Related papers: Interstellar stereoisomerism
Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…
With the well-established correlation between the relative stabilities of isomers and their interstellar abundances coupled with the prevalence of isomeric species among the interstellar molecular species, isomerization remains a plausible…
Astrochemistry aims at studying chemical processes in astronomical environments. This discipline -- located at the crossroad between astrophysics and chemistry -- is rapidly evolving and explores the issue of the formation of molecules of…
The interstellar medium (ISM) has a multiphase structure characterized by gas, dust and molecules. The gas can be found in different charge states: neutral, low-ionized (warm) and high-ionized (hot). It is possible to probe the multiphase…
The Interstellar Medium (ISM) comprises gases at different temperatures and densities, including ionized, atomic, molecular species, and dust particles. The neutral ISM is dominated by neutral hydrogen and has ionization fractions up to 8%.…
This is the first in a series of three papers describing a project with the Cosmic Origins Spectrograph on the Hubble Space Telescope to measure abundances of the neutral interstellar medium (ISM) in a sample of 9 nearby star-forming…
An accurate treatment of the multiphase interstellar medium (ISM) in hydrodynamic galaxy simulations requires that we follow not only the thermal evolution of the gas, but also the evolution of its chemical state, including its molecular…
The increasing number of observations towards different environments in the Milky Way, as well as theoretical and experimental works, are improving our knowledge of the astrochemical processes in the interstellar medium (ISM). In this…
The abundances of gas and dust (solids and complex molecules) in the interstellar medium (ISM) as well as their composition and structures impact practically all of astrophysics. Fundamental processes from star formation to stellar winds to…
Accurate enthalpies of formation are reported for known and potential astromolecules using high level ab initio quantum chemical calculations. A total of 130 molecules comprising of 31 isomeric groups and 24 cyanide/isocyanide pairs with…
The wavelength range 912-2000A (hereafter far-UV) provides access to absorption lines of the interstellar medium (ISM), circumgalactic medium (CGM), and intergalactic medium (IGM) in phases spanning a wide range of ionization, density,…
The interstellar medium (ISM) is the material that fills the space between the stars in all galaxies; it is a multi-phase medium in pressure equilibrium, with densities and temperatures covering over 6 orders of magnitude. Although…
Modern observations of the interstellar medium (ISM) in galaxies detect a variety of atomic and molecular species. The goal is to connect these observations to the astrochemical properties of the ISM. 3D hydro-chemical simulations attempt…
We present a method for modelling star-forming clouds that combines two different models of the thermal evolution of the interstellar medium (ISM). In the combined model, where the densities are low enough that at least some part of the…
Electrons densities in different locations of our galaxy are obtained in pulsar astronomy by dividing the dispersion measure (DM) by the distance of the pulsar to Earth. The properties of the interstellar plasma are related to its heating.…
The interstellar medium (ISM) is a very complex medium which contains the matter needed to form stars and planets. The ISM is in permanent interaction with radiation, turbulence, magnetic and gravitational fields, and accelerated particles.…
We introduce the PRISM interstellar medium (ISM) model for thermochemistry and its implementation in the RAMSES-RTZ code. The model includes a non-equilibrium primordial, metal, and molecular chemistry network for 115 species coupled to…
We present an analysis of the molecular and atomic gas emission in the rest-frame far-infrared and sub-millimetre, from the lensed z=2.3 sub-millimetre galaxy SMM J2135-0102. We obtain very high signal-to-noise detections of 11 transitions…
Stereoisomers have the same molecular formula and the same atom connectivity and their existence can be related to the presence of different three-dimensional arrangements. Stereoisomerism is of great importance in many different fields…
In recent astrochemical studies it has become crucial to study all the complete conformational panorama of the molecule, some of which are potentially detectable in the interstellar medium (ISM). In this context, the isomeric ratio can be…