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We show that the formation of a gel by conducting colloidal particles leads to a dramatic enhancement in bulk conductivity, due to inter-particle electron tunneling, combining predictions from molecular dynamics simulations with structural…

Soft Condensed Matter · Physics 2013-06-24 Biagio Nigro , Claudio Grimaldi , Peter Ryser , Francesco Varrato , Giuseppe Foffi , Peter J. Lu

We report measurements of the frequency-dependent shear moduli of aging colloidal systems that evolve from a purely low-viscosity liquid to a predominantly elastic glass or gel. Using microrheology, we measure the local complex shear…

Soft Condensed Matter · Physics 2009-11-13 S. Jabbari-Farouji , M. Atakhorram , D. Mizuno , E. Eiser , G. H. Wegdam , F. C. MacKintosh , Daniel Bonn , C. F. Schmidt

Inorganic nanocrystal gels retain distinct properties of individual nanocrystals while offering tunable, network structure-dependent characteristics. We review different mechanisms for assembling gels from colloidal nanocrystals including…

We perform Monte Carlo simulations of a simplified two-dimensional model for colloidal hard spheres in an external uniaxial AC electric field. Experimentally, the external field induces dipole moments in the colloidal particles, which in…

Soft Condensed Matter · Physics 2015-05-28 Ahmad M. Almudallal , Ivan Saika-Voivod

The thermodynamics of a quantum system of layers containing perpendicularly oriented dipolar molecules is studied within an oscillator approximation for both bosonic and fermionic species. The system is assumed to be built from chains with…

Quantum Gases · Physics 2013-04-19 J. R. Armstrong , N. T. Zinner , D. V. Fedorov , A. S. Jensen

We study the structure and the dynamics in the formation of irreversible gels by means of molecular dynamics simulation of a model system where the gelation transition is due to the random percolation of permanent bonds between neighboring…

Soft Condensed Matter · Physics 2015-06-25 T. Abete , A. de Candia , E. Del Gado , A. Fierro , A. Coniglio

We derive a multiphysics model that accounts for network elasticity with spontaneous strains, swelling and nematic interactions in liquid crystal gels (LCGs). We discuss the coupling among the various physical mechanisms, with particular…

Soft Condensed Matter · Physics 2018-11-28 Alessandro Lucantonio , Antonio DeSimone

Cosmic large-scale structures, animal flocks, and living tissues are non-equilibrium organized systems created by dissipative processes. Despite the uniqueness, the realization of dissipative structures is still difficult. Herein, we report…

Colloidal particles with appropriate wetting properties can become very strongly trapped at an interface between two immiscible fluids. We have harnessed this phenomenon to create a new class of soft materials with intriguing and…

Soft Condensed Matter · Physics 2009-11-13 K. A. White , A. B. Schofield , B. P. Binks , P. S. Clegg

Colloid-polymer mixtures can undergo spinodal decomposition into colloid-rich and colloid-poor regions. Gelation results when interconnected colloid-rich regions solidify. We show that this occurs when these regions undergo a glass…

Soft Condensed Matter · Physics 2009-11-10 S. Manley , H. M. Wyss , K. Miyazaki , J. C. Conrad , V. Trappe , L. J. Kaufman , D. R. Reichman , D. A. Weitz

Thermosensitive microgels are widely studied hybrid systems combining properties of polymers and colloidal particles in a unique way. Due to their complex morphology their interactions and packing, and consequentially the viscoelastcity of…

Soft Condensed Matter · Physics 2019-06-19 Gaurasundar M. Conley , James L. Harden , Frank Scheffold

A cubic structure of polymer colloid complexes is studied. The technique of the research includes i) an analysis of well-known literature SAXS data; on this base, at some assumptions, ii) constructing a simple model to estimate geometric…

Statistical Mechanics · Physics 2012-10-29 Andrei N. Yakunin

The aggregation of attractive colloids has been extensively studied from both theoretical and experimental perspectives as the fraction of solid particles is changed, and the range, type and strength of attractive or repulsive forces…

Soft Condensed Matter · Physics 2019-11-07 Safa Jamali , Robert C. Armstrong , Gareth H. McKinley

Discrete mesoscale network models, in which explicitly modeled polymer chains are replaced by implicit pairwise potentials, are capable of predicting the macroscale mechanical response of polymeric materials such as elastomers and gels,…

Soft Condensed Matter · Physics 2024-07-16 Robert J. Wagner , Meredith N. Silberstein

It has recently been shown that in a broad class of disordered systems oscillatory shear training can embed memories of specific shear protocols in relevant physical parameters such as the yield strain. These shear protocols can be used to…

Soft Condensed Matter · Physics 2020-04-28 Eric M Schwen , Meera Ramaswamy , Chieh-Min Cheng , Linda Jan , Itai Cohen

Chemotaxis systems of Keller--Segel type constitute one of the central mathematical frameworks for understanding aggregation phenomena in biological and ecological systems. Over the past decades, the theory has evolved from the classical…

Analysis of PDEs · Mathematics 2026-03-06 Kolade M Owolabi , Eben Mare , Clara O Ijalana , Kolawole S Adegbie

Molecular self-assembly plays a very important role in various aspects of technology as well as in biological systems. Governed by the covalent, hydrogen or van der Waals interactions - self-assembly of alike molecules results in a large…

Colloidal gels are out-of-equilibrium structures, made up of a rarefied network of colloidal particles. Comparing experiments to numerical simulations, with hydrodynamic interactions switched off, we demonstrate the crucial role of the…

Soft Condensed Matter · Physics 2015-09-17 C. Patrick Royall , Jens Eggers , Akira Furukawa , Hajime Tanaka

The effects of particle roughness and short-ranged non-central forces on colloidal gels are studied using computer simulations in which particles experience a sinusoidal variation in energy as they rotate. The number of minima $n$ and…

Soft Condensed Matter · Physics 2019-09-05 Hong T. Nguyen , Alan L. Graham , Peter H. Koenig , Lev D. Gelb

The liquid-liquid phase separation of a binary solvent can be arrested by colloidal particles trapped at the interface [K. Stratford et al., Science 309, 5744 (2005)]. We show experimentally that the colloidal network so formed can remain…

Soft Condensed Matter · Physics 2015-05-14 Eduardo Sanz , Kathryn A. White , Paul S. Clegg , Michael E. Cates
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