgO, and CaO, under electric field. Then we obtain the optical dielectric constants E(Slab) from the differences of the slopes of…

Strongly Correlated Electrons · Physics 2020-05-20 Hirofumi Sakakibara , Takao Kotani , Masao Obata , Tatsuki Oda

Functionals of the meta-generalized gradient approximation (MGGA) are nowadays widely used in chemistry and solid-state physics for the simulation of electronic systems like molecules, solids, or surfaces. Due to their dependency on the…

Materials Science · Physics 2022-05-31 Jan Doumont , Fabien Tran , Peter Blaha