Related papers: Strict Entropy Decrease of Clausius Entropy in an …
The entropy of an electronic system offers important insights into the nature of its quantum mechanical ground state. This is particularly valuable in cases where the state is difficult to identify by conventional experimental probes, such…
There are currently two main, continuum models of entropy: a 'reversible', Clausius entropy model and an 'irreversible', Onsager-Prigogine entropy model. It is shown that the equations of the 'reversible' and the 'irreversible' entropy…
The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…
Non-equilibrium quantum thermodynamics is an intensively developing field with many existing applications. We study the dynamics of temperatures and chemical potentials of fermionic reservoirs coupled to an open quantum system. We show that…
Compressible (full) potential flow is expressed as an equivalent first-order system of conservation laws for density $\rho$ and velocity $v$. Energy $E$ is shown to be the only nontrivial entropy for that system in multiple space…
A theory for non-equilibrium systems is derived from a maximum entropy approach similar in spirit to the equilibrium theory given by Gibbs. Requiring Hamilton's principle of stationary action to be satisfied on average during a trajectory,…
We give a modified derivation of the Einstein equation of state by considering the Clausius relation $T\delta S-\delta N =\delta Q$ on a null hypersurface with a non-vanishing expansion ($\theta \neq 0$), i.e. not in the equilibrium. The…
From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…
The example provided in the comment [arXiv:0803.2241] concerns a situation where the system is initially at negative temperature. It is known that in such cases the Law of Entropy Decrease holds. Nevertheless, this does not challenge the…
In this work, Entropy-Stable (ES) schemes are formulated for the multicomponent compressible Euler equations. Entropy-conservative (EC) and ES fluxes are derived. Particular attention is paid to the limit case of zero partial densities…
The specific thermal enthalpy of a moist-air parcel is defined analytically following a method in which specific moist entropy is derived from the Third Law of thermodynamics. Specific thermal enthalpy is computed by integrating specific…
We consider the problem of defining free energy and other thermodynamic functions when the entropy is given as a general function of the probablity distribution, including that for non extensive forms. We find that the free energy, which is…
In this work we study the mathematical aspects of the development in the continuum thermodynamics known as the "Entropy Principle". It started with the pioneering works of B.Coleman, W.Noll and I. Muller in 60th of XX cent. and got its…
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…
In this study, we present a reformulation of classical equilibrium thermodynamics by replacing the obscure and ambiguous concept of entropy with the clear and intuitive concept of information stored in a thermodynamic system. Specifically,…
The thermal-equilibrium canonical distribution is currently obtained by maximizing the Boltzmann-Gibbs-von Neumann-Shannon entropy $S_{BG}(p)=k\sum^{W}_{i=1}p_{i}\ln 1/p_{i}$ constrained to $\sum^{W}_{i=1}p_{i}=1$ and…
The entropy shows an unavoidable tendency of disorder in thermostatistics according to the second thermodynamics law. This provides a minimization entropy principle for quantum thermostatistics with the von Neumann entropy and nonextensive…
Self-gravitating systems are expected to reach a statistical equilibrium state either through collisional relaxation or violent collisionless relaxation. However, a maximum entropy state does not always exist and the system may undergo a…
We derive an expression for the minimal rate of entropy that sustains two reservoirs at different temperatures $T_0$ and $T_\ell$. The law displays an intuitive $\ell^{-1}$ dependency on the relative distance and a characterisic $\log^2…
The Von Neumann entropy of reduced states is a measure of bipartite entanglement. Despite its name, the entanglement entropy cannot by itself be used as a resource for creating thermodynamic heat flows. In order to extract heat from an…