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Several different enzymes display an apparent diffusion coefficient that increases with the concentration of their substrate. Moreover, their motion becomes directed in substrate gradients. Currently, there are several competing models for…

Biological Physics · Physics 2020-09-23 Giovanni Giunta , Hamid Seyed-Allaei , Ulrich Gerland

Reaction-diffusion processes across layered media arise in several scientific domains such as pattern-forming E. coli on agar substrates, epidermal-mesenchymal coupling in development, and symmetry-breaking in cell polarisation. We develop…

Pattern Formation and Solitons · Physics 2020-09-18 Andrew L. Krause , Václav Klika , Jacob Halatek , Paul K. Grant , Thomas E. Woolley , Neil Dalchau , Eamonn A. Gaffney

Evaporating suspensions of colloidal particles lead to the formation of a variety of patterns, ranging from a left-over ring of a dried coffee drop to uniformly distributed solid pigments left behind wet paint. To characterize the…

Soft Condensed Matter · Physics 2014-11-19 C. Nadir Kaplan , L. Mahadevan

When a colloidal sessile droplet dries on a substrate, the particles suspended in it usually deposit in a ring-like pattern. This phenomenon is commonly referred to as the "coffee-ring" effect. One paradigm for why this occurs is as a…

Fluid Dynamics · Physics 2016-12-14 Saeed Jafari Kang , Vahid Vandadi , James D. Felske , Hassan Masoud

We study small perturbations of diffusion processes in $\mathbb{R}^d$ that leave invariant a finite collection of hypersurfaces. Each surface is assumed to be repelling for the unperturbed process, and the unperturbed motion on each of the…

Probability · Mathematics 2026-02-12 Leonid Koralov , Chenglin Liu

The coffee-ring effect is a universal feature of evaporating sessile droplets with pinned contact line, wherein solutes or particles are advected to the droplet's edge due to evaporation-driven flows. While existing models have successfully…

Evaporating a droplet containing dispersed colloids leaves behind a dried deposit whose shape is determined by capillary flows and the resulting particle transport. The classical coffee-ring effect occurs when an outward radial flow drives…

Soft Condensed Matter · Physics 2026-04-27 Samuel S. Nielsen , Ryker Fish , Brian C. Seper , Brennan Sprinkle , Michelle M. Driscoll

Motivated by bacterial chemotaxis and multi-species ecological interactions in heterogeneous environments, we study a general one-dimensional reaction-cross-diffusion system in the presence of spatial heterogeneity in both transport and…

Pattern Formation and Solitons · Physics 2023-03-08 Eamonn A. Gaffney , Andrew L. Krause , Philip K. Maini , Chenyuan Wang

Abridged abstract: Inert interactions between randomly moving entities and spatial disorder play a crucial role in quantifying the diffusive properties of a system. These interactions affect only the movement of the entities, and examples…

Statistical Mechanics · Physics 2022-09-20 Seeralan Sarvaharman , Luca Giuggioli

The present work investigates numerically the transport of colloidal particles within an evaporating sessile droplet and their deposition on the substrate in unfavourable conditions. The coupled phenomena of fluid flow and heat and mass…

Fluid Dynamics · Physics 2025-07-21 A. Mokhtari , M. AitSaada , S. Chikh , L. Tadrist

Transported chemical reactions in unsaturated porous media are relevant across a range of environmental and industrial applications. Continuum scale dispersive models are often based on equivalent parameters derived from analogy with…

Effects of substrate temperature, substrate wettability and particles concentration are experimentally investigated for evaporation of a sessile water droplet containing colloidal particles. Time-varying droplet shapes and temperature of…

Fluid Dynamics · Physics 2016-10-21 Nagesh D. Patil , Prathamesh G. Bange , Rajneesh Bhardwaj , Atul Sharma

A model of randomly distributed overlapping spheres of different radii is represented to describe a heterogeneous porous medium. Two-particle correlation function of the relative position of pores of different radii in the medium space was…

Soft Condensed Matter · Physics 2016-03-04 V. D. Borman , A. A. Belogorlov , V. A. Byrkin , V. N. Tronin , V. I. Troyan

"When the liquid phase of a particle-laden droplet evaporates, a ring of solute is typically formed - what has become known as the "coffee ring effect". A key focus of recent work has been the suppression of the coffee-ring effect to leave…

Fluid Dynamics · Physics 2022-12-22 John McCarthy , Alfonso Castrejón-Pita , Mokhtar Adda-Bedia , Dominic Vella

We investigate the upscaling of diffusive transport parameters as function of pore scale material structure using a stochastic framework. We focus on sub-REV (representative elementary volume) scale where the complexity of pore space…

Materials Science · Physics 2021-06-21 Alraune Zech , Matthijs de Winter

Our numerical study aims to investigate particle deposit patterns from the evaporation of a sessile colloidal droplet. An in house finite volume code is developed to simulate the coupled phenomena of flow and heat and mass transfer with…

Fluid Dynamics · Physics 2025-07-21 A. Mokhtari , M. Ait Saada , S. Chikh , L. Tadrist

The process of preparing heterogeneous catalysts on porous supports includes a drying stage, in which the porous material, impregnated with an aqueous solution of the catalyst precursor, is dried, and the precursor is precipitated on the…

Chemical Physics · Physics 2026-01-06 N. V. Peskov

Solute deposits from evaporating drops with pinned contact line are usually concentrated near the contact line. The stain, or pattern, left on the substrate then consists of a single ring, commonly known as a coffee ring. Here we report on…

Soft Condensed Matter · Physics 2007-05-23 Vladimir A. Belyi , D. Kaya , M. Muthukumar

When a droplet containing a non-volatile component is dried on a substrate, it leaves a ringlike deposit on the substrate. We propose a theory which predicts the deposit distribution based on a model of fluid flow and contact line motion of…

Soft Condensed Matter · Physics 2016-02-17 Xingkun Man , Masao Doi

This paper studies the mechanisms of dispersion in the laminar flow through the pore space of a $3$-dimensional porous medium. We focus on pre-asymptotic transport prior to the asymptotic hydrodynamic dispersion regime, in which solute…

Fluid Dynamics · Physics 2018-03-05 Marco Dentz , Matteo Icardi , Juan J. Hidalgo
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