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Lattice vibrations are highly sensitive to crystal symmetries and their changes across phase transitions. The latter can modify irreducible (co)representations and corresponding infrared and Raman selection rules of phonons. This concept is…

We have found that the polarization dependence of Raman scattering in organic crystals at finite temperatures can only be described by a fourth-rank formalism. This generalization of the second-rank Raman tensor $\mathcal{R}$ stems from the…

The Raman active G mode in graphene exhibits strong coupling to electrons, yet the comprehensive treatment of this interaction in the calculation of its temperature-dependent Raman spectrum remains incomplete. In this study, we calculate…

Time-resolved Raman spectroscopy techniques offer various ways to study the dynamics of molecular vibrations in liquids or gases and optical phonons in crystals. While these techniques give access to the coherence time of the vibrational…

Quantum Physics · Physics 2021-04-06 Santiago Tarrago Velez , Vivishek Sudhir , Nicolas Sangouard , Christophe Galland

We develop a theoretical framework for probing moir\'e phonon modes using Raman spectroscopy, and illustrate it with the example of twisted bilayer graphene (TBG). These moir\'e phonons arise from interlayer sliding motion in twisted 2D…

Strongly Correlated Electrons · Physics 2025-06-24 Vitor Dantas , Héctor Ochoa , Rafael M. Fernandes , Natalia B. Perkins

Phonons are quasiparticles associated with mechanical vibrations in materials. They are at the root of the propagation of sound and elastic waves, as well as of thermal phenomena, which are pervasive in our everyday life and in many…

The contribution of interface phonons to the first order Raman scattering in nanocrystals with non spherical geometry is analyzed. Interface optical phonons in the spheroidal geometry are discussed and the corresponding Frohlich-like…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 F. Comas , C. Trallero-Giner , Nelson Studart , G. E. Marques

Statistical properties of light produced in spontaneous Raman scattering on an ensemble of molecules indicate the quantum nature of this phenomenon. The scattered light is non-classical and has high non-classical intensity correlations…

Optics · Physics 2026-05-15 Ivan V. Panyukov , Evgeny S. Andrianov

Frequency combs have revolutionized optical frequency metrology, allowing one to determine highly accurate transition frequencies of a wealth of molecular species. Despite a recognized scientific interest, these progresses have only…

Optical systems are scalable under low-intensity illumination since their governing equations are linearly dependent of the optical signal strength. Nonetheless, in high-intensity regimes, the induced polarization becomes nonlinear,…

A theoretical study describing the coherence properties of near-field Raman scattering in two- and one-dimensional systems is presented. The model is applied to the Raman modes of pristine graphene and graphene edges. Our analysis is based…

Mesoscale and Nanoscale Physics · Physics 2014-03-31 Luiz Gustavo Cançado , Ryan Beams , Ado Jorio , Lukas Novotny

Raman spectroscopy is an integral part of graphene research. It is used to determine the number and orientation of layers, the quality and types of edge, and the effects of perturbations, such as electric and magnetic fields, strain,…

Materials Science · Physics 2015-06-16 Andrea C. Ferrari , Denis M. Basko

Three-color coherent anti-Stokes Raman scattering represents non-degenerate four wave mixing process that includes both a non-resonant and resonant processes, the contributions of which depend on how the molecular vibrational modes are…

Optics · Physics 2020-10-14 Supriya Nagpal , Bryan Semon , Gombojav O. Ariunbold

We have investigated the phonon dynamics of a single-molecule embedded in a mechanical resonator made of an organic crystal. The whole system is placed in an optical resonator within the bad cavity limit. We have found that the optical…

Quantum Physics · Physics 2024-01-05 Victor Ceban , Mihai A. Macovei

Raman scattering on phonon--plasmon coupled modes in high magnetic fields is considered theoretically. The calculations of the dielectric function were performed in the long-wave approximation for the semiclassical and ultra-quantum…

Materials Science · Physics 2007-05-23 L. A. Falkovsky

The multiphonon quantum dynamics in laser-pumped cavity optomechanical samples containing a vibrating mirror is investigated. Especially, we focus on dispersive interaction regimes where the externally applied coherent field frequency…

Quantum Physics · Physics 2022-03-09 Mihai A. Macovei , Adriana Pálffy

We investigate the modulation of optical phonons in semiconductor crystal by surface acoustic wave (SAW) propagating on the crystal surface. The SAW fields induce changes on the order of 10\textsuperscript{-3} in the average Raman…

Mesoscale and Nanoscale Physics · Physics 2016-06-08 F. Iikawa , A. Hernández-Mínguez , M. Ramsteiner , P. V. Santos

While the vibrational thermodynamics of materials with small anharmonicity at low temperatures has been understood well based on the harmonic phonons approximation; at high temperatures, this understanding must accommodate how phonons…

Materials Science · Physics 2015-10-20 Tian Lan

Spontaneous vibrational Raman scattering is a ubiquitous form of light-matter interaction whose description necessitates quantization of the electromagnetic field. It is usually considered as an incoherent process because the scattered…

Quantum Physics · Physics 2023-07-18 Valeria Vento , Santiago Tarrago Velez , Anna Pogrebna , Christophe Galland

High-gain resonant nonlinear Raman scattering on trapped cold atoms within a high-fineness ring optical cavity is simply explained under a nonlinear opto-mechanical mechanism, and a proposal using it to detect frequency of micro-trap on…

Atomic Physics · Physics 2014-03-24 Lin Zhang