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Resistive solid state sensors are widely used in multiple applications, including molecular and gas detection. Absorption or intercalation of the target species varies the lattice parameters and an effective thickness of thin films, which…

Materials Science · Physics 2020-06-11 Sudhansu Sekhar Das , Gregory Kopnov , Alexander Gerber

Palladium satisfies most of the requirements for an effective hydrogen storage material with two major drawbacks: it has a relatively low gravimetric hydrogen density and is prohibitively expensive for large-scale applications. Pd-based…

Materials Science · Physics 2022-01-19 S. S. Das , G. Kopnov , A. Gerber

For hydrogen sensor and storage applications, films of Au and Pd were (i) co-sputtered at different rates or (ii) deposited in a sequential layer-by-layer fashion on a cover glass. Peculiarities of hydrogen uptake and release were optically…

We deposit intrinsic hydrogenated amorphous silicon (a-Si:H) thin films by reactive pulsed laser deposition, for various hydrogen pressures in the 0-20 Pa range, at a low deposition temperature of 120C, and investigate the hydrogen…

Materials Science · Physics 2017-04-17 A. Mellos , M. Kandyla , D. Palles , M. Kompitsas

We tune the thermodynamics of hydrogen absorption in Mg by means of elastic clamping. The loading isotherms measured by hydrogenography show that Mg films covered with Mg-alloy-forming elements, such as Pd and Ni, have hydrogen plateau…

Materials Science · Physics 2015-05-13 A. Baldi , M. Gonzalez-Silveira , V. Palmisano , B. Dam , R. Griessen

The present work is essentially focused on the study of optical and structural properties of hydrogenated amorphous silicon thin films (a-Si:H) prepared by radio-frequency cathodic sputtering. We examine separately the influence of hydrogen…

Materials Science · Physics 2007-05-23 A. Barhdadi , M. Chafik El Idrissi

Anisotropic nanostructured porous Pd films are fabricated using oblique angle deposition in vacuum on a glass substrate. They display a dichroic response, due to localised surface plasmon resonances (LSPR) within the nanoparticles forming…

Chemical Physics · Physics 2018-07-20 William L. Watkins , Yves Borensztein

Strain has emerged as a promising approach for tuning electrocatalytic properties, yet its role in sputter-deposited thin films remains poorly understood. In this work, magnetron-sputtered platinum (Pt) thin films with different stress…

Previously, it has been shown that the strength of the perpendicular magnetic anisotropy (PMA) of thin Palladium-Cobalt bi-layer films can be modified when hydrogen gas is absorbed by the Palladium (Pd) layer. In our recent work we showed…

Materials Science · Physics 2016-01-15 Chris Lueng , Peter J. Metaxas , Mikhail Kostylev

We investigate the response of palladium-cobalt bi-layer thin films to hydrogen charging at atmospheric pressure for spintronic applications. We find that hydrogen absorption by the palladium layer results in the narrowing and shifting of…

Materials Science · Physics 2015-06-12 Crosby S. Chang , Mikhail Kostylev , Eugene Ivanov

Metal hydrides are critical materials in numerous technologies including hydrogen storage, gas separation, and electrocatalysis. Here, using Pd-H as a model metal hydride, we perform electrochemical insertion studies of hydrogen via liquid…

Materials Science · Physics 2018-08-07 Jesse D. Benck , Ariel Jackson , David Young , Daniel Rettenwander , Yet-Ming Chiang

TiZrV film is mainly applied in the ultra-high vacuum pipe of storage ring. Thin film coatings of palladium which was added onto the TiZrV film to increase the service life of nonevaporable getters and enhance pumping speed for H2, was…

Accelerator Physics · Physics 2016-01-20 Jie Wang , Bo Zhang , Yan-Hui Xu , Wei Wei , Le Fan , Xiang-Tao Pei , Yuan-Zhi Hong , Yong Wang

In this work, we characterized gadolinium oxide films deposited on silicon by high pressure sputtering with a two-step process: first, we sputtered metallic gadolinium in an argon atmosphere and then, we performed an in-situ plasma…

Materials Science · Physics 2024-02-05 María Ángela Pampillón , Pedro Carlos Feijoo , Enrique San Andrés

Devising effective platinum (Pt)-free nanomaterials for catalyzing oxygen reduction reaction (ORR) is desired, but some main drawbacks still exist for commercial implementation in fuel cell systems. Herein, we present the preparation of…

We show that the internal quality factors of high impedance superconducting resonators made of granular aluminum can be improved by coating them with micrometric films of solid para-hydrogen molecular crystals. We attribute the average…

Catalyzing capping layers on top of metal hydrides are often employed to enhance the hydrogenation kinetics of metal-hydride based systems such as hydrogen sensors. Here, we experimentally study the hydrogenation kinetics of capping layers…

Materials Science · Physics 2021-04-26 Lars Bannenberg , Herman Schreuders

A novel technique to deposit metals on highly conjugated polyaniline films has been developed. In general, electrodeposition of metals, having low reduction potential, from aqueous solution, is difficult due to disruptive effect of hydrogen…

Applied Physics · Physics 2020-06-09 Amrita Singh , Asfiya Contractora , Ravindra D. Kale , Vinay A Juvekar

This work reports a systematic study of the evolution of charge transport mechanism in granular ultra-thin films of palladium of thickness varying between 6nm and 2nm. While the films with thickness > 4nm exhibit metallic behaviour, that at…

Metal hydrides often display dramatic changes in optical properties upon hydrogenation. These shifts make them prime candidates for many tunable optical devices, such as optical hydrogen sensors and switchable mirrors. While some of these…

Materials Science · Physics 2018-10-10 Kevin J. Palm , Joseph B. Murray , Tarun C. Narayan , Jeremy N. Munday

Entropy stabilization has garnered significant attention as a new approach to designing novel materials. Much of the work in this area has focused on bulk ceramic processing, leaving entropy-stabilized thin films relatively underexplored.…

Materials Science · Physics 2020-06-29 Valerie Jacobson , Dave Diercks , Bobby To , Andriy Zakutayev , Geoff Brennecka
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